Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 7.2, Problem 6P

(a)

Interpretation Introduction

Interpretation:

The systematic name of the given compound should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

  • The first step is to find out the parent chain of the hydrocarbon.  Parent chain should contain maximum number of multiple bonds, maximum number of substituents of the functional group which is used as main suffix.
  • Other functional group, if any, should be identified and name it as prefix.
  • Numbering should be done in such a way that to get the lowest number for suffix functional group, multiple bonds.
  • The punctuation used to separate numbers is commas and hyphen is used to separate a number and alphabet.
  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond.  Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number.  In the case of more than one substituent, alphabetical order should be followed.

(b)

Interpretation Introduction

Interpretation:

The systematic name of the given compound should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

  • The first step is to find out the parent chain of the hydrocarbon. Parent chain should contain maximum number of multiple bonds, maximum number of substituents of the functional group which is used as main suffix.
  • Other functional group, if any, should be identified and name it as prefix.
  • Numbering should be done in such a way that to get the lowest number for suffix functional group, multiple bonds.
  • The punctuation used to separate numbers is commas and hyphen is used to separate a number and alphabet.
  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond.  Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number.  In the case of more than one substituent, alphabetical order should be followed.

(c)

Interpretation Introduction

Interpretation:

The systematic name of the given compound should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

  • The first step is to find out the parent chain of the hydrocarbon. Parent chain should contain maximum number of multiple bonds, maximum number of substituents of the functional group which is used as main suffix.
  • Other functional group, if any, should be identified and name it as prefix.
  • Numbering should be done in such a way that to get the lowest number for suffix functional group, multiple bonds.
  • The punctuation used to separate numbers is commas and hyphen is used to separate a number and alphabet.
  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond.  Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number.  In the case of more than one substituent, alphabetical order should be followed.

(d)

Interpretation Introduction

Interpretation:

The systematic name of the given compound should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

  • The first step is to find out the parent chain of the hydrocarbon. Parent chain should contain maximum number of multiple bonds, maximum number of substituents of the functional group which is used as main suffix.
  • Other functional group, if any, should be identified and name it as prefix.
  • Numbering should be done in such a way that to get the lowest number for suffix functional group, multiple bonds.
  • The punctuation used to separate numbers is commas and hyphen is used to separate a number and alphabet.
  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond.  Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number.  In the case of more than one substituent, alphabetical order should be followed.

(e)

Interpretation Introduction

Interpretation:

The systematic name of the given compound should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

  • The first step is to find out the parent chain of the hydrocarbon. Parent chain should contain maximum number of multiple bonds, maximum number of substituents of the functional group which is used as main suffix.
  • Other functional group, if any, should be identified and name it as prefix.
  • Numbering should be done in such a way that to get the lowest number for suffix functional group, multiple bonds.
  • The punctuation used to separate numbers is commas and hyphen is used to separate a number and alphabet.
  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond.  Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number.  In the case of more than one substituent, alphabetical order should be followed.

(f)

Interpretation Introduction

Interpretation:

The systematic name of the given compound should be identified.

Concept Introduction:

IUPAC NOMENCLATURE RULES:

  • The first step is to find out the parent chain of the hydrocarbon. Parent chain should contain maximum number of multiple bonds, maximum number of substituents of the functional group which is used as main suffix.
  • Other functional group, if any, should be identified and name it as prefix.
  • Numbering should be done in such a way that to get the lowest number for suffix functional group, multiple bonds.
  • The punctuation used to separate numbers is commas and hyphen is used to separate a number and alphabet.
  • If the ‘ane’ ending of the alkane is replaced by ‘yne’ ending, the name of alkyne is obtained.
  • Select the longest chain which contain the triple bond in such a way to get lowest value for the functional group.
  • Two types of alkynes will be there according to the position of triple bond.  Terminal alkyne is the one which contain triple bond at the end of the chain and internal alkyne is the one which contain triple bond not at the end but present in any other positions in the chain.
  • When the counting is done from either sides of triple bond in a compound which contain same number for the functional group suffix, the correct name will be the one which have lowest substituent number.  In the case of more than one substituent, alphabetical order should be followed.

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Chapter 7 Solutions

Organic Chemistry

Ch. 7.6 - Prob. 12PCh. 7.6 - Prob. 13PCh. 7.7 - Prob. 14PCh. 7.7 - Which alkyne should be used for the synthesis of...Ch. 7.7 - Prob. 16PCh. 7.8 - Prob. 17PCh. 7.8 - Only one alkyne forms an aldehyde when it...Ch. 7.9 - Describe the alkyne you should start with and the...Ch. 7.9 - Prob. 20PCh. 7.10 - Prob. 21PCh. 7.10 - Prob. 22PCh. 7.10 - Rank the following from strongest base to weakest...Ch. 7.12 - Prob. 26PCh. 7 - What is the major product obtained from the...Ch. 7 - Draw a condensed structure for each of the...Ch. 7 - A student was given the structural formula of...Ch. 7 - Prob. 30PCh. 7 - What is each compounds systematic name?Ch. 7 - What reagents should be used to carry out the...Ch. 7 - Prob. 33PCh. 7 - Prob. 34PCh. 7 - Prob. 35PCh. 7 - Prob. 36PCh. 7 - What is the major product of the reaction of 1 mol...Ch. 7 - What is each compounds systematic name? a....Ch. 7 - What is the molecular formula of a hydrocarbon...Ch. 7 - Answer Problem 39, parts a-b, using 2-butyne as...Ch. 7 - Prob. 41PCh. 7 - a. Starting with 3-methyl 1-butyne, how can you...Ch. 7 - Prob. 43PCh. 7 - Which of the following pairs are keto-enol...Ch. 7 - Prob. 45PCh. 7 - Do the equilibria of the following acid-base...Ch. 7 - What stereoisomers are obtained when 2-butyne...Ch. 7 - Draw the keto tautomer for each of the following:Ch. 7 - Show how each of the following compounds can be...Ch. 7 - A chemist is planning to synthesize 3-octyne by...Ch. 7 - Prob. 51PCh. 7 - What stereoisomers are obtained from the following...Ch. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Prob. 55PCh. 7 - Prob. 56PCh. 7 - Prob. 57P
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