Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 16, Problem 16.44E
Interpretation Introduction

Interpretation:

The value of νL for a 13C in a magnetic field of 3.22T is to be calculated.

Concept introduction:

Spectroscopy based on the splitting of Ml levels of a nuclei is termed as nuclear magnetic resonance or NMR. The splitting is due to the similar behaviour of nucleus as the electron. Like electrons, nucleus have nonzero spin and a magnetic dipole associated with it. This leads to splitting in an external magnetic field.

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Calculate the energy separation between the spin states of an electron in a magnetic field of 0.250 T.
3 Calculate the frequencies and wavelengths for the rotational transition J = 0 → J = 1 and J = 4 → J = 5 for the HCl molecule. The internuclear distance is Re = 0.12745 nm. What is the frequency shift between the two isotopomers H35Cl and H37Cl for the two transitions?
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