Principles of Instrumental Analysis
Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 9, Problem 9.6QAP
Interpretation Introduction

Interpretation:

The reason for the 30% more absorption for a solution containing 50% ethanol than the solution containing no ethanol needs to be explained, if both the solution contains the same amount of nickel.

Concept introduction:

Spectral lines are lines which help identify atoms and molecules. These are a result of absorption or emission of light in a comparatively narrower frequency range compared to the frequencies nearby.

In a defined space, the amount of a substance gives its concentration. The capacity of a substance to absorb a specific wavelength of light gives its absorbance.

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Solve the problems using a step-by-step process (solutions). 1. Solutions of fluorene (diphenylmethane) in benzene can be analyzed by making use of its absorbance at 301 nm wavelength. If a solution of fluorene of unknown concentration in benzene exhibits an absorbance of 0.720 in a 1.00-cm cuvette cell. What is the concentration of fluorene? (Ans. c = 6.55 x10-5 M)
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Solve the problems using a step-by-step process (solutions). 1. Solutions of fluorene (diphenylmethane) in benzene can be analyzed by making use of its absorbance at 301 nm wavelength. If a solution of fluorene of unknown concentration in benzene exhibits an absorbance of 0.720 in a 1.00-cm cuvette cell. What is the concentration of fluorene? (Ans. c = 6.55 x10-5 M)     2. If, with a beam of monochromatic light, 65.0% of the incident light is absorbed in its passage through a column of a certain colored solution, what is the absorbance of the solution? (Ans. A = 0.456)     3. A 1.0x10-3 M solution of a dye X shows an absorbance of 0.20 at 450 nm wavelength and an absorbance of 0.05 at 620 nm wavelength. Calculate the extinction coefficient for each wavelength. (Ans. e450 = 200 ; e620 = 50)
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