Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 16, Problem 16.28E
Interpretation Introduction

Interpretation:

The magnetic field strength that is required to achieve resonance between the two spin states of an electron on a compound that absorbs microwave radiation having a frequency of 1.165GHz is to be calculated.

Concept introduction:

Electron spin resonance is the method to study the materials with an unpaired electron. An unpaired electron absorbs the microwave radiation under the strong magnetic field. The difference between two energy levels is calculated by the formula shown below.

ΔEmag=geμBB

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Q2. Consider the hydrogenation of ethylene C2H4 + H2 = C2H6 The heats of combustion and molar entropies for the three gases at 298 K are given by: C2H4 C2H6 H2 AH comb/kJ mol‍¹ -1395 -1550 -243 Sº / J K¹ mol-1 220.7 230.4 131.1 The average heat capacity change, ACP, for the reaction over the temperature range 298-1000 K is 10.9 J K¹ mol¹. Using these data, determine: (a) the standard enthalpy change at 800 K (b) the standard entropy change at 800 K (c) the equilibrium constant at 800 K.
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