Concept explainers
(a)
Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.
Concept introduction: Halogens react with
Dehydrohalogenation reaction is a class of reaction in which the removal of hydrogen halide takes place in the presence of strong base.
The reaction between bromine and
(b)
Interpretation: All the steps and reagents needed to convert cyclohexane into given compound is to be shown.
Concept introduction: Halogens react with alkanes in presence of heat or light to form alkyl halides. This is known as halogenation reaction. This is a free radical substitution reaction. In this the halogen substitutes the hydrogen atom from
Dehydrohalogenation reaction is class of reaction in which the removal of hydrogen halide takes place in presence of strong base.
In the presence of peroxide, alkene is oxidized to
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Chapter 13 Solutions
Organic Chemistry (6th Edition)
- Draw structures corresponding to the following IUPAC names: (a) 1, 1-Dimethylcyclooctane (b) 3-Cyclobutylhexane (c) 1, 2-Dichlorocyclopentane (d) l, 3-Dibromo-5-methylcyclohexanearrow_forwardDraw the structures of the following molecules: (a) trans-l-Bromo-3-methylcyclohexane (b) cis-1, 2-Dimethylcyclobutane (c) trans-1 -tert-Butyl-2-ethylcyclohexanearrow_forwardWhen 2-pentene is treated with Cl, in methanol, three products are formed. Account for the formation of each product (you need not explain their relative percentages). CI OCH3 H,CO CI CI CI Cle CH;CHCHCH,CH, + CH;CHCHCH,CH3 + CH,CHČHCH,CH, CH;OH CH;CH=CHCH,CH, 50% 35% 15%arrow_forward
- Draw the structure of an alkane with molecular formula C7H16 that contains (a) one 4° carbon; (b) only 1° and 2° carbons; (c) 1°, 2°, and 3° hydrogens.arrow_forwardConsider cycloheptatrienone and ethylene, and draw a possible product formed from each type of cycloaddition: (a) [2 + 2]; (b) [4 + 2]; (c) [6 + 2].arrow_forwardWhat is the proper name for the following compound? CH;CH2 CH,CH2CH,Br C=C CH;CH2 CH3 O 1-bromo-5-ethyl-4-methyl-3-heptene O 7-bromo-3-ethyl-4-methyl-3-heptene O cis-7-bromo-3-ethyl-4-methyl-3-heptene 1-bromo-3-pentenyl-2-pentene O trans-7-bromo-3-ethyl-4-methyl-3-heptenearrow_forward
- Draw the products formed when the following alkynes are treated with each set of reagents: [1] H2O, H2SO4, HgSO4; or [2] R2BH followed by H2O2, −OH.arrow_forwardWhat is the name of the organic reactant and the resulting product of the reaction below? H H H H H H H-C-C-ċ=ċ-ċ-c-H + CI-CI H H H H O reactant: cis-3-hexene; product: 3,4-dichlorohexane reactant: trans-3-hexene; product: 3,4-dichlorohexane O reactant: cis-3-hexene product: 3,4-chlorohexane O reactant: cis-3-hexene product: dichlorohexanearrow_forwardCompounds A and B are isomers of the molecular formula CyH19Br. Both yield the same alkene Cin an elimination reaction. Hydrogenation of C yields the product 2,3,3,4 tetramethyl pentane. What are the structures of A, B, and C?arrow_forward
- Give the proper IUPAC name for the following compounds: CH,- CH, CH,- CH - CH -CH, CH, Br CH CH, Br H:-CH; CH - CH-CH, H;C CH, CH, CH, CH- CH- CH, c=C H,C-CH, CH, CH- CH, H H ОН CIarrow_forward4-Give the IUPAC names of the following compounds: (a) CH,CH₂C=CCOOH (d) CH, COOH (b) CH₂CH(NH₂)CH(OH)COOH NO₂ O.N COOH NO₂ (c) (CH;),C=CHCOOH (1) OHarrow_forwardThe action of heating one mole of water (containing a trace of acid catalyst) on one mole of compound Y produces one mole of CH,COOH and one mole of CH, CH,NH, The structure of Y is: Select one: O CHCNCCH, CH,CH,NHCH,CH, OH CH CHNHCH,CH, O CHCH,CNHCH; O CH;CH NHÖCH;arrow_forward
