Whether D-erythrose and L-erythose are enantiomers or diastereomers has to be stated. Concept Introduction: Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images. Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

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Answer 1

Question

Chapter 20.3, Problem 4P

a)

Interpretation Introduction

Interpretation:

Whether D-erythrose and L-erythose are enantiomers or diastereomers has to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

b)

Interpretation Introduction

Interpretation:

Whether L-erythrose and L-threose, enantiomers or diastereomers are to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

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Are d-erythrose and l-erythrose enantiomers or diastereomers?

m) Which pyranose ring (A, B, C, or D) in the tetrasaccharide below is derived from D-altrose? The Fischer projections for the four aldohexoses that make up this tetrasaccharide are shown below. B C D HOH CHO CHO CHO CHO HO+H HTOH Fонно н HOH HOH H-OH H-OH H-+-OH H-TOHHOH HOH H+OH HOHнтон нон CHOH CHOH CHOH CHOH De D-glue Dalose Datrone i NH Į HOH STEP 1 OH, HO- answer 1. Just add arrows and charges for steps 1, 2, and 3 in formation of this enamine з no arrows needed here OH н Н ЮН -OH STEP 3 :ÖH н H STEP 2 на это про за поч

Which one is b-D glucose and which one is a-L glucose ? 2. Which one is b-fructose and which a-L fructose?

Answer 2

Question

Chapter 20.3, Problem 4P

a)

Interpretation Introduction

Interpretation:

Whether D-erythrose and L-erythose are enantiomers or diastereomers has to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

b)

Interpretation Introduction

Interpretation:

Whether L-erythrose and L-threose, enantiomers or diastereomers are to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

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Answer 3

Question

Chapter 20.3, Problem 4P

a)

Interpretation Introduction

Interpretation:

Whether D-erythrose and L-erythose are enantiomers or diastereomers has to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

b)

Interpretation Introduction

Interpretation:

Whether L-erythrose and L-threose, enantiomers or diastereomers are to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

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Answer 4

Question

Chapter 20.3, Problem 4P

a)

Interpretation Introduction

Interpretation:

Whether D-erythrose and L-erythose are enantiomers or diastereomers has to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

b)

Interpretation Introduction

Interpretation:

Whether L-erythrose and L-threose, enantiomers or diastereomers are to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

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Answer 5

Chapter 20.3, Problem 4P

a)

Interpretation Introduction

Interpretation:

Whether D-erythrose and L-erythose are enantiomers or diastereomers has to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

b)

Interpretation Introduction

Interpretation:

Whether L-erythrose and L-threose, enantiomers or diastereomers are to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

Answer 6

Chapter 20.3, Problem 4P

a)

Interpretation Introduction

Interpretation:

Whether D-erythrose and L-erythose are enantiomers or diastereomers has to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

Answer 7

Chapter 20.3, Problem 4P

a)

Interpretation Introduction

Interpretation:

Whether D-erythrose and L-erythose are enantiomers or diastereomers has to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

Answer 8

b)

Interpretation Introduction

Interpretation:

Whether L-erythrose and L-threose, enantiomers or diastereomers are to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

Answer 9

b)

Interpretation Introduction

Interpretation:

Whether L-erythrose and L-threose, enantiomers or diastereomers are to be stated.

Concept Introduction:

Enantiomers are the compounds with same chemical formula. These are known as optical isomers. Enantiomers are basically stereo-isomers of the same compound. Two compounds are called enantiomers of each other if these are formed a non-superimposable mirror images.

Diastereomers are also the compounds with the same chemical formula. These are also the types of stereo-isomers. Two compounds are called diastereomers of each other if both the compounds have different configuration at the one or more (not all) equivalent stereo centers. These are not mirror images of each other.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 20.1 - Prob. 1P Ch. 20.2 - Prob. 2P Ch. 20.2 - Prob. 3P Ch. 20.3 - Prob. 4P Ch. 20.3 - Prob. 5P Ch. 20.3 - Prob. 6P Ch. 20.4 - Prob. 7P Ch. 20.4 - Prob. 8P Ch. 20.5 - Prob. 9P Ch. 20.5 - Prob. 10P

Solution Summary: The author explains that D-erythrose and L-threose are enantiomers or diasteres.

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