Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 13, Problem 37QP
Interpretation Introduction
Interpretation: After drinking a carbonate soft drink below sea level it tastes flat, the reason why the miner could not stop belching throughout the trip up is to be explained.
Concept introduction:
The solubility of gas depends upon the pressure of the gas.
The relation between solubility and pressure of a gas is expressed as
Here,
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Divers who go to great depths in the ocean experience large differences in pressure between the surface and their final destinations below the surface. At times, they have to avoid quick changes in pressure because of the effects on the solubility of nitrogen in their blood. If the solubility decreases quickly, then gas bubbles can form in the person’s blood, causing a dangerous condition called “the bends.”
In one or two sentences, state whether you would expect the condition to be a greater hazard for divers as they dive down or as they return to the surface. Then, explain your prediction in terms of the solubility of gases in liquids at different pressures.
1. The solubility of L-glutamic acid (an amino acid) in water has been determined to be as follows (all values
are grams of L-glutamic acid/100 mL of water):
Temp.
0 °C
0.34
50 °C
2.19
75 °C
5.53
100 °C
14.00
(a) What is the minimum volume of water (rounded to the nearest mL) that you would use to recrystallize
50.0 g of L-glutamic acid? Please show all work.
(c) Where is the missing L-glutamic acid?
(b) How much purified L-glutamic acid would you expect to recover at 0°C assuming no losses due to
technique? Please show all work.
An aqueous solution of sodium iodide (NaI) has a molality of 0.150 mol·kg–1 at 18°C.
a) Convert this concentration to molarity. You may assume that the solution has adensity of 1.00 g·cm–3at 18°C. Report your answer to 3 significant figures.
Mm(NaI) = 149.9 g/molMm(H2O) = 18.0 g/mol
b) Assuming a boiling point elevation constant of 0.51 °C/m and a Van’t Hoff factorequal to 1.76, calculate the boiling point of the solution.
c) To make homemade ice cream, you cool the milk and cream by immersing thecontainer in ice and a concentrated solution of rock salt (NaCl) in water. If you wantto have a water-salt solution that freezes at –10°C, what mass of NaCl must you addto 3.0 kg of water? You may assume the Van’t Hoff factor for NaCl is equal to 1.85.Mm(NaCl) = 58.4 g/mol
Chapter 13 Solutions
Chemistry
Ch. 13.1 - Prob. 1PPACh. 13.1 - Prob. 1PPBCh. 13.1 - Prob. 1PPCCh. 13.2 - Prob. 1CPCh. 13.2 - Prob. 2CPCh. 13.2 - Practice Problem ATTEMPT
Determine (a) the...Ch. 13.2 - Practice Problem BUILD
Determine the molality of...Ch. 13.2 - Prob. 1PPCCh. 13.3 - Practice Problem ATTEMPT
An aqueous solution that...Ch. 13.3 - Practice Problem BUILD
Determine the percent...
Ch. 13.3 - Practice Problem CONCEPTUALIZE
The diagrams...Ch. 13.3 - Prob. 1CPCh. 13.3 - What is the molality of a solution prepared by...Ch. 13.3 - Prob. 3CPCh. 13.3 - Prob. 4CPCh. 13.4 - Practice ProblemATTEMPT Calculate the...Ch. 13.4 - Prob. 1PPBCh. 13.4 - Practice Problem CONCEPTUALIZE
The first diagram...Ch. 13.4 - The solubility of N2 in water at 25°C and an N 2...Ch. 13.4 - Calculate the molar concentration of O 2 in water...Ch. 13.5 - Practice ProblemATTEMPT Calculate the vapor...Ch. 13.5 - Prob. 1PPBCh. 13.5 - Practice ProblemCONCEPTUALIZE The diagrams...Ch. 13.5 - 13.5.1 A solution contains 75.0 g of glucose...Ch. 13.5 - Determine the boiling point and the freezing point...Ch. 13.5 - 13.5.3 Calculate the osmotic pressure of a...Ch. 13.5 - 13.5.4 A 1.00-m solution of has a freezing point...Ch. 13.6 - Prob. 1PPACh. 13.6 - Prob. 1PPBCh. 13.6 - Practice Problem CONCEPTUALIZE
The diagrams...Ch. 13.6 - 13.6.1 A solution made by dissolving 14.2 g of...Ch. 13.6 - Prob. 2CPCh. 13.7 - Practice ProblemATTEMPT The freezing-point...Ch. 13.7 - Practice ProblemBUILD Using the experimental van't...Ch. 13.7 - Practice Problem CONCEPTUALIZE
The diagram...Ch. 13.8 - Practice ProblemATTEMPT Determine the osmotic...Ch. 13.8 - Practice Problem BUILD
Determine the...Ch. 13.8 - Practice Problem CONCEPTUALIZE
The first diagram...Ch. 13.9 - Practice Problem ATTEMPT
Calculate the molar mass...Ch. 13.9 - Practice Problem BUILD
What mass of naphthalene...Ch. 13.9 - Practice Problem CONCEPTUALIZE
The first diagram...Ch. 13.10 - Practice Problem ATTEMPT A solution made by...Ch. 13.10 - Practice Problem BUILD What mass of insulin must...Ch. 13.10 - Practice ProblemCONCEPTUALIZE The first diagram...Ch. 13.11 - Practice Problem ATTEMPT An aqueous solution that...Ch. 13.11 - Practice Problem BUILD
An aqueous solution that is...Ch. 13.11 - Practice Problem CONCEPTUALIZE The diagrams...Ch. 13 - Which of the following processes is accompanied by...Ch. 13 - 13.2
For each of the processes depicted here,...Ch. 13 - 13.3
For each of the processes depicted here,...Ch. 13 - Prob. 4KSPCh. 13 - Describe and give examples of an unsaturated...Ch. 13 - Prob. 2QPCh. 13 - Prob. 3QPCh. 13 - Prob. 4QPCh. 13 - Prob. 5QPCh. 13 - As you know, some solution processes are...Ch. 13 - Prob. 7QPCh. 13 - 13.8 Describe the factors that affect the...Ch. 13 - Prob. 9QPCh. 13 - Prob. 10QPCh. 13 - Prob. 11QPCh. 13 - Prob. 12QPCh. 13 - Prob. 13QPCh. 13 - Prob. 14QPCh. 13 - Prob. 15QPCh. 13 - Prob. 16QPCh. 13 - Prob. 17QPCh. 13 - Prob. 18QPCh. 13 - Prob. 19QPCh. 13 - Prob. 20QPCh. 13 - 13.21 The alcohol content of hard liquor is...Ch. 13 - Prob. 22QPCh. 13 - Prob. 23QPCh. 13 - 13.24 The density of an aqueous solution...Ch. 13 - Prob. 25QPCh. 13 - Prob. 26QPCh. 13 - Prob. 27QPCh. 13 - What is thermal pollution? Why is it harmful to...Ch. 13 - Prob. 29QPCh. 13 - A student is observing two beakers of water. One...Ch. 13 - Prob. 31QPCh. 13 - Prob. 32QPCh. 13 - The solubility of KNO 3 is 155 g per 100 g of...Ch. 13 - Prob. 34QPCh. 13 - 13.35 The solubility of in water at What is its...Ch. 13 - Prob. 36QPCh. 13 - Prob. 37QPCh. 13 - Prob. 38QPCh. 13 - Prob. 39QPCh. 13 - Prob. 40QPCh. 13 - Prob. 41QPCh. 13 - Prob. 42QPCh. 13 - Prob. 43QPCh. 13 - Prob. 44QPCh. 13 - Prob. 45QPCh. 13 - 13.46 Write the equations relating boiling-point...Ch. 13 - Prob. 47QPCh. 13 - Prob. 48QPCh. 13 - Prob. 49QPCh. 13 - Prob. 50QPCh. 13 - Prob. 51QPCh. 13 - Prob. 52QPCh. 13 - Prob. 53QPCh. 13 - What are ion pairs? What effect does ion-pair...Ch. 13 - Prob. 55QPCh. 13 - Prob. 56QPCh. 13 - 13.57 A solution is prepared by dissolving 396 g...Ch. 13 - Prob. 58QPCh. 13 - Prob. 59QPCh. 13 - Prob. 60QPCh. 13 - Prob. 61QPCh. 13 - Prob. 62QPCh. 13 - Prob. 63QPCh. 13 - 13.64 How many liters of the antifreeze ethylene...Ch. 13 - Prob. 65QPCh. 13 - Prob. 66QPCh. 13 - Prob. 67QPCh. 13 - Prob. 68QPCh. 13 - 13.69 Both and are used to melt ice on roads and...Ch. 13 - Prob. 70QPCh. 13 - Prob. 71QPCh. 13 - Prob. 72QPCh. 13 - Prob. 73QPCh. 13 - Calculate the difference in osmotic pressure (in...Ch. 13 - 13.75 Which of the following aqueous solutions has...Ch. 13 - Prob. 76QPCh. 13 - 13.77 Arrange the following solutions in order of...Ch. 13 - Prob. 78QPCh. 13 - Indicate which compound in each of the following...Ch. 13 - Prob. 80QPCh. 13 - Prob. 81QPCh. 13 - Prob. 82QPCh. 13 - Prob. 83QPCh. 13 - The elemental analysis of an organic solid...Ch. 13 - 13.85 A solution of 2.50 g of a compound having...Ch. 13 - 13.86 The molar mass of benzoic acid determined...Ch. 13 - 13.87 A solution containing 0.8330 g of a polymer...Ch. 13 - Prob. 88QPCh. 13 - A solution of 6.85 g of a carbohydrate in 100.0 g...Ch. 13 - Prob. 90QPCh. 13 - Prob. 91QPCh. 13 - Prob. 92QPCh. 13 - Prob. 93QPCh. 13 - Prob. 94QPCh. 13 - Prob. 95APCh. 13 - Prob. 96APCh. 13 - 13.97 Acetic acid is a polar molecule and can form...Ch. 13 - Prob. 98APCh. 13 - Prob. 99APCh. 13 - Prob. 100APCh. 13 - Prob. 101APCh. 13 - Prob. 102APCh. 13 - Prob. 103APCh. 13 - Prob. 104APCh. 13 - Prob. 105APCh. 13 - A solution of 1.00 g of anhydrous aluminum...Ch. 13 - Explain why reverse osmosis is (theoretically)...Ch. 13 - A 1.32-g sample of a mixture of cyclohexane ( C 6...Ch. 13 - Prob. 109APCh. 13 - Prob. 110APCh. 13 - Prob. 111APCh. 13 - Prob. 112APCh. 13 - Prob. 113APCh. 13 - Prob. 114APCh. 13 - Prob. 115APCh. 13 - Iodine ( I 2 ) is only sparingly soluble in water...Ch. 13 - Concentrated hydrochloric acid is usually...Ch. 13 - Explain each of the following statements: (a) The...Ch. 13 - A mixture of NaCl and sucrose ( C 12 H 22 O 12 )...Ch. 13 - Prob. 120APCh. 13 - At 27°C, the vapor pressure of pure water is 23.76...Ch. 13 - A nonvolatile organic compound Z was used to make...Ch. 13 - Prob. 123APCh. 13 - Prob. 124APCh. 13 - Prob. 125APCh. 13 - Prob. 126APCh. 13 - Prob. 127APCh. 13 - Prob. 128APCh. 13 - Prob. 129APCh. 13 - Prob. 130APCh. 13 - Prob. 131APCh. 13 - Consider the three mercury manometers shown in the...Ch. 13 - Prob. 133APCh. 13 - Prob. 134APCh. 13 - Prob. 135APCh. 13 - 13.136 In the apparatus shown, what will happen if...Ch. 13 - Prob. 137APCh. 13 - Prob. 138APCh. 13 - Lysozyme is an enzyme that cleaves bacterial cell...Ch. 13 - Prob. 140APCh. 13 - Prob. 141APCh. 13 - Prob. 142APCh. 13 - Prob. 143APCh. 13 - Prob. 144APCh. 13 - Prob. 145APCh. 13 - What masses of sodium chloride, magnesium...Ch. 13 - Prob. 147APCh. 13 - Prob. 148APCh. 13 - Prob. 149APCh. 13 - Hemoglobin, the oxygen-transport protein, binds...Ch. 13 - Prob. 151APCh. 13 - 13.152 The vapor pressure of ethanol and the...Ch. 13 - Prob. 153APCh. 13 - A mixture of two volatile liquids is said to be...Ch. 13 - A mixture of two volatile liquids is said to be...Ch. 13 - Prob. 3SEPPCh. 13 - Prob. 4SEPP
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY