Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 29.SE, Problem 48AP
Interpretation Introduction
Interpretation:
To explain how the 3-phosphoglyceryl phosphate and phosphoenolpyruvate transfer a phosphate group to ADP while glucose 6-phosphate.
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Below is the overall net equation for the complete oxidation of pyruvate.
Calculate the number of ATP molecules that can be produced from the
complete oxidation of 6 molecules of pyruvate.
Pyruvate + 4NAD+ + FAD + GDP + Pi + 2H₂O →
3CO2 + 4NADH + 4H+ + FADH2 + GTP
(Given: The oxidation of one NADH yields 2.5 ATP; the oxidation of one
FADH2 yields 1.5 ATP; and one GDP yields 1 ATP.)
O 75 ATP
O 60 ATP
O 12.5 ATP
O 32 ATP
Which yields more energy upon hydrolysis, ATP or glycerol 1-phosphate? Why?
NADH and FADH2 can "create" ATP only if the cell can do electron transport
True
False
Chapter 29 Solutions
Organic Chemistry
Ch. 29.1 - Prob. 1PCh. 29.3 - Write the equations for the remaining passages of...Ch. 29.3 - Prob. 3PCh. 29.4 - Write a mechanism for the dehydration reaction of...Ch. 29.4 - Evidence for the role of acetate in fatty-acid...Ch. 29.4 - Does the reduction of acetoacetyl ACP in step 6...Ch. 29.5 - Prob. 7PCh. 29.5 - Look at the entire glycolysis pathway, and make a...Ch. 29.6 - Prob. 9PCh. 29.7 - Prob. 10P
Ch. 29.7 - Write mechanisms for step 2 of the citric acid...Ch. 29.7 - Prob. 12PCh. 29.8 - Prob. 13PCh. 29.9 - Write all the steps in the transamination reaction...Ch. 29.9 - What -keto acid is formed on transamination of...Ch. 29.9 - Prob. 16PCh. 29.SE - Prob. 17VCCh. 29.SE - Identify the following intermediate in the citric...Ch. 29.SE - The following compound is an intermediate in the...Ch. 29.SE - Prob. 20VCCh. 29.SE - In the pentose phosphate pathway for degrading...Ch. 29.SE - Prob. 22MPCh. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - Prob. 25MPCh. 29.SE - Prob. 26MPCh. 29.SE - Prob. 27MPCh. 29.SE - Prob. 28MPCh. 29.SE - Prob. 29MPCh. 29.SE - Prob. 30MPCh. 29.SE - Prob. 31MPCh. 29.SE - Prob. 32APCh. 29.SE - Prob. 33APCh. 29.SE - Prob. 34APCh. 29.SE - Prob. 35APCh. 29.SE - Prob. 36APCh. 29.SE - Prob. 37APCh. 29.SE - Prob. 38APCh. 29.SE - Prob. 39APCh. 29.SE - Prob. 40APCh. 29.SE - Prob. 41APCh. 29.SE - Prob. 42APCh. 29.SE - Prob. 43APCh. 29.SE - Prob. 44APCh. 29.SE - Prob. 45APCh. 29.SE - Prob. 46APCh. 29.SE - Prob. 47APCh. 29.SE - Prob. 48APCh. 29.SE - Prob. 49APCh. 29.SE - Prob. 50APCh. 29.SE - In glycerol metabolism, the oxidation of...Ch. 29.SE - Prob. 52APCh. 29.SE - Prob. 53APCh. 29.SE - Prob. 54APCh. 29.SE - In step 7 of fatty-acid biosynthesis (Figure...Ch. 29.SE - Prob. 56AP
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- The first step of the metabolic process known as glycolysis is the conversion of glucose to glucose- 6-phosphate. This process has a positive value for rG' Glucose + Pi Glucose-6-phosphate + H2O rG' = +13.8 kJ/mol-rxn This reaction is coupled to the hydrolysis of ATP ATP + H2O ADP + Pi rG' = -30.5 kJ/mol-rxn What is the sum of these two equations and the value of rG' for the coupled reaction? Is the coupled reaction product-favored at equilibrium?arrow_forwardCan a chemical that, in essence, goes through the body unchanged be an essential nutrient? Explain.arrow_forwardRefer to the following reaction. The substrate of this reaction is called through a mechanism called "Feed Forward Activation". (A) Phosphoenolpyruvate, Fructose 1,6-bisphosphate Lactate, NADH OPO₂²- ADP ATP J = 4 O H₂C H₂C 2-phosphoglycerate, AMP Glyceraldehyde 3-phosphate, ATP and the enzyme is activated by high conc. ofarrow_forward
