The structure of the chloroalkane (compound A) with the general formula must be drawn which gives trans 2-butene on treatment with sodium methoxide. Concept Introduction : Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

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Answer 1

Question

Chapter 7.9, Problem 30ATS

(a)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound A) with the general formula must be drawn which gives trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

(b)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound B) with the general formula C₄H₉Cl must be drawn which gives different disubstituted alkene other than trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

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Devise a synthesis of each alkene using a Wittig reaction to form the double bond. You may use benzene and organic alcohols having four or fewer carbons as starting materials and any required reagents. a. CH,CH2CH2CH=CHCH3 b. GgH;CH=CHCH2CH¿CH3 c. (CHa2C=CHCH(CH)2

Draw the constitutional isomer formed when the following alkenes are treated with each set of reagents: [1] H20, H,SO,; or [2] BH3 followed by H2O2, "OH. a. b. c.

a) What is the major alkene formed when A is dehydrated with H2SO4? (b) What is the major alkene formed when A is treated with POCl3 and pyridine? Explain why the major product is different in these reactions.

Answer 2

Question

Chapter 7.9, Problem 30ATS

(a)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound A) with the general formula must be drawn which gives trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

(b)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound B) with the general formula C₄H₉Cl must be drawn which gives different disubstituted alkene other than trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

Expert Solution & Answer

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Answer 3

Question

Chapter 7.9, Problem 30ATS

(a)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound A) with the general formula must be drawn which gives trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

(b)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound B) with the general formula C₄H₉Cl must be drawn which gives different disubstituted alkene other than trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

Expert Solution & Answer

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See solution

Answer 4

Question

Chapter 7.9, Problem 30ATS

(a)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound A) with the general formula must be drawn which gives trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

(b)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound B) with the general formula C₄H₉Cl must be drawn which gives different disubstituted alkene other than trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

Expert Solution & Answer

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Answer 5

Chapter 7.9, Problem 30ATS

(a)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound A) with the general formula must be drawn which gives trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

(b)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound B) with the general formula C₄H₉Cl must be drawn which gives different disubstituted alkene other than trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

Answer 6

Chapter 7.9, Problem 30ATS

(a)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound A) with the general formula must be drawn which gives trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

Answer 7

Chapter 7.9, Problem 30ATS

(a)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound A) with the general formula must be drawn which gives trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound B) with the general formula C₄H₉Cl must be drawn which gives different disubstituted alkene other than trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structure of the chloroalkane (compound B) with the general formula C₄H₉Cl must be drawn which gives different disubstituted alkene other than trans 2-butene on treatment with sodium methoxide.

Concept Introduction :

Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

Answer 10

Expert Solution & Answer

Answer 11

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Answer 12

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Answer 13

Ch. 7.2 - Prob. 1CC Ch. 7.3 - Prob. 2CC Ch. 7.3 - Prob. 1LTS Ch. 7.3 - Prob. 3PTS Ch. 7.3 - Prob. 4ATS Ch. 7.3 - Prob. 2LTS Ch. 7.3 - Prob. 5PTS Ch. 7.3 - Prob. 6ATS Ch. 7.3 - Prob. 7CC Ch. 7.4 - Prob. 8CC

The structure of the chloroalkane (compound A) with the general formula must be drawn which gives trans 2-butene on treatment with sodium methoxide. Concept Introduction : Chloroalkane undergoes an E2 reaction with sodium methoxide. More substituted alkane is the major (Saytzef) product.

Solution Summary: The author explains the structure of the chloroalkane (compound A) with the general formula must be drawn which gives trans 2-butene on treatment with sodium methoxide.

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