Physical Universe
Physical Universe
16th Edition
ISBN: 9780077862619
Author: KRAUSKOPF, Konrad B. (konrad Bates), Beiser, Arthur
Publisher: Mcgraw-hill Education,
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Chapter 9, Problem 59E
To determine

Give reason for spherical symmetry of s orbital and check whether its probability density varies in direction.

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Discuss in detail (in words only) the Radial Wave Functions in Quantum Mechanics.
What is the smallest value that ℓ may have if L is within 10° of the z axis?
4. (a) Using ɛn = 2ML2 (n² + n3 + n²), show that the partition function of a massive particle (M) in a 3-dimensional box (V = L³) is given by Z, = ngV, where the quantum concentration is no = (Mt/2nh²)³/2 ; you may need e-a?x² dx = \T/2a. (b) Now the partition function for non-interacting N such particles is given by ZN = ZN/N!. Explain why. (f) Find the inter-particle spacing Ap at n = ng and argue that Ap~ħ/p, i. e. 2p is on the order of the thermal de Broglie wavelength, where p is the thermal average momentum.

Chapter 9 Solutions

Physical Universe

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