Organic Chemistry
9th Edition
ISBN: 9781305080485
Author: John E. McMurry
Publisher: Cengage Learning
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Chapter 29.SE, Problem 38AP
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A
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Chapter 29 Solutions
Organic Chemistry
Ch. 29.1 - Prob. 1PCh. 29.3 - Write the equations for the remaining passages of...Ch. 29.3 - Prob. 3PCh. 29.4 - Write a mechanism for the dehydration reaction of...Ch. 29.4 - Evidence for the role of acetate in fatty-acid...Ch. 29.4 - Does the reduction of acetoacetyl ACP in step 6...Ch. 29.5 - Prob. 7PCh. 29.5 - Look at the entire glycolysis pathway, and make a...Ch. 29.6 - Prob. 9PCh. 29.7 - Prob. 10P
Ch. 29.7 - Write mechanisms for step 2 of the citric acid...Ch. 29.7 - Prob. 12PCh. 29.8 - Prob. 13PCh. 29.9 - Write all the steps in the transamination reaction...Ch. 29.9 - What -keto acid is formed on transamination of...Ch. 29.9 - Prob. 16PCh. 29.SE - Prob. 17VCCh. 29.SE - Identify the following intermediate in the citric...Ch. 29.SE - The following compound is an intermediate in the...Ch. 29.SE - Prob. 20VCCh. 29.SE - In the pentose phosphate pathway for degrading...Ch. 29.SE - Prob. 22MPCh. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - One of the steps in the pentose phosphate pathway...Ch. 29.SE - Prob. 25MPCh. 29.SE - Prob. 26MPCh. 29.SE - Prob. 27MPCh. 29.SE - Prob. 28MPCh. 29.SE - Prob. 29MPCh. 29.SE - Prob. 30MPCh. 29.SE - Prob. 31MPCh. 29.SE - Prob. 32APCh. 29.SE - Prob. 33APCh. 29.SE - Prob. 34APCh. 29.SE - Prob. 35APCh. 29.SE - Prob. 36APCh. 29.SE - Prob. 37APCh. 29.SE - Prob. 38APCh. 29.SE - Prob. 39APCh. 29.SE - Prob. 40APCh. 29.SE - Prob. 41APCh. 29.SE - Prob. 42APCh. 29.SE - Prob. 43APCh. 29.SE - Prob. 44APCh. 29.SE - Prob. 45APCh. 29.SE - Prob. 46APCh. 29.SE - Prob. 47APCh. 29.SE - Prob. 48APCh. 29.SE - Prob. 49APCh. 29.SE - Prob. 50APCh. 29.SE - In glycerol metabolism, the oxidation of...Ch. 29.SE - Prob. 52APCh. 29.SE - Prob. 53APCh. 29.SE - Prob. 54APCh. 29.SE - In step 7 of fatty-acid biosynthesis (Figure...Ch. 29.SE - Prob. 56AP
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- The first step of the metabolic process known as glycolysis is the conversion of glucose to glucose- 6-phosphate. This process has a positive value for rG' Glucose + Pi Glucose-6-phosphate + H2O rG' = +13.8 kJ/mol-rxn This reaction is coupled to the hydrolysis of ATP ATP + H2O ADP + Pi rG' = -30.5 kJ/mol-rxn What is the sum of these two equations and the value of rG' for the coupled reaction? Is the coupled reaction product-favored at equilibrium?arrow_forwardExplain why monitoring blood lactate levels might be a useful technique to gauge the amount of conditioning in an Olympic runner.arrow_forwardWhy are so many different enzymes needed?arrow_forward
- 17. In the urea cycle, ions are converted to urea. Da. pynuvate Ob. sodium Oc, ammonium Od. glutamate 18. Amino acids that are degraded into are termed ketogenic. Oa. a-ketoglutarate b. oxaloacetate Oc. fumarate Od. acetyl CoA 19. When 100 mg of a substance are required daily by the body, the substance would be classified as a a. micronutrient Ob. macronutrient C. nonessential nutrient d. more than one choice is correct 20. What role do most of the water-soluble vitamins have in the body? ca. catalysis b. hormone precursors Oc. components of cell membranes d. coenzymesarrow_forwardWhich of the following substances can be considered as metabolic intermediates? Water ATP Pyruvic acid Glucosearrow_forwardThe number of ATP molecules consumed and produced during glycolysis under anaerobic conditions are summarized in the following diagram (the ATP hydrolysis and synthesis reactions are shown in green). Phosphate Carbon atom 2 ATP 2 ADP ●●●●●● Glucose I Energy-Investing Phase O 2 ATP O 6 ATP O 1 ATP 8 ATP NADH + NAD* +H* O 4 ATP ●●●● 2 ADP 2 ATP NADH + NAD +H Based on the diagram above, for each glucose molecule broken down, what is the net energy yield of glycolysis in terms of ATP under anaerobic conditions? Pyruvate 2 ADP 2 ATP ●●●●● Energy-Generating Phase Pyruvatearrow_forward
- For a given acid HA, it was determined that at pH 6.0 the concentration of the conjugate base [A] was 0.075 M and the acid [HA] was 0.025 M. What percent of this acid is ionized at pH 6.0? What is the pKa of this acid? What pH would this acid be 50% lonized?arrow_forwardATP is produced during synthesis of compounds. O True O Falsearrow_forwardH 'Н H LDA H₂Oarrow_forward
- - Part A When blood glucose levels rise following a meal, the events listed below occur. Arrange these events in the appropriate sequence. Arrange the events from earliest to latest. Reset Help Glycogen synthesis Glycolysis replenishes ATP supplies. (glycogenesis) occurs with excess Blood levels pass through normal to below normal Glucose is absorbed by cells. Glucagon is secreted. Insulin levels rise. glucose. (hypoglycemic). The liver releases glucose into the bloodstream. earliest latestarrow_forwardWhat are coupled reactions? How do they help in chemical reactions in living organisms?arrow_forwardThe transfer or removal of an amino group (transamination/oxidative deamination) from an amino acid leads to an a-keto acid that constitutes a metabolic pathway intermediate, for example, an intermediate of the citric acid cycle. Which citric acid cycle intermediate is provided by the transamination or oxidative deamination of glutamate, as illustrated below? COO™ + I CH-NH3 I CH₂ I CH₂ | COO™ Glutamate Transamination COO™ _i_€ ? Metabolic pathway intermediate COO™ Oxaloacetatearrow_forward
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