Physics for Scientists and Engineers with Modern Physics
4th Edition
ISBN: 9780131495081
Author: Douglas C. Giancoli
Publisher: Addison-Wesley
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Chapter 18.1, Problem 1CE
If you double the volume of a gas while keeping the pressure and number of moles constant, the average (rms) speed of the molecules (a) doubles, (b) quadruples, (c) increases by
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If you double the typical speed of the molecules in a gas, by what factor does the pressure change? Give a simple explanation why the pressure changes by this factor.
The rms speed of the molecules of an ideal gas
(a) is the same as the most probable speed of the molecules.
(b) is always equal to V2 times the maximum molecular speed.
(c) will increase as the temperature of a gas increases.
(d) All of the above.
Rank the following gases in order from (a) highest to lowest rms speed of molecules and (b) highest to lowest average translational kinetic energy of a molecule: (i) oxygen (M = 32.0 g/mol) at 300 K; (ii) nitrogen(M = 28.0 g/mol) at 300 K; (iii) oxygen at 330 K; (iv) nitrogen at 330 K.
Chapter 18 Solutions
Physics for Scientists and Engineers with Modern Physics
Ch. 18.1 - In a mixture of the gases oxygen and helium, which...Ch. 18.1 - Now you can return to the Chapter-Opening...Ch. 18.1 - If you double the volume of a gas while keeping...Ch. 18.1 - By what factor must the absolute temperature...Ch. 18.4 - As the air warms up in the afternoon, how would...Ch. 18 - Why doesnt the size of different molecules enter...Ch. 18 - When a gas is rapidly compressed (say, by pushing...Ch. 18 - In Section 181 we assumed the gas molecules made...Ch. 18 - Explain in words how Charless law follows from...Ch. 18 - Prob. 5Q
Ch. 18 - As you go higher in the Earths atmosphere, the...Ch. 18 - Prob. 7QCh. 18 - Is temperature a macroscopic or microscopic...Ch. 18 - Explain why the peak of the curve for 310 K in...Ch. 18 - Escape velocity for the Earth refers to the...Ch. 18 - Prob. 11QCh. 18 - If the pressure in a gas is doubled while its...Ch. 18 - What everyday observation would tell you that not...Ch. 18 - Prob. 14QCh. 18 - Alcohol evaporates more quickly than water at room...Ch. 18 - Explain why a hot humid day is far more...Ch. 18 - Is it possible to boil water at room temperature...Ch. 18 - What exactly does it mean when we say that oxygen...Ch. 18 - A length of thin wire is placed over a block of...Ch. 18 - Consider two days when the air temperature is the...Ch. 18 - (a) Why does food cook faster in a pressure...Ch. 18 - How do a gas and a vapor differ?Ch. 18 - (a) At suitable temperatures and pressures, can...Ch. 18 - Why does dry ice not last long at room...Ch. 18 - Under what conditions can liquid CO2 exist? Be...Ch. 18 - Why does exhaled air appear as a little white...Ch. 18 - Prob. 27QCh. 18 - Prob. 1PCh. 18 - Prob. 2PCh. 18 - (I) By what factor will the rms speed of gas...Ch. 18 - (I) A gas is at 20C. To what temperature must it...Ch. 18 - (I) What speed would a 1.0-g paper clip have if it...Ch. 18 - (I) A 1.0-mol sample of hydrogen gas has a...Ch. 18 - (I) Twelve molecules have the following speeds,...Ch. 18 - (II) The rms speed of molecules in a gas at 20.0C...Ch. 18 - (II) If the pressure in a gas is tripled while its...Ch. 18 - Prob. 10PCh. 18 - (II) Show that for a mixture of two gases at the...Ch. 18 - (II) What is the rms speed of nitrogen molecules...Ch. 18 - (II) (a) For an ideal gas at temperature T show...Ch. 18 - Prob. 14PCh. 18 - Prob. 15PCh. 18 - Prob. 16PCh. 18 - Prob. 17PCh. 18 - Prob. 18PCh. 18 - Prob. 19PCh. 18 - (I) A group of 25 particles have the following...Ch. 18 - Prob. 21PCh. 18 - (I) CO2 exists in what phase when the pressure is...Ch. 18 - (I) (a) At atmospheric pressure, in what phases...Ch. 18 - Prob. 25PCh. 18 - Prob. 26PCh. 18 - Prob. 27PCh. 18 - Prob. 28PCh. 18 - Prob. 29PCh. 18 - Prob. 30PCh. 18 - (II) If the air pressure at a particular place in...Ch. 18 - (II) What is the mass of water in a closed room...Ch. 18 - Prob. 33PCh. 18 - Prob. 34PCh. 18 - (II) A pressure cooker is a sealed pot designed