Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 8, Problem 8.50E
What is the solubility product constant of
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Chapter 8 Solutions
Physical Chemistry
Ch. 8 - 8.1. What is the charge on a small sphere that is...Ch. 8 - 8.2. The force of attraction due to gravity...Ch. 8 - 8.3. Two small metallic bodies are given opposite...Ch. 8 - Prob. 8.4ECh. 8 - What is the force of attraction between a...Ch. 8 - Prob. 8.6ECh. 8 - 8.7. How much work is required to move a single...Ch. 8 - 8.8. Explain why an electromotive force is not, in...Ch. 8 - Prob. 8.9ECh. 8 - For each of the following reactions, determine the...
Ch. 8 - Prob. 8.11ECh. 8 - Prob. 8.12ECh. 8 - 8.13. Is the disproportionation reaction...Ch. 8 - Prob. 8.14ECh. 8 - Prob. 8.15ECh. 8 - Prob. 8.16ECh. 8 - Prob. 8.17ECh. 8 - 8.18. Determine and for each of the following...Ch. 8 - Prob. 8.19ECh. 8 - Prob. 8.20ECh. 8 - Prob. 8.21ECh. 8 - Prob. 8.22ECh. 8 - Prob. 8.23ECh. 8 - Prob. 8.24ECh. 8 - Prob. 8.25ECh. 8 - Prob. 8.26ECh. 8 - Prob. 8.27ECh. 8 - What is the Zn2+:Cu2+ ratio on a Daniell cell that...Ch. 8 - Prob. 8.29ECh. 8 - Determine the voltage of this reaction with the...Ch. 8 - The thermite reaction can act as the basis of an...Ch. 8 - A concentration cell has different concentrations...Ch. 8 - Prob. 8.34ECh. 8 - Prob. 8.35ECh. 8 - a What is the equilibrium constant for the...Ch. 8 - Prob. 8.37ECh. 8 - Prob. 8.38ECh. 8 - Prob. 8.39ECh. 8 - Prob. 8.40ECh. 8 - Prob. 8.41ECh. 8 - Consider the following formation reaction for HI:...Ch. 8 - Prob. 8.43ECh. 8 - 8.44. Determine an expression for , the change in...Ch. 8 - Prob. 8.45ECh. 8 - Prob. 8.46ECh. 8 - Determine the equilibrium constant for the...Ch. 8 - Prob. 8.48ECh. 8 - Prob. 8.49ECh. 8 - What is the solubility product constant of Hg2Cl2,...Ch. 8 - Prob. 8.51ECh. 8 - Prob. 8.52ECh. 8 - Prob. 8.53ECh. 8 - Prob. 8.54ECh. 8 - Prob. 8.55ECh. 8 - Prob. 8.56ECh. 8 - Prob. 8.57ECh. 8 - Show that a can be written as n+mnn+n+nn, where m...Ch. 8 - Prob. 8.59ECh. 8 - Prob. 8.60ECh. 8 - What molality of NaCl is necessary to have the...Ch. 8 - Prob. 8.62ECh. 8 - Prob. 8.63ECh. 8 - Calculate the molar enthalpy of formation of I(aq)...Ch. 8 - Prob. 8.65ECh. 8 - Hydrofluoric acid, HF(aq), is a weak acid that is...Ch. 8 - Prob. 8.68ECh. 8 - Prob. 8.69ECh. 8 - Prob. 8.70ECh. 8 - Prob. 8.71ECh. 8 - Prob. 8.72ECh. 8 - The mean activity coefficient for an aqueous...Ch. 8 - Human blood plasma is approximately 0.9NaCl. What...Ch. 8 - Under what conditions does the extended...Ch. 8 - Prob. 8.76ECh. 8 - Approximate the expected voltage for the following...Ch. 8 - Prob. 8.78ECh. 8 - Prob. 8.79ECh. 8 - Prob. 8.80ECh. 8 - a The salt NaNO3 can be thought of as...Ch. 8 - Prob. 8.82ECh. 8 - What is the estimated velocity for Cu2+ ions...Ch. 8 - Prob. 8.84ECh. 8 - Prob. 8.85ECh. 8 - Prob. 8.86ECh. 8 - Calculate a the solubility product constant for...
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- You are given four different aqueous solutions and told that they each contain NaOH, Na2CO3, NaHCO3, or a mixture of these solutes. You do some experiments and gather these data about the samples. Sample A: Phenolphthalein is colorless in the solution. Sample B: The sample was titrated with HCl until the pink color of phenolphthalein disappeared, then methyl orange was added. The solution became pink. Methyl orange changes color from pH 3.01 (red) to pH 4.4 (orange). Sample C: Equal volumes of the sample were titrated with standardized acid. Using phenolphthalein as an indicator required 15.26 mL of standardized acid to change the phenolphthalein color. The other sample required 17.90 mL for a color change using methyl orange as the indicator. Sample D: Two equal volumes of the sample were titrated with standardized HCl. Using phenolphthalein as the indicator, it took 15.00 mL of acid to reach the equivalence point; using methyl orange as the indicator required 30.00 mL HCl to achieve neutralization. Identify the solute in each of the solutions.arrow_forwardWhat must be the concentration of chromate ion in order to precipitate strontium chromate, SrCrO4, from a solution that is 0.0034 M Sr2+?arrow_forwardEach pair of ions below is found together in aqueous solution. Using the table of solubility product constants in Appendix J, devise a way to separate these ions by adding a reagent to precipitate one of the ions as an insoluble salt and leave the other in solution. (a) Cu2+ and Ag+ (b) A13+ and Fe3+arrow_forward
- Calculate the solubility in grams per 100 mL of BaF2 in a 0.10 M BaCl2 solution.arrow_forwardThe Handbook of Chemistry and Physics (http://openstaxcollege.org/l/16Handbook) gives solubilities of the following compounds in grams per 100 mL of water. Because these compounds are only slightly soluble, assume that the volume does not change on dissolution and calculate the solubility product for each. (a) BaSiF6, 0.026 g/100 mL (contains SiF62- ions) (b) Ce(IO3)4, 1.5102 g/100 mL (c) Gd2(SO4)3, 3.98 g/100 mL (d) (NH4)2PtBr6, 0.59 g/100 mL (contains PtBr62- ions)arrow_forwardA solution is 1.5 104 M Zn2 and 0.20 M HSO4. The solution also contains Na2SO4. What should be the minimum molarity of Na2SO4 to prevent the precipitation of zinc sulfide when the solution is saturated with hydrogen sulfide (0.10 M H2S)?arrow_forward
- According to the Resource Conservation and Recovery Act (RCRA), waste material is classified as toxic and must be handled as hazardous if the lead concentration exceeds 5 mg/L. By adding chloride ion, the lead ion will precipitate as PbCl2, which can be separated from the liquid portion. Once the lead has been removed, the rest of the waste can be sent to a conventional waste treatment facility. How many grams of sodium chloride must be added to 500 L of a waste solution to reduce the concentration of the Pb2+ ion from 10 to 5 mg/L?arrow_forwardA solution contains Ca2+ and Pb2+ ions, both at a concentration of 0.010 M. You wish to separate the two ions from each other as completely as possible by precipitating one but not the other using aqueous Na2SO4 as the precipitating agent. (a) Which will precipitate first as sodium sulfate is added, CaSO4 or PbSO4? (b) What will be the concentration of the first ion that precipitates (Ca2+ or Pb2+) when the second, more soluble salt begins to precipitate?arrow_forwardUse the solubility rules (Table 4.1) to decide which of the following compounds are expected to be soluble and which insoluble. a AgBr b Ca(NO3)2 c MgI2 d PbSO4arrow_forward
- The text describes zinc hydroxide as an amphoteric hydroxide, so Zn(OH)2 is soluble in basic solution. What is the molar solubility of Zn(OH)2 in 1.00 M NaOH? What is the pH of the equilibrium solution?arrow_forwardConsider the reaction BaF2(s)+SO42(aq)BaSO4(s)+2 F(aq) (a) Calculate K for the reaction. (b) Will BaSO4 precipitate if Na2SO4 is added to a saturated solution of BaF2?arrow_forward
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