(a) Interpretation: The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted. Concept introduction: Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

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Answer 1

Question

Chapter 10, Problem 10.68AP

Interpretation Introduction

(a)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(c)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(d)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

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(b) Consider the reaction of 1-bromobutane with a large excess of ammonia (NH3). Draw the reactants, the transition state, andthe products. Note that the initial product is the salt of an amine (RNH3+ Br - ), which is deprotonated by the excess ammonia to give the amine.

Alkenes can be converted to alcohols by hydroboration-oxidation. (a) Draw the structure of the alcohol or alcohols formed in the reaction sequence. Clearly indicate stereochemistry by drawing a wedged bond, a dashed bond and two in-plane bonds per each chiral carbon. Draw hydrogen atoms that are connected to wedge-and-dash bonds.(b) Characterize the product or products of the reactions. Be sure to draw hydrogens on oxygen, where applicable. Select Draw Rings More Erase H 1. B₂H6, (a) diglyme 2. H2O2, HOT, H₂O ✓ C O Q2 Q

stion 6 of 14 Alkenes can be converted to alcohols by hydroboration-oxidation. (a) Draw the structure of the alcohol or alcohols formed in the reaction sequence. Clearly indicate stereochemistry by drawing a wedged bond, a dashed bond and two in-plane bonds per each chiral carbon. Draw hydrogen atoms that are connected to wedge-and-dash bonds.(b) Characterize the product or products of the reactions. Be sure to draw hydrogens on oxygen, where applicable. Select Draw Rings More Erase C 1. B2H6. diglyme (a) 2. H2O2, HO¯, H20

Answer 2

Question

Chapter 10, Problem 10.68AP

Interpretation Introduction

(a)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(c)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(d)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

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Answer 3

Question

Chapter 10, Problem 10.68AP

Interpretation Introduction

(a)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(c)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(d)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

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Answer 4

Question

Chapter 10, Problem 10.68AP

Interpretation Introduction

(a)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(c)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(d)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

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Answer 5

Chapter 10, Problem 10.68AP

Interpretation Introduction

(a)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(b)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(c)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Interpretation Introduction

(d)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 6

Chapter 10, Problem 10.68AP

Interpretation Introduction

(a)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 7

Chapter 10, Problem 10.68AP

Interpretation Introduction

(a)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The mechanism for each of the known conversions by the use of curved-arrow notation is to be predicted.

Concept introduction:

Substitution reaction is the reaction in which one group is replaced by the other group present in the reaction medium. Nucleophilic substitution reactions takes place when an electron rich species, the nucleophile, reacts at an electrophilic saturated carbon atom attached to an electronegative group displacing the leaving group.

Answer 14

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Answer 15

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Answer 16

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Answer 17

Ch. 10 - Prob. 10.1P Ch. 10 - Prob. 10.2P Ch. 10 - Prob. 10.3P Ch. 10 - Prob. 10.4P Ch. 10 - Prob. 10.5P Ch. 10 - Prob. 10.6P Ch. 10 - Prob. 10.7P Ch. 10 - Prob. 10.8P Ch. 10 - Prob. 10.9P Ch. 10 - Prob. 10.10P

Solution Summary: The author explains the mechanism for each of the known conversions by the use of curved-arrow notation.

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