Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Question
Chapter 9, Problem 9.19QAP
Interpretation Introduction
Interpretation:
The physical effects and interferences that the method of standard additions would correct or compensate for in AAS should be described.
Concept introduction:
Standard addition is a method which is referred to as the technique of quantitative analysis to lower the effects of the matrix interfering in the signals of analyte measurement. Interference is a type of phenomenon which leads to fluctuations in the intensity of the signals of analyte measurements in spectroscopy.
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Chapter 9 Solutions
Principles of Instrumental Analysis
Ch. 9 - Prob. 9.1QAPCh. 9 - Prob. 9.2QAPCh. 9 - Why is an electrothermal atomizer more sensitive...Ch. 9 - Prob. 9.4QAPCh. 9 - Prob. 9.5QAPCh. 9 - Prob. 9.6QAPCh. 9 - Prob. 9.7QAPCh. 9 - Prob. 9.8QAPCh. 9 - Prob. 9.9QAPCh. 9 - Prob. 9.10QAP
Ch. 9 - Prob. 9.11QAPCh. 9 - Prob. 9.12QAPCh. 9 - Prob. 9.13QAPCh. 9 - Prob. 9.14QAPCh. 9 - Prob. 9.15QAPCh. 9 - Prob. 9.16QAPCh. 9 - Prob. 9.17QAPCh. 9 - In the concentration range of 1 to 100 g/mL P,...Ch. 9 - Prob. 9.19QAPCh. 9 - Prob. 9.20QAPCh. 9 - Prob. 9.21QAPCh. 9 - The chromium in an aqueous sample was determined...Ch. 9 - Prob. 9.23QAP
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- Instrumentation of IR spectroscopy? Please answer at your own words.arrow_forwardExactly 5.00 mL aliquots of a solution containing analyte X were transferred into 50.00-mL volumetric flasks and the pH of the solution is adjusted to 9.0. The following volumes of a standard solution containing 2.00 µg/mL of X were then added into each flask and the mixture was diluted to volume: 0.000, 0.500, 1.00, 1.50 and 2.00 mL. The fluorescence of each of these solutions was measured with a fluorometer, and the following values were obtained: 3.26, 4.80, 6.42, 8.02 and 9.56, respectively. ii. Using relevant functions in Excel, derive a least-squares equation for the data, and use the parameters of this equation to find the concentration of the phenobarbital in the unknown solution.arrow_forwardCalculate the molarity of KMnO4 stock solution X used for the analysis. Plot a graph of absorbance A vs. wavelength λ and determine the λ max (maximum wavelength).arrow_forward
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- 1. State the difference between transmittance, absorbance, molar absorptivity, and fluorescence. Which one(s) is proportional to analyte concentration?arrow_forwardHow do I solve for [FeSCN2+] heres the formula they provided me and my data but I would like steps on how to solve it and what data I should be using to solve for it u can use any fake numbers you need to help me understand ! I'm confused only by the absorbance part , what number am I using for the absorbance? Is it Fe3+ added to ScN- absorbance values ? also e = 202 and L = 1.0arrow_forwardDerive an expression relating absorbance to the concentrations of standard and unknown ( c subscript s and c subscript x) and the volumes of the standards and unknown ( V subscript s and V subscript x ) as well as the volume to which the solutions were diluted (V subscript t). Derive expressions for the slope and the intercept of the straight line obtained in (a) in terms of the variables listed above.arrow_forward
- Provide an explanation of the effects which are responsible for the three absorbances profile in relation to the height of the burner. Figure below shows the absorbance profile of the three elements.arrow_forward6 Why standard solutions are used in Atomic absorption Spectroscopy (AAS) whereas UV-Vis molecular absorbance only extinction coefficient is necessary?arrow_forward
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