EBK ORGANIC CHEMISTRY STUDY GUIDE AND S
6th Edition
ISBN: 9781319385415
Author: PARISE
Publisher: VST
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Chapter 10, Problem 10.7P
Interpretation Introduction
Interpretation:
The major
Concept introduction:
The dehydration of alcohol leads to the formation of the alkene. This dehydration can be done acid-catalyzed mechanism. In this mechanism first step is the abstraction of a proton by the hydroxide group. The second step is the removal of water to give an intermediate “carbocation”. The third step is the generation of an alkene by the removal of
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7. Consider the following three step reaction.
[4
(a) Add curved arrows in Step [1] to show the movement of electrons.
H
Lö:
HÖ
[1]
+ H-Ci:
(b) Use the curved arrows drawn in Step [2] to identify the structure of X.
X is converted in Step [3] to phenol and HCI.
[2]
+ H-CI:
[3]
phenol
Draw the geometric isomers (if any) of the following alkenes. Identify the geometric isomer as either cisor transor as either Eor Z, where applicable.
a.BrHC=CHBr
c. (HO)(CH3CH2)C=CH(CH2CH3)
b.ClHC=CCl2
d. (I)(CH3CH2CH2)C=C(CH2CH3)(CH3)
Draw the alkene structure that produced the following compounds in a ozonolysis reaction as specified.
1. O3
2. (CH3)2S
You do not have to consider stereochemistry.
You do not have to explicitly draw H atoms.
In cases where there is more than one answer, just draw one.
Chapter 10 Solutions
EBK ORGANIC CHEMISTRY STUDY GUIDE AND S
Ch. 10 - Prob. 10.1PCh. 10 - Prob. 10.2PCh. 10 - Prob. 10.3PCh. 10 - Prob. 10.4PCh. 10 - Prob. 10.5PCh. 10 - Prob. 10.6PCh. 10 - Prob. 10.7PCh. 10 - Prob. 10.8PCh. 10 - Prob. 10.9PCh. 10 - Prob. 10.10P
Ch. 10 - Prob. 10.11PCh. 10 - Prob. 10.12PCh. 10 - Prob. 10.13PCh. 10 - Prob. 10.14PCh. 10 - Prob. 10.15PCh. 10 - Prob. 10.16PCh. 10 - Prob. 10.17PCh. 10 - Prob. 10.18PCh. 10 - Prob. 10.19PCh. 10 - Prob. 10.20PCh. 10 - Prob. 10.21PCh. 10 - Prob. 10.22PCh. 10 - Prob. 10.23PCh. 10 - Prob. 10.24PCh. 10 - Prob. 10.25PCh. 10 - Prob. 10.26PCh. 10 - Prob. 10.27PCh. 10 - Prob. 10.28PCh. 10 - Prob. 10.29PCh. 10 - Prob. 10.30PCh. 10 - Prob. 10.31PCh. 10 - Prob. 10.32PCh. 10 - Prob. 10.33PCh. 10 - Prob. 10.34PCh. 10 - Prob. 10.35PCh. 10 - Prob. 10.36PCh. 10 - Prob. 10.37PCh. 10 - Prob. 10.38PCh. 10 - Prob. 10.39APCh. 10 - Prob. 10.40APCh. 10 - Prob. 10.41APCh. 10 - Prob. 10.42APCh. 10 - Prob. 10.43APCh. 10 - Prob. 10.44APCh. 10 - Prob. 10.45APCh. 10 - Prob. 10.46APCh. 10 - Prob. 10.47APCh. 10 - Prob. 10.48APCh. 10 - Prob. 10.49APCh. 10 - Prob. 10.50APCh. 10 - Prob. 10.51APCh. 10 - Prob. 10.52APCh. 10 - Prob. 10.53APCh. 10 - Prob. 10.54APCh. 10 - Prob. 10.55APCh. 10 - Prob. 10.56APCh. 10 - Prob. 10.57APCh. 10 - Prob. 10.58APCh. 10 - Prob. 10.59APCh. 10 - Prob. 10.60APCh. 10 - Prob. 10.61APCh. 10 - Prob. 10.62APCh. 10 - Prob. 10.63APCh. 10 - Prob. 10.64APCh. 10 - Prob. 10.65APCh. 10 - Prob. 10.66APCh. 10 - Prob. 10.67APCh. 10 - Prob. 10.68APCh. 10 - Prob. 10.69APCh. 10 - Prob. 10.70AP
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- Provide an IUPAC name for the compound below. ball & stick 0O labels (Specify (E) or (Z) stereochemistry, if relevant, for straight chain alkenes only. It is not necessary to use italics in writing compound names. Pay attention to commas, dashes, and parentheses. )arrow_forwardDraw the structure for an alkene that gives the following reaction product. 7 CH2l2, Zn/Cu Ignore alkene stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. / [F ?arrow_forwardH₂N- -Br H₂C Provide the locant and substituent in the order that they will be written in the name. The parent name is (old IUPAC version) or (new IUPAC version).arrow_forward
- Draw the alkene that would react with the reagent given to account for the product formed. ? + + H₂O **** H₂S04 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. CH3 CH3 CHCCH3 | | OH CH3 +1arrow_forwardIt is sometimes necessary to isomerize a cis alkene to a trans alkene in asynthesis, a process that cannot be accomplished in a single step. Usingthe reactions , devise a stepwise method to convert cis-but-2-ene to trans-but-2-ene.arrow_forwardProvide an IUPAC name for each of the compounds shown. (Specify (E)/(Z) stereochemistry, if relevant, for straight chain alkenes only. Pay attention to commas, dashes, etc.) Br. H C=C CH3 H₂C-CH₂ CI CH₂CH3arrow_forward
- 8. Using Zaitsev's rule, choose the most stable alkene among the following. Draw out the structures of each of the options then select the correct answer. Recall that Zaitsev's Rule is about alkene stability. The trend for this is similar to the trend for carbocation stability. Either more or fewer groups on the alkene (and the carbocation) make it more stable. This question is wanting you to remember if more or fewer. it's A) 1,2-dimethylcyclohexene B) 1,6-dimethylcyclohexene C) cis-3,4-dimethylcyclohexene D) They are all of equal stability according to Zaitsev's rule. hatarrow_forwardWrite a structural formula and give two acceptable IUPAC names for each alkene of molecular formula C7H14 that has a tetrasubstituted double bond.arrow_forwardDraw the structural formula for all the alkenes with the indicated molecular formula that, without undergoing a rearrangement, produce the compound shown as a major product. Br. C7H12 Br2/H₂O OH . You do not have to consider stereochemistry. • If more than one structure fits the description, draw them all. ⚫ Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate structures with + signs from the drop-down menu. 0 ? F ChemDoodle Previous Nextarrow_forward
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