Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 29.SE, Problem 52AP
Interpretation Introduction
Interpretation:
To determine the complete equation for the synthesis of the given
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Fatty acids and triglycerides are an important source of nutrition and a dense form
of stored energy. Digestion of fats yields more energy per gram than digestion of
carbohydrates.
Each turn on the B-oxidation spiral results in the formation of a new acetyl COA
molecule. This molecule can then be used to generate more energy in
A) fatty acid synthesis
B) ketolysis
C) glycolysis
D) tricarboxylic acid cycle
E) oxidative phosphorylation
draw and Identify different types of organic reaction mechanims in the following metabolic pathways.
Conversion of Pyruvate to Acetyl CoA
Citric acid cycle
Gluconeogenesis pathway (pyruvate to glucose)
Catabolism of triacylglycerols- beta-oxidation pathway
Biosynthesis of fatty acids from Acetyl CoA
Glycolysis (from glucose to two molecules of pyruvate)
Coenzyme A, NAD*, and FAD are coenzymes that are necessary for energy production. Classify each statement as describing
coenzyme A, NAD+, or FAD.
Coenzyme A
NAD+
FAD
Answer Bank
accepts two hydrogen atoms when it is reduced
derived from the vitamin pantothenic acid (B₂)
accepts two electrons and one proton when it is reduced
derived from the vitamin nicotinamide
derived from the vitamin riboflavin (B₂)
forms part of acetyl-SCOA, which is part of the citric acid cycle
Chapter 29 Solutions
Organic Chemistry
Ch. 29.1 - Prob. 1PCh. 29.3 - Write the equations for the remaining passages of...Ch. 29.3 - Prob. 3PCh. 29.4 - Write a mechanism for the dehydration reaction of...Ch. 29.4 - Evidence for the role of acetate in fatty-acid...Ch. 29.4 - Does the reduction of acetoacetyl ACP in step 6...Ch. 29.5 - Prob. 7PCh. 29.5 - Look at the entire glycolysis pathway, and make a...Ch. 29.6 - Prob. 9PCh. 29.7 - Prob. 10P
Ch. 29.7 - Write mechanisms for step 2 of the citric acid...Ch. 29.7 - Prob. 12PCh. 29.8 - Prob. 13PCh. 29.9 - Write all the steps in the transamination reaction...Ch. 29.9 - What -keto acid is formed on transamination of...Ch. 29.9 - Prob. 16PCh. 29.SE - Prob. 17VCCh. 29.SE - Identify the following intermediate in the citric...Ch. 29.SE - The following compound is an intermediate in the...Ch. 29.SE - Prob. 20VCCh. 29.SE - In the pentose phosphate pathway for degrading...Ch. 29.SE - Prob. 22MPCh. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - Prob. 25MPCh. 29.SE - Prob. 26MPCh. 29.SE - Prob. 27MPCh. 29.SE - Prob. 28MPCh. 29.SE - Prob. 29MPCh. 29.SE - Prob. 30MPCh. 29.SE - Prob. 31MPCh. 29.SE - Prob. 32APCh. 29.SE - Prob. 33APCh. 29.SE - Prob. 34APCh. 29.SE - Prob. 35APCh. 29.SE - Prob. 36APCh. 29.SE - Prob. 37APCh. 29.SE - Prob. 38APCh. 29.SE - Prob. 39APCh. 29.SE - Prob. 40APCh. 29.SE - Prob. 41APCh. 29.SE - Prob. 42APCh. 29.SE - Prob. 43APCh. 29.SE - Prob. 44APCh. 29.SE - Prob. 45APCh. 29.SE - Prob. 46APCh. 29.SE - Prob. 47APCh. 29.SE - Prob. 48APCh. 29.SE - Prob. 49APCh. 29.SE - Prob. 50APCh. 29.SE - In glycerol metabolism, the oxidation of...Ch. 29.SE - Prob. 52APCh. 29.SE - Prob. 53APCh. 29.SE - Prob. 54APCh. 29.SE - In step 7 of fatty-acid biosynthesis (Figure...Ch. 29.SE - Prob. 56AP
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- Mark any/all processes that are reductions. O FADH2 → FAD O hydrogenation of fats FAD FADH2 NAD* NADH NADH NAD*arrow_forwardDefine the term oxidative deamination?arrow_forwardTrypanosomes living in the bloodstream obtain all their free energy from glycolysis. They take up glucose from the host’s blood and excrete pyruvate as a waste product. In this part of their life cycle, trypanosomes do not carry out any oxidative phosphorylation, but they do use another oxygen-dependent pathway, which is absent in mammals, to oxidize NADH. Would this pathway be necessary if the trypanosome excreted lactate rather than pyruvate? Explain.arrow_forward
- Stearic acid is the common name for the C18 straight-chain, saturated fatty acid. Draw the structure of the fatty acyl-CoA that this forms (you don't have to draw out all of the atoms in coenzyme A; you can represent it as S-, and then show all of the reactions). Draw & identify all of the compounds formed when the eighteen carbon fat is converted to two molecules of acetyl-CoA and the fourteen-carbon fat via two turns of the fatty acid spiral. List the enzymes and coenzymes that are part of the pathway.arrow_forwardWhat is the name of the enzyme that converts glycerol to glycerol-3-phosphate?arrow_forwardClassify each substance as an oxidizing agent, a reducing agent, or neither: (a) NADH; (b) ADP; (c) FAD.arrow_forward
- During the overall process of glycolysis, in which of the following occurs for each glucose molecule processed. net loss of two ATP molecules net loss of four ATP molecules net gain of two ATP molecules net gain of four ATP moleculesarrow_forwardGlycolysis is the first step in the oxidation of fatty acids to produce energy. True or Falsearrow_forward
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