Organic Chemistry (6th Edition)
6th Edition
ISBN: 9781260119107
Author: Janice Gorzynski Smith
Publisher: McGraw Hill Education
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Chapter 13, Problem 61P
Devise a synthesis of each compound using
a.
c. 
d. 
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Show how to bring about each conversion in good yield.
a.
b.
C6H5
Cl
OH
COOH
C6H5 COOH
What is the major organic product obtained from the following reaction?
A.
CI
B.
H
1. (CH3CH₂)2CuLi
2. H3O+
C.
D.
•ay.a
OH
Synthesize each compound from cyclohexanol using any other organic or inorganic compounds.
CH,OH
a.
g.
(Each cyclohexane ring must
come from cyclohexanol.)
COOH
b.
d.
h.
сно
CHs
(Each cyclohexane ring must
come from cyclohexanol.)
Chapter 13 Solutions
Organic Chemistry (6th Edition)
Ch. 13.1 - Prob. 1PCh. 13.1 - Prob. 2PCh. 13.2 - Prob. 3PCh. 13.3 - Prob. 4PCh. 13.3 - Prob. 5PCh. 13.4 - Prob. 7PCh. 13.5 - Problem 15.8 Which bond in the each compound is...Ch. 13.6 - Prob. 9PCh. 13.6 - Prob. 10PCh. 13.7 - Prob. 11P
Ch. 13.7 - Prob. 12PCh. 13.8 - Prob. 13PCh. 13.8 - Prob. 14PCh. 13 - Prob. 27PCh. 13 - Prob. 28PCh. 13 - Prob. 34PCh. 13 - 15.37 What alkane is needed to make each alkyl...Ch. 13 - 15.38 Which alkyl halides can be prepared in good...Ch. 13 - Prob. 37PCh. 13 - 15.40 Explain why radical bromination of p-xylene...Ch. 13 - a. What product(s) (excluding stereoisomers) are...Ch. 13 - Prob. 40PCh. 13 - 15.43 Draw the products formed when each alkene is...Ch. 13 - 15.44 Draw all constitutional isomers formed when...Ch. 13 - 15.45 Draw the organic products formed in each...Ch. 13 - Prob. 45PCh. 13 - 15.47 Treatment of a hydrocarbon A (molecular...Ch. 13 - 15.48 Draw the products formed in each reaction...Ch. 13 - 15.53 Consider the following bromination: .
a....Ch. 13 - 15.54 Draw a stepwise mechanism for the following...Ch. 13 - Prob. 57PCh. 13 - 15.57 Devise a synthesis of each compound from...Ch. 13 - Prob. 59PCh. 13 - Prob. 60PCh. 13 - 15.60 Devise a synthesis of each compound using ...Ch. 13 - Prob. 62PCh. 13 - Prob. 63PCh. 13 - 15.63 As described in Section 9.16, the...Ch. 13 - 15.64 Ethers are oxidized with to form...
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- Design a synthesis of each compound from alcohols having four or fewer carbons, acetylene, and ethylene oxide as the only organic starting materials. You may use any other inorganic reagents you choose. a. b. C. CO₂H xx но d. OHarrow_forwardcis-Cyclohexane-1,2-diol can be synthesized from cyclohexene by using which reagent? a.O3 b.OsO4 c.H2SO4 d.mCPBAarrow_forwardWhat is the major organic product obtained from the following reaction? A. B. HN 1. H₂NCH3, H* cat. 2. NaBH3CN C. D. HNarrow_forward
- What is the major organic product obtained from the following reaction? A. B. NH₂ OH 1. LIAIH4 2. H3O+ NH₂ C. D. NH NH₂arrow_forwardConvert benzene into each compound. You may also use any inorganic reagents and organic alcohols having four or fewer carbons. One step of the synthesis must use a Grignard reagent.arrow_forward17. What is the missing reagent in the reaction below? aq. HCI A. CH2(COOE1)2, NaOEt C. CH2(COOE1)2, HOAC B. CH3CO2Et, NaOEt D. CH3CO,Et, HOAC 18. In several reactions of carhonyl compounds that we have studied, the reaction proceeds by carrow_forward
- b. a. C. HO Draw the products of each reaction. COOH COOH + NaOCH3 OH OH H₂SO4 H₂SO4arrow_forwardCompound that is most easily hydrolyzed by acid in water `NH A. В. F C. D.arrow_forwardDevise a synthesis of each compound from benzene. You may use alcohols with one or two carbons and any inorganic reagents. a. qe Br H Br b. C. N OHarrow_forward
- Synthesis 10.63 Devise a synthesis of each product from the given starting material. More than one step is required. a. b. d. e. Br Br OH OCH3 ta CI OHarrow_forward1. Draw the products in each reaction. a. H b. CH3-C-CH₂CH3 CI -OH K+ -OC(CH3)3 CH₂CH3 a Xa C. d. CH₂CH₂OH CH3CH₂O™arrow_forwardDesign a synthesis of each compound from alcohols having four or fewer carbons, acetylene, and ethylene oxide as the only organic starting materials. You may use any other inorganic reagents you choose. a. b. C. CO₂Harrow_forward
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