Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 7, Problem 37P
What is the major product of the reaction of 1 mol of propyne with each of the following reagents?
- a. HBr (1 mol)
- b. HBr (2 mol)
- c. Br2 (1 mol)/CH2Cl2
- d. Br2 (2 mol)/CH2Cl2
- e. aqueous H2SO4, HgSO4
- f. R2BH in THF followed by H2O2/HO–/H2O
- g. excess H2, Pd/C
- h. H2/Lindlar catalyst
- i. sodium amide
- j. the product of part i followed by 1-chloropropane
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Choose the correct reagent(s) for the following reaction.
OA 1.H20/Hg(OAC)2 2. NaBH4
OB. H20/H2SO4 (cat.)
O C. 1 BH3.THF 2. NaOH/H202
ГОН
37. What will be the major product of the reaction of 1 mol of propyne with each of the following reagents?
a. HBr (1 mol)
b. HBr (2 mol)
c. Br2 (1 mol)/CH,Cl2
d. Br2 (2 mol)/CH2C12
e. aqueous H2SO4, HgSO4
f. borane in THF followed by
H,O2/HO¯/H2O
g. excess H2, Pd/C
h. H,/Lindlar catalyst
i. sodium in liquid ammonia at -78 °C
j. sodium amide
k. product of part j followed by
1-chloropropane
What is the major product of the following reaction?
A.
B.
NO₂
NO₂
NO₂
CH3CI, AICI3
C.
D.
NO₂
NO₂
Chapter 7 Solutions
Organic Chemistry
Ch. 7.1 - What is the molecular formula for a monocyclic...Ch. 7.1 - Prob. 2PCh. 7.1 - Draw the structure and give the common and...Ch. 7.1 - Prob. 4PCh. 7.1 - Name the following:Ch. 7.2 - Prob. 6PCh. 7.2 - Name the following:Ch. 7.3 - Prob. 8PCh. 7.3 - Why does cis-2-butene have a higher boiling point...Ch. 7.4 - What orbitals are used to form the carbon-carbon ...
Ch. 7.6 - Prob. 12PCh. 7.6 - Prob. 13PCh. 7.7 - Prob. 14PCh. 7.7 - Which alkyne should be used for the synthesis of...Ch. 7.7 - Prob. 16PCh. 7.8 - Prob. 17PCh. 7.8 - Only one alkyne forms an aldehyde when it...Ch. 7.9 - Describe the alkyne you should start with and the...Ch. 7.9 - Prob. 20PCh. 7.10 - Prob. 21PCh. 7.10 - Prob. 22PCh. 7.10 - Rank the following from strongest base to weakest...Ch. 7.12 - Prob. 26PCh. 7 - What is the major product obtained from the...Ch. 7 - Draw a condensed structure for each of the...Ch. 7 - A student was given the structural formula of...Ch. 7 - Prob. 30PCh. 7 - What is each compounds systematic name?Ch. 7 - What reagents should be used to carry out the...Ch. 7 - Prob. 33PCh. 7 - Prob. 34PCh. 7 - Prob. 35PCh. 7 - Prob. 36PCh. 7 - What is the major product of the reaction of 1 mol...Ch. 7 - What is each compounds systematic name? a....Ch. 7 - What is the molecular formula of a hydrocarbon...Ch. 7 - Answer Problem 39, parts a-b, using 2-butyne as...Ch. 7 - Prob. 41PCh. 7 - a. Starting with 3-methyl 1-butyne, how can you...Ch. 7 - Prob. 43PCh. 7 - Which of the following pairs are keto-enol...Ch. 7 - Prob. 45PCh. 7 - Do the equilibria of the following acid-base...Ch. 7 - What stereoisomers are obtained when 2-butyne...Ch. 7 - Draw the keto tautomer for each of the following:Ch. 7 - Show how each of the following compounds can be...Ch. 7 - A chemist is planning to synthesize 3-octyne by...