Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Question
Chapter 13.10, Problem 22P
Interpretation Introduction
Interpretation:
Moles of
Concept introduction:
In the synthesis of fatty acids, firstly acetyl thioester and malonyl thioester combines to form a four carbon thioester. This thioester reacts with malonyl thioester. Each malonyl thioester adds two carbon. Each time malonyl thioester is added, two carbon atoms are increased in the fatty acid chain.
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Chapter 13 Solutions
Essential Organic Chemistry, Global Edition
Ch. 13.1 - Identify the most acidic hydrogen in each...Ch. 13.1 - Prob. 2PCh. 13.1 - Prob. 3PCh. 13.1 - Prob. 4PCh. 13.1 - Explain why HO cannot remove a proton from the...Ch. 13.2 - Prob. 6PCh. 13.2 - Prob. 7PCh. 13.3 - Prob. 8PCh. 13.3 - Prob. 9PCh. 13.3 - Prob. 10P
Ch. 13.4 - Prob. 11PCh. 13.5 - Prob. 12PCh. 13.5 - Prob. 13PCh. 13.6 - Prob. 14PCh. 13.7 - Prob. 16PCh. 13.8 - Prob. 17PCh. 13.8 - Prob. 18PCh. 13.8 - Prob. 19PCh. 13.9 - Prob. 20PCh. 13.10 - Propose a mechanism for the formation of...Ch. 13.10 - Prob. 22PCh. 13.10 - a. If the biosynthesis of palmitic acid were...Ch. 13 - Draw the enol tautomers for each of the following...Ch. 13 - Number the following compounds in order from...Ch. 13 - Prob. 26PCh. 13 - Explain why the pKa of a hydrogen bonded to the...Ch. 13 - Prob. 28PCh. 13 - Prob. 29PCh. 13 - Prob. 30PCh. 13 - Prob. 31PCh. 13 - Prob. 32PCh. 13 - Prob. 33PCh. 13 - Using cyclopentanone as the reactant, show the...Ch. 13 - Prob. 35PCh. 13 - Prob. 36PCh. 13 - Prob. 37PCh. 13 - Prob. 38PCh. 13 - Prob. 39PCh. 13 - Prob. 40PCh. 13 - Prob. 41PCh. 13 - Prob. 42PCh. 13 - Prob. 43PCh. 13 - Prob. 44PCh. 13 - Describe how the following compounds can be...Ch. 13 - Prob. 46PCh. 13 - Which would require a higher temperature:...Ch. 13 - Prob. 48PCh. 13 - Propose a mechanism for the following reaction:Ch. 13 - Show how the following compounds could be...Ch. 13 - Prob. 51PCh. 13 - Prob. 52P
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- Classify each of the following as (1) an energy-storage lipid, (2) a membrane lipid, or (3) an emulsification lipid. a. Oils b. Glycocholic acid c. Glycerophospholipids d. Sphingophospholipidsarrow_forwardDraw the condensed structural formula of a triacylglycerol formed from glycerol and three molecules of palmitic acid.arrow_forwardDraw the product of the complete hydrogenation (reduction) of the following fatty acid: -HO-arrow_forward
- Stearic acid (18:0) is classified as what type of fatty acid? O polysaturated O saturated O polyunsaturated monounsaturatedarrow_forward2 A reaction is completed on oleic acid that removes its double bond and saturates its fatty acid chain to become completely saturated. What is true about the product? a) The melting point of the product will be greater than that of the starting material. Ob) The intermolecular forces between molecules of the product will be less than those between molecules of starting material. c) The number of kinks in the fatty acid chain will increase.arrow_forwardIn addition to glycerol, fatty acids and phosphate, phosphoglycerols generally contain: nonpolar amino acids creatine O polar or ionic alcohols O sterols O aromatic amino acidsarrow_forward
- Caprylic acid is an 8-carbon saturated fatty acid. Draw the structure of caprylic acid.arrow_forwardDraw the structure of a triacylglycerol formed from glycerol, one molecule of stearic acid, and two molecules of oleic acid. The stearic acid should form an ester bond with the 2° OH group of glycerol.arrow_forwardA mixture of fatty acyl methyl esters are separated based ona) Chargeb) Chain length and degree of saturationc) Molecular weightd) Ionic sizearrow_forward
- Indicate the FALSE alternative regarding saponification: a) Soap is obtained as the main product and glycerin as a by-product. b) Saponification can be carried out on both solid fats and oils. c) High molecular weight fatty acids are obtained. d) This method of obtaining soap is also called basic hydrolysis. e) The carbon chain of the soap obtained may contain saturated or unsaturated carbon-carbon bonds.arrow_forwardThese types of fatty acids lower blood chloesterol O Saturated O Monounsaturated Trans O Polyunsaturatearrow_forward4. Draw the product of hydrogenation of the following lipid. H₂C O HC H₂C-0-arrow_forward
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