Organic Chemistry (8th Edition)
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 20, Problem 50P
Interpretation Introduction

Interpretation:

The structure of glucuronide formed by the reaction of βD-glucuronic acid and phenol is to be drawn.

Concept Introduction:

The structural representation of sugar molecule in cyclic form is known as Haworth projection.  Sugar molecule that has six-membered-ring is known as pyranose and sugar molecule that has five-membered-ring is called furanose.  A sugar molecule in which hydroxyl groups of first and sixth carbon atom are on the same side is known as α sugar, otherwise β sugar.

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d-Glucuronic acid is found widely in plants and animals. One of its functions is to detoxify poisonous HO-containing compounds by reacting with them inthe liver to form glucuronides. Glucuronides are water soluble and, therefore, readily excreted. After ingestion of a poison such as turpentine or phenol, theglucuronides of these compounds are found in urine. Draw the structure of the glucuronide formed by the reaction of β-d-glucuronic acid and phenol.
Bile salts are derivative of cholestrol. However, the solubilities of these compounds in water are drastically different; cholestrol is highly hydrophobic, and the bile salts are soluble in digestive juices. Explain the differences.
NAD is: B E) . Amines can be produced by: A) B) Oxidation of nitro compounds Reduction of nitro compounds Acidification of nitro compounds Hydrolysis of nitro compounds IUPAC name of the following compound is The reduced form of NADH A dehydrating coenzyme A hydrating coenzyme A methylating coenzyme The oxidized form of NADH A) 3-methylhexanoic acid 3-methylbenzoicacid 3-methylcyclohexanoic acid. 1-methylcyclohexanoic acid A) B) Peptide bonds are: A) B D) The compound 4-hydroxyhexanedioc acid has following functional groups (s) 2 Carboxylic acids alcohol and carboxylic acid ester and alcohol alcohol and aromatic group ක COOH Esters Amines Amides Carboxylic acids and amines CH₁ 3-metnyl кусто

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Organic Chemistry (8th Edition)

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