- The image below shows the reactions of the citric acid cycle. Label the reaction types on the diagram. COO CH-OH CH₂ COO 8-5-9-8 HC H₂O NADH +H+ NAD+- FADH2 "7 FAD COO C=O CH₂ COO™ COO CH3-C-COA + H₂O acetyl-CoA COA COO™ Ī CH₂ HỌ—C—COO CH₂ COO™ COO HO-C-H COO™ COO™ CH₂ CH-COO NAD+ NAD+ + COA Attempt 2 NADH + H+ + CO2 NADH + H+ + CO2 COO™ CH₂ CH₂ C=O COO™arrow_forwardThe enzyme that catalyzes reaction below can be classified as: NAD* NADH + H* Но- H-Ć- Н—с—н H- malate dehydrogenase Oxaloacetate Malatearrow_forwardHow many moles of ATP are obtained from the catabolism of 5g of a triglyceride made of a C16 fatty acid, a C17 fatty acid, and a C24 fatty acid. Use the following molecular mass values for your calculations. H=1g/mol, C=12g/mol, O=16g/molarrow_forward
- Trypanosomes living in the bloodstream obtain all their free energy from glycolysis. They take up glucose from the host’s blood and excrete pyruvate as a waste product. In this part of their life cycle, trypanosomes do not carry out any oxidative phosphorylation, but they do use another oxygen-dependent pathway, which is absent in mammals, to oxidize NADH. Would this pathway be necessary if the trypanosome excreted lactate rather than pyruvate? Explain.arrow_forwardDetermine the number of ATP molecules that can be formed from the complete oxidation of 10 molecules of acetyl CoA. The overall net equation for the complete oxidation of acetyl CoA is provided below. Acetyl CoA + 3NAD+ + FAD + GDP + Pi + 2H₂O → 2CO2 + HS-CoA + 3NADH + 3H+ + FADH2 + GTP (Given: The oxidation of one NADH yields 2.5 ATP; the oxidation of one FADH2 yields 1.5 ATP; and one GDP yields 1 ATP.) O 10 ATP O 7,5 ATP O 100 ATP O 75 ATParrow_forwardThe rate-limiting step is a metabolic pathway is the slowest step which determines the overall rate of the other reactions in the pathway. In glycolysis, the rate limiting step is a phosphorylation reaction where phosphofructokinase (PFK-1) catalyzes the reaction fructose-6-bisphosphate -> fructose-1,6-bisphosphate, the same step in gluconeogenesis. Select one: The statement is FALSE. The statement is TRUE.arrow_forward
- Anaerobic glycolysis (i.e., lactic acid fermentation) produces pyruvate that is then converted to lactate through the activity of lactate dehydrogenase. The conversion of pyruvate to lactate would seem to be an unnecessary step, since this process does not result in any further release of energy. Explain the necessity for the production of lactate as the endpoint for anaerobic glycolysis.arrow_forwardTo learn more about the role of the electron transport chain in generating energy during respiration in this organism, you use two drugs. These drugs can each pick up electrons from specific intermediates in the pathway as shown above. You treat cells carrying out respiration with either a saturating dose of drug A or B, so that all the electrons which would normally continue along the pathway are captured by the drug in question. Complete the following table. In the presence of drug A, will the rate of ATP synthesis increase, decrease, or stay the same? Explain your reasoning. In the presence of drug B, will the rate of ATP synthesis increase, decrease, or stay the same? Explain your reasoning.arrow_forward
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