to...Ch. 18 - (II) When using a mercury barometer (Section 136),...Ch. 18 - (II) If the humidity is 45% at 30.0C, what is the...Ch. 18 - Prob. 38PCh. 18 - Prob. 40PCh. 18 - (II) For oxygen gas, the van der Waals equation of...Ch. 18 - Prob. 44PCh. 18 - (II) At about what pressure would the mean free...Ch. 18 - Prob. 46PCh. 18 - (II) A very small amount of hydrogen gas is...Ch. 18 - Prob. 48PCh. 18 - Prob. 49PCh. 18 - Prob. 50PCh. 18 - Prob. 51PCh. 18 - Prob. 53PCh. 18 - Prob. 54PCh. 18 - Prob. 55PCh. 18 - A sample of ideal gas must contain at least N =...Ch. 18 - In outer space the density of matter is about one...Ch. 18 - Calculate approximately the total translational...Ch. 18 - (a) Estimate the rms speed of an amino acid, whose...Ch. 18 - The escape speed from the Earth is 1.12 104 m/s,...Ch. 18 - Prob. 61GPCh. 18 - Prob. 62GPCh. 18 - Consider a container of oxygen gas at a...Ch. 18 - In humid climates, people constantly dehumidify...Ch. 18 - Prob. 65GPCh. 18 - Prob. 66GPCh. 18 - Prob. 67GPCh. 18 - At room temperature, it takes approximately 2.45 ...Ch. 18 - Calculate the total water vapor pressure in the...Ch. 18 - Prob. 70GPCh. 18 - The density of atoms, mostly hydrogen, in...Ch. 18 - Prob. 72GPCh. 18 - A sauna has 8.5 m3 of air volume, and the...Ch. 18 - Prob. 74GPCh. 18 - Prob. 75GP
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- Cylinder A contains oxygen (O2) gas, and cylinder B contains nitrogen (N2) gas. If the molecules in the two cylinders have the same rms speeds, which of the following statements is false? (a) The two gases haw different temperatures. (b) The temperature of cylinder B is less than the temperature of cylinder A. (c) The temperature of cylinder B is greater than the temperature of cylinder A. (d) The average kinetic energy of the nitrogen molecules is less than the average kinetic energy of the oxygen molecules.arrow_forwardA gas is at 200 K. If we wish to double the rms speed of the molecules of the gas, to what value must we raise its temperature? (a) 283 K (b) 400 K (c) 566 K (d) 800 K (e) 1 130 Karrow_forwardOne cylinder contains helium gas and another contains krypton gas at the same temperature. Mark each of these statements true, false, or impossible to determine from the given information. (a) The rms speeds of atoms in the two gases are the same. (b) The average kinetic energies of atoms in the two gases are the same. (c) The internal energies of 1 mole of gas in each cylinder are the same. (d) The pressures in the two cylinders ale the same.arrow_forward
- An ideal gas is contained in a vessel at 300 K. The temperature of the gas is then increased to 900 K. (i) By what factor does the average kinetic energy of the molecules change, (a) a factor of 9, (b) a factor of 3, (c) a factor of 3, (d) a factor of 1, or (e) a factor of 13? Using the same choices as in part (i), by what factor does each of the following change: (ii) the rms molecular speed of the molecules, (iii) the average momentum change that one molecule undergoes in a collision with one particular wall, (iv) the rate of collisions of molecules with walls, and (v) the pressure of the gas?arrow_forwardConsider the Maxwell-Boltzmann distribution function plotted in Problem 28. For those parameters, determine the rms velocity and the most probable speed, as well as the values of f(v) for each of these values. Compare these values with the graph in Problem 28. 28. Plot the Maxwell-Boltzmann distribution function for a gas composed of nitrogen molecules (N2) at a temperature of 295 K. Identify the points on the curve that have a value of half the maximum value. Estimate these speeds, which represent the range of speeds most of the molecules are likely to have. The mass of a nitrogen molecule is 4.68 1026 kg. Equation 20.18 can be used to find the rms velocity given the temperature, Boltzmanns constant, and the mass of the atom or molecule. The mass of a nitrogen molecule is 4.68 1026 kg. vrms=3kBTm=3(1.381023J/K)4.681026kg=511m/s Using the results of Problem 28 and the rms velocity, we can calculate the value of f(v). f(vrms) = (3.11 108)(511)2 e(5.75106(511)2) = 0.00181 The