Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 10, Problem 10.86E
Interpretation Introduction

Interpretation:

The reason as to why the given wavefunction for the 1-D particle-in-a-box cannot be assumed to give zero value on integration is to be explained.

Concept introduction:

For the orthogonality of the two different wavefunctions, the product of the wavefunctions is integrated over the entire limits. It is expressed by the equation as given below.

0ΨmΨn=0

Where, Ψm and Ψn are two different wavefunctions. The essential condition for two wavefunctions to be orthogonal to each other is mn.

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Chapter 10 Solutions

Physical Chemistry

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