The NMR spectra are to be assigned to ethyl acetate, methyl propionate and propyl formate. Concept introduction: Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. Proton NMR spectroscopy identifies the number of hydrogen atoms present in a molecule and the nature of the functional group. The value of chemical peaks depends upon the chemical environment around the hydrogen atom.

Question

In Section 6.2d, we saw that the pK, of an acid is equal to the pH of the solution at which half the acid has dissociated into its conjugate base. UV-vis spectroscopy can be used to measure the relative concentrations involved if the acid or conjugate base absorbs UV-vis light. With this in mind, suppose that a particular acid has a Amax of 312 nm. The figure here shows the absorbance at that wavelength as a function of pH. What is the pk, of the acid? 3 4 6 7 8 10 11 12 pH Absorbance at 312 nm

Answer 1

Question

Chapter 16, Problem 16.53E

Interpretation Introduction

Interpretation:

The NMR spectra are to be assigned to ethyl acetate, methyl propionate and propyl formate.

Concept introduction:

Spectroscopy method is used to identify the structure of the molecule. It is based on the interactions between matter and electromagnetic radiations. Proton NMR spectroscopy identifies the number of hydrogen atoms present in a molecule and the nature of the functional group. The value of chemical peaks depends upon the chemical environment around the hydrogen atom.

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In Section 6.2d, we saw that the pK, of an acid is equal to the pH of the solution at which half the acid has dissociated into its conjugate base. UV-vis spectroscopy can be used to measure the relative concentrations involved if the acid or conjugate base absorbs UV-vis light. With this in mind, suppose that a particular acid has a Amax of 312 nm. The figure here shows the absorbance at that wavelength as a function of pH. What is the pk, of the acid? 3 4 6 7 8 10 11 12 pH Absorbance at 312 nm

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