Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Question
Chapter 13.3, Problem 3P
(a)
Interpretation Introduction
Interpretation:
Easiest hydrogen to remove by the chlorine radical should be identified.
Concept introduction:
Radical or free radical: unpaired valence electron of an atom, molecule, or ion is called as radical
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which weakest bond strength.
(b)
Interpretation Introduction
Interpretation:
The secondary hydrogen should be identified.
Radical or free radical:
Unpaired valence electron of an atom, molecule, or ion is called as radical
Bond strength is depends on the formation of the radical, if the radical is involving in resonance which weakest bond strength.
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A. Electron-donating and Electron-withdrawing effects in conjugated structures
1. Go to the website http://molview.org/
2. Draw the following structure on MolView. For each structure, obtain the following information:
a. Charge
b. Bond dipoles
c. Over-all dipole
Structure 1:
Structure 2:
H
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F
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Structure 3:
Structure 4:
Structure 5:
Structure 6:
You have to obtain the output from MolView. You can either copy the 3D image with the information, or you may
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1. What are your observations based on the data you have obtained?
2. What can you infer about the nature of the substituents? Provide at least two inferences and explain your basis.
3. Which substituents is/are electron donating? Which of them are electron-withdrawing?
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I0-
Chapter 13 Solutions
Organic Chemistry
Ch. 13.2 - Prob. 1PCh. 13.2 - Write the steps for formation of...Ch. 13.3 - Prob. 3PCh. 13.4 - Prob. 4PCh. 13.5 - Prob. 7PCh. 13.5 - a. Would chlorination or bromination produce a...Ch. 13.5 - Prob. 10PCh. 13.6 - Prob. 11PCh. 13.7 - Prob. 12PCh. 13.7 - Prob. 13P
Ch. 13.8 - Prob. 14PCh. 13.8 - Draw the stereoisomers of the major...Ch. 13.9 - a. How many stereoisomers are formed from the...Ch. 13.9 - Prob. 17PCh. 13.9 - Prob. 19PCh. 13.9 - Prob. 20PCh. 13.9 - Prob. 21PCh. 13.10 - Prob. 22PCh. 13.11 - How many atoms share the unpaired electrons in...Ch. 13.11 - Prob. 24PCh. 13 - Prob. 25PCh. 13 - Prob. 26PCh. 13 - Prob. 27PCh. 13 - Prob. 28PCh. 13 - Prob. 29PCh. 13 - Prob. 30PCh. 13 - Prob. 31PCh. 13 - Prob. 32PCh. 13 - Prob. 33PCh. 13 - Prob. 34PCh. 13 - Prob. 35PCh. 13 - Starting with cyclohexane, how could the following...Ch. 13 - a. Propose a mechanism for the following reaction:...Ch. 13 - What stereoisomers are obtained from the following...Ch. 13 - Prob. 39PCh. 13 - Prob. 40PCh. 13 - Prob. 41PCh. 13 - Draw the products of the following reactions,...Ch. 13 - a. What five-carbon alkene forms the same product...Ch. 13 - Prob. 44PCh. 13 - Prob. 45PCh. 13 - Prob. 46PCh. 13 - Explain why the rate of bromination of methane...Ch. 13 - Prob. 48P
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