Concept explainers
Interpretation: The bonding in
Concept Introduction:
Lewis dot structure is the representation which shows the bonding between atoms present in a molecule. It shows lone pairs and bond pairs that exist on each bonded atom. Lewis dot structure is also known as Lewis dot formula or electron dot structure.
Molecular orbital theory explained the bonding, magnetic and spectral properties of molecule. It is based on the formation of molecular orbitals by the combination of atomic orbitals.
Molecular orbital diagrams represents the distribution of electrons in different molecular orbitals in increasing order of their energy. Hence lower energy molecular orbitals occupy first then only electron moves in higher energy orbitals.
Want to see the full answer?
Check out a sample textbook solutionChapter 18 Solutions
Chemical Principles
- Give the Lewis structure, molecular structure, and hybridization of the oxygen atom for OF2. Would you expect OF2 to be a strong oxidizing agent like O2F2 discussed in Exercise 61?arrow_forwardSketch the resonance structures for the N2O molecule. Is the hybridization of the N atoms the same or different in each structure? Describe the orbitals involved in bond formation by the central N atom.arrow_forwardThe ionization energy of O2 is smaller than the ionization energy of atomic O; the opposite is true for the ionization energies of N2 and atomic N. Explain this behavior in terms of the molecular orbital energy diagrams of O2 and N2.arrow_forward
- Describe the hybridization of silicon and the molecular structure of the following molecules and ions: (a) (CH3)3SiH. (b) SIO44-. (c) Si2H6. (d) Si(OH)4. (e) SiF62-arrow_forwardIdentify the hybrid orbitals used by boron in BCl3 and in BCl4, the ion formed from the reaction of BCl3 and Cl. Explain your choices.arrow_forwardSuppose you carry out the following reaction of ammonia and boron trifluoride in the laboratory. (a) What is the geometry of the boron atom in BF3? In H3NBF3? (b) What is the hybridization of the boron atom in the two compounds? (c) Considering the structures and bonding of NH3 and BF3, why do you expect the nitrogen on NH3 to donate an electron pair to the B atom of BF3? (d) BF3 also reacts readily with water. Based on the ammonia reaction above, speculate on how water can interact with BF3.arrow_forward
- what is the lewis structure of ICl4-and what is its geometry?arrow_forwardBoron trifluoride (BF3) has no dipole moment (u = 0 D). Explain how this observation confirms the geometry of BF3 predicted by VSEPR theory.arrow_forwardthe three stable oxides of carbon monoxide (CO), Carbon dioxide(CO2), and carbon suboxide (C3O2). for each oxide draw the Lewis structure, predict the molecular structure, and described the bonding in terms of the hybrid orbitals for carbon atoms.arrow_forward
- What is the hybridization of the central atom in the hypophosphite (PO3-2) ion?arrow_forwardDraw the Lewis structure of NF3. What are its electron-pair and molecular geometries? What is the hybridization of the nitrogen atom? What orbitals on N and F overlap to form bonds between these elements?arrow_forwarduse VESPR theory to predict the molecular geometry of SiF4, SiF5- and (SiF6)2- (show lone pair electrons on the silicon atom). what is the hybridization, oxidation state and formal charge of the silicon in these molecules /ions?arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
- Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning