Concept explainers
(a)
Interpretation:
Whether the given name describes a single stereoisomer unambiguously is to be determined and the name using R and S designations for the chiral centers is to be written if the name describes a single stereoisomer.
Concept introduction:
For disubstituted cycloalkanes, cis isomers are the ones in which the two substituents lie on the same side of the ring, while trans isomers are the ones in which they lie on the opposite side of the ring.
A stereocenter is an atom with the property in that interchanging any two of its attached groups produces a different stereoisomer. A tetrahedral stereocenter is called a chiral center when it is bonded to four different groups. The four substituents attached to the chiral center are prioritized according to their
Each stereoisomer is described by a single name. For more than one stereoisomers, more than one names are written.
If there are two or more distinct structures possible for a given single name, then it suggests that the given name does not describe a single stereoisomer unambiguously.
If there is only one structure possible for a given single name, then it suggests that the given name describes a single stereoisomer unambiguously.
(b)
Interpretation:
Whether the given name describes a single stereoisomer unambiguously is to be determined and the name using R and S designations for the chiral centers is to be written if the name describes a single stereoisomer.
Concept introduction:
For disubstituted cycloalkanes, cis isomers are the ones in which the two substituents lie on the same side of the ring, while trans isomers are the ones in which they lie on the opposite side of the ring.
A stereocenter is an atom with the property in that interchanging any two of its attached groups produces a different stereoisomer. A tetrahedral stereocenter is called a chiral center when it is bonded to four different groups. The four substituents attached to the chiral center are prioritized according to their atomic numbers. The substituent atom having the greater atomic number has higher priority. When writing the IPUAC name, the R or S designation is written in parenthesis for each asymmetric carbon atom, and hyphens are used to separate those designations from the rest of the IUPAC name.
Each stereoisomer is described by a single name. For more than one stereoisomers, more than one names are written.
If there are two or more distinct structures possible for a given single name, then it suggests that the given name does not describe a single stereoisomer unambiguously.
If there is only one structure possible for a given single name, then it suggests that the given name describes a single stereoisomer unambiguously.
(c)
Interpretation:
Whether the given name describes a single stereoisomer unambiguously is to be determined and the name using R and S designations for the chiral centers is to be written if the name describes a single stereoisomer.
Concept introduction:
For disubstituted cycloalkanes, cis isomers are the ones in which the two substituents lie on the same side of the ring, while trans isomers are the ones in which they lie on the opposite side of the ring.
A stereocenter is an atom with the property in that interchanging any two of its attached groups produces a different stereoisomer. A tetrahedral stereocenter is called a chiral center when it is bonded to four different groups. The four substituents attached to the chiral center are prioritized according to their atomic numbers. The substituent atom having the greater atomic number has higher priority. When writing the IPUAC name, the R or S designation is written in parenthesis for each asymmetric carbon atom, and hyphens are used to separate those designations from the rest of the IUPAC name.
Each stereoisomer is described by a single name. For more than one stereoisomers, more than one names are written.
If there are two or more distinct structures possible for a given single name, then it suggests that the given name does not describe a single stereoisomer unambiguously.
If there is only one structure possible for a given single name, then it suggests that the given name describes a single stereoisomer unambiguously.
(d)
Interpretation:
Whether the given name describes a single stereoisomer unambiguously is to be determined and the name using R and S designations for the chiral centers is to be written if the name describes a single stereoisomer.
Concept introduction:
Whether the given name describes a single stereoisomer unambiguously is to be determined and the name using R and S designations for the chiral centers is to be written if the name describes a single stereoisomer.
Concept introduction:
For disubstituted cycloalkanes, cis isomers are the ones in which the two substituents lie on the same side of the ring, while trans isomers are the ones in which they lie on the opposite side of the ring.
A stereocenter is an atom with the property in that interchanging any two of its attached groups produces a different stereoisomer. A tetrahedral stereocenter is called a chiral center, when it is bonded to four different groups. The four substituents attached to the chiral center are prioritized according to their atomic numbers. The substituent atom having the greater atomic number has the higher priority. When writing the IPUAC name, the R or S designation is written in parenthesis for each asymmetric carbon atom, and hyphens are used to separate those designations from the rest of the IUPAC name.
Each stereoisomer is described by a single name. For more than one stereoisomers, more than one names are written.
If there are two or more distinct structures possible for a given single name, then it suggests that the given name does not describe a single stereoisomer unambiguously.
If there is only one structure possible for a given single name, then it suggests that the given name describes a single stereoisomer unambiguously.
(e)
Interpretation:
Whether the given name describes a single stereoisomer unambiguously is to be determined and the name using R and S designations for the chiral centers is to be written if the name describes a single stereoisomer.
Concept introduction:
Whether the given name describes a single stereoisomer unambiguously is to be determined and the name using R and S designations for the chiral centers is to be written if the name describes a single stereoisomer.
Concept introduction:
For disubstituted cycloalkanes, cis isomers are the ones in which the two substituents lie on the same side of the ring, while trans isomers are the ones in which they lie on the opposite side of the ring.
A stereocenter is an atom with the property in that interchanging any two of its attached groups produces a different stereoisomer. A tetrahedral stereocenter is called a chiral center when it is bonded to four different groups. The four substituents attached to the chiral center are prioritized according to their atomic numbers. The substituent atom having the greater atomic number has the higher priority. When writing the IPUAC name, the R or S designation is written in parenthesis for each asymmetric carbon atom and hyphens are used to separate those designations from the rest of the IUPAC name.
Each stereoisomer is described by a single name. For more than one stereoisomers, more than one names are written.
If there are two or more distinct structures possible for a given single name, then it suggests that the given name does not describe a single stereoisomer unambiguously.
If there is only one structure possible for a given single name, then it suggests that the given name describes a single stereoisomer unambiguously.
Want to see the full answer?
Check out a sample textbook solutionChapter C Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
- Draw the stereoisomers for the following molecules listed below. Be sure to label all chiral centers as R or S and define the relationship between all pairs of stereoisomers for each molecule set A) 1,4-dimethylcyclohexane B) 1,3-cyclohexanediol C) 1,3-dimethylcyclopentanearrow_forwardIDENTIFY THE CONFIGURATION OF EACH CHIRAL CENTER IN THE FOLLOWING COMPOUNDS.arrow_forwardUsing only C, H, and O, write structural formulas for the lowest-molecular-weight chiral. Q) Alkanearrow_forward
- Identify the configuration of each chiral center in the following compounds. Draw the enantiomer for each of the following compoundsarrow_forwardShown below is Streptomycin, an antibiotic medication used to treat a number of bacterial infections, including tuberculosis, plague, and endocarditis. Neomycin B has broad-spectrum antibacterial activity. Circle and label as many functional groups in these molecules as you can. Label each chiral carbon in Streptomycin. How many total stereoisomers exist for Streptomycin? Label each chiral carbon in Neomycin B. How many total stereoisomers exist for Neomycin B?arrow_forwardAssign the configuration of each chiral center in the following compound. (Note: In this compound, locants are assigned starting at the top, with the carbon atom of the -CHO group.) CHO H-OH HO-H но- HO-H H- OH CH₂OH 2R,3R,4R,5R None of the choices are correct. 2R,3S,4S,5R 2S,3S,4S,5S 2S,3R,4R,5S Save for Later Submit Answerarrow_forward
- OH 1. Consider this compound: CH;CH2CHCH,CHCH2CH3 ČH3 a) How many chiral carbons does this compound have? b) What is the maximum number of stereoisomers that could exist for this compound? Show how you arrived at your answer.arrow_forward4. Which of the following statements is a correct description of the most stable chair conformation of 1,1,3-trimethylcyclohexane? Show structures to explain your answer a) The methyl group at C-3 is equatorial. b) C-1 is a tertiary carbon and C-3 is a primary carbon. c) C-1 is a quaternary carbon and C-3 is a secondary carbon. d) C-1 is a tertiary carbon and C-3 is a secondary carbon. e) Both methyl groups at C-1 are equatorial.arrow_forward2. The number of possible stereoisomers can be determined by the equation 2" where n = number of asymmetric centers. For the following molecule, what is the possible number of stereoisomers? Draw out all possible stereoisomers. Are there structures that are identical to each other? CH3 ноarrow_forward
- There is one or more chiral carbon(s) in: a) 2,3-dibromopentane b) 1-bromo-1-chloropentane c) 1-bromo-5-chloropentane d) 2,2-dibromopentane O all of them O a) and d) O a), b), and C O a) and b) O a) O d) O b)arrow_forwardDraw a structural formula of the S configuration of the compound shown below. • Use the wedge /hash bond tools to indicate stereochemistry where it exists. Include H atoms at chiral centers only. • Ifa group is achiral, do not use wedged or hashed bonds on it. CH3 CH3 CH;CHCHCN CH,CH,CH,CHCH,CH, CH2NH2 Draw a structural formula of the RS configuration of the compound shown below. Use the wedge /hash bond tools to indicate stereochemistry where it exists. • Include H atoms at chiral centers only. If a group is achiral, do not use wedged or hashed bonds on it. ÇIarrow_forwardDraw the molecule in the box below that has the IUPAC name, S-3-chloro-2-methylhexane (You have three chances until the answer will be given; you have already tried 0 times) Draw only one molecule in each drawing box. Video to aid you in drawing a chiral carbon Compound #1arrow_forward
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co