most probable speed, for which this function has its maximum value, is given by Equation 20.20. vmp=2kBTm=2(1.381023J/K)(295K)4.681026kg=417m/s f(vmp) = (3.11108)(417)2 e(5.75106(417)2) = 0.00199 We plot these points on the speed distribution. The most probable speed is indeed at the peak of the distribution function. Since the function is not symmetric, the rms velocity is somewhat higher than the most probable speed. Figure P20.29ANSarrow_forwardTwo containers hold an ideal gas at the same temperature and pressure. Both containers hold the same type of gas, but container B has twice the volume of container A. (i) What is the average translational kinetic energy per molecule in container B? (a) twice that of container A (b) the same as that of container A (c) half that of container A (d) impossible to determine (ii) From the same choices, describe the internal energy of the gas in container B.arrow_forward
- Which of the assumptions below is not made in the kinetic theory of gases? (a) The number of molecules is very large. (b) The molecules obey Newtons laws of motion. (c) The forces between molecules are long range. (d) The gas is a pure substance. (e) The average separation between molecules is large compared to their dimensions. (f) of (his account are correct statements necessary for a clear and complete explanation? (ii) Which are correct statements that are not necessary to account for the higher thermometer reading? (iii) Which are incorrect statements?arrow_forwardA vertical cylinder of cross-sectional area A is fitted with a tight-fitting, frictionless piston of mass m (Fig. P16.56). The piston is not restricted in its motion in any way and is supported by the gas at pressure P below it. Atmospheric pressure is P0. We wish to find die height h in Figure P16.56. (a) What analysis model is appropriate to describe the piston? (b) Write an appropriate force equation for the piston from this analysis model in terms of P, P0, m, A, and g. (c) Suppose n moles of an ideal gas are in the cylinder at a temperature of T. Substitute for P in your answer to part (b) to find the height h of the piston above the bottom of the cylinder.arrow_forwardA 40.0-g projectile is launched by the expansion of hot gas in an arrangement shown in Figure P12.4a. The cross sectional area of the launch tube is 1.0 cm2, and the length that the projectile travels down the tube after starting from rest is 52 cm. As the gas expands, the pressure varies as shown in Figure P12.4b. The values for the initial pressure and volume are P1 = 11 105 Pa and Vi = 8.0 cm3 while the final values are Pf = 1.0 105 Pa and Vf = 8.0 cm3. Friction between the projectile and the launch tube is negligible, (a) If the projectile is launched into a vacuum, what is the speed of the projectile as it leaves the launch tube? (b) If instead the projectile is launched into air at a pressure of 1.0 105 Pa. what fraction of the work done by the expanding gas in the tube is spent by the projectile pushing air out of the way as it proceeds down tile tube?arrow_forward
- Two cylinders A and B at the same temperature contain the same quantity of the same kind of gas. Cylinder A has three times the volume of cylinder B. What can you conclude about the pressures the gases exert? (a) We can conclude nothing about the pressures. (b) The pressure in A is three times the pressure in B. (c) The pressures must be equal. (d) The pressure in A must be one-third the pressure in B.arrow_forwardFifteen identical particles have various speeds: one has a speed of 2.00 m/s, two have speeds of 3.00 m/s, three have speeds of 5.00 m/s, four have speeds of 7.00 m/s, three have speeds of 9.00 m/s, and two have speeds of 12.0 m/s. Find (a) the average speed, (b) the rms speed, and (c) the most probable speed of these particles.arrow_forwardInitially, the translational rms speed of a molecule if an ideal gas is 560 m/s. The pressure and volume of this gas are kept constant, while the number of molecules is increased by a factor of 7. What is the final translational rms speed of the molecules?arrow_forward
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