Concept explainers
Verify that the following wavefunctions are indeed eigenfunctions of the Schrödinger equation, and determine their energy eigenvalues.
(a)
(b)
(c)
Want to see the full answer?
Check out a sample textbook solutionChapter 10 Solutions
Physical Chemistry
- Imagine a particle free to move in the x direction. Which of the following wavefunctions would be acceptable for such a particle? In eachcase, give your reasons for accepting or rejecting each function. (i) Ψ(x)=x2; (ii) Ψ(x)=1/x; (iii) Ψ(x)=e-x^2.arrow_forward5. Consider a particle constrained to move in one dimension described by the wavefunction v (x) = Ne2** (a) Determine the normalization constant (b) Is the wavefunction an eigenfunction of d? +16x? dx? (c) Calculate the probability of finding the particle anywhere along the negative x-axisarrow_forwardA normalized wavefunction for a particle confined between 0 and L in the x direction is ψ = (2/L)1/2 sin(πx/L). Suppose that L = 10.0 nm. Calculate the probability that the particle is (a) between x = 4.95 nm and 5.05 nm, (b) between x = 1.95 nm and 2.05 nm, (c) between x = 9.90 nm and 10.00 nm, (d) between x = 5.00 nm and 10.00 nm.arrow_forward
- 8a. What is the expectation value of the linear momentum for the 1-D wavefunction: -ax 2 (x) = Ne where -0arrow_forwardWhat are the allowed total angular momentum quantum numbers of a composite system in which j1 = 5 and j2 = 3?arrow_forward2. Which of the following wavefunctions are eigenfunctions d? of the operator dx- For those that are eigenfunctions, what is the eigenvalue (a) Y = ex (b) Y = x? (c) Y = sin x (d) Y = 3 cos x (e) Y = sin x + cos xarrow_forward106. Combining two real wave functions ₁ and 2, the following functions are constructed: A = ₁ + $₂₂ B = = ₁ +i0₂, C = ₁ −i0₂, D=i(0₁ +0₂). The correct statement will then be (a) A and B represent the same state (c) A and D represents the same state (b) A and C represent the same state. (d) B and D represent the same state.arrow_forwardConsider the wave function V222(x, ỹ, z) for a particle in a cubic box. Figure 4.45a shows a contour plot in a cut plane at ž = 0.75. (a) Convince yourself that the contour plot in a cut at ž = 0.25 would have the same pattern, but each positive peak would become negative, and vice versa. (b) Describe the shape of this wave function in a plane cut at ỹ = 0.5.arrow_forwardConsider the three spherical harmonics (a) Y0,0, (b) Y2,–1, and (c) Y3,+3. (a) For each spherical harmonic, substitute the explicit form of the function taken from Table 7F.1 into the left-hand side of eqn 7F.8 (the Schrödinger equation for a particle on a sphere) and confirm that the function is a solution of the equation; give the corresponding eigenvalue (the energy) and show that it agrees with eqn 7F.10. (b) Likewise, show that each spherical harmonic is an eigenfunction of lˆz = (ℏ/i)(d/dϕ) and give the eigenvalue in each case.arrow_forwardConsider a 1D particle in a box confined between a = 0 and x = 3. The Hamiltonian for the particle inside the box is simply given by Ĥ . Consider the following normalized wavefunction 2m dz² ¥(2) = 35 (x³ – 9x). Find the expectation value for the energy of the particle inside the box. Give your 5832 final answer for the expectation value in units of (NOTE: h, not hbar!). In your work, compare the expectation value to the lowest energy state of the 1D particle in a box and comment on how the expectation value you calculated for the wavefunction ¥(x) is an example of the variational principle.arrow_forwardConsider a particle of mass m confined to a one-dimensional box of length L and in a state with normalized wavefunction ψn. (a) Without evaluating any integrals, explain why ⟨x⟩ = L/2. (b) Without evaluating any integrals, explain why ⟨px⟩ = 0. (c) Derive an expression for ⟨x2⟩ (the necessary integrals will be found in the Resource section). (d) For a particle in a box the energy is given by En = n2h2/8mL2 and, because the potential energy is zero, all of this energy is kinetic. Use this observation and, without evaluating any integrals, explain why <p2x> = n2h2/4L2.arrow_forwardThe radial wave function of a quantum state of Hydrogen is given by R(r)= (1/[4(2π)^{1/2}])a^{-3/2}( 2 - r/a ) exp(-r/2a), where a is the Bohr radius. (a) Show analytically that this function has an extremum at r=4a. (b) Sketch the graph of R(r) x r. For a decent sketch of this graph, take into account some values of R(r) at certain points of interest, such as r=0, 2a, 4a, and so on. Also take into account the extremes of the function R(r) and their inflection points, as well as the limit r--> infinity. (c) Determine the radial probability density P(r) associated with the quantum state in question. (d) Show that the function P(r) you determined in part (c) is properly normalized.arrow_forwardarrow_back_iosSEE MORE QUESTIONSarrow_forward_ios
- Physical ChemistryChemistryISBN:9781133958437Author:Ball, David W. (david Warren), BAER, TomasPublisher:Wadsworth Cengage Learning,Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningIntroductory Chemistry: A FoundationChemistryISBN:9781337399425Author:Steven S. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
- Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning