(a) Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity. Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high p K a value.

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Answer 1

Question

Chapter 7.8, Problem 16P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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Rank the nucleophiles in each group in order of increasing nucleophilicity. а. "ОН, NH, Ha0 b. "OH, Br", F (polar aprotic solvent) c. H20, "OH, CHC0O

Identify the stronger nucleophile in each pair. a. NH3,−NH2 b. CH3NH2, CH3OH c. CH3CO2−, CH3CH2O−

Identify the stronger nucleophile in each pair. a.NH3, −NH2 b.CH3NH2, CH3OH c.CH3CO2−, CH3CH2O−

Answer 2

Question

Chapter 7.8, Problem 16P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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Answer 3

Question

Chapter 7.8, Problem 16P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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Answer 4

Question

Chapter 7.8, Problem 16P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

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Answer 5

Chapter 7.8, Problem 16P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 6

Chapter 7.8, Problem 16P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 7

Chapter 7.8, Problem 16P

Interpretation Introduction

(a)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 8

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 9

Interpretation Introduction

(b)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 10

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 11

Interpretation Introduction

(c)

Interpretation: The given nucleophiles are to be arranged in order of increasing nucleophilicity.

Concept introduction: The electron rich chemical species that contains negative charge or lone pair of electrons are known as nucleophile. The strong nucleophile is strong base whose conjugate acid has high pKa value.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 7.1 - Problem 7.1 Telfairine, a naturally occurring...Ch. 7.2 - Give the IUPAC name for each compound. a. b. c. d.Ch. 7.2 - Prob. 3P Ch. 7.3 - An sp3 hybridized CCl bond is more polar than an...Ch. 7.4 - Prob. 5P Ch. 7.6 - Prob. 6P Ch. 7.7 - Prob. 10P Ch. 7.8 - Prob. 15P Ch. 7.8 - Prob. 16P Ch. 7.8 - Prob. 17P

Solution Summary: The author explains that the nucleophilicity of a group depends upon its basicity.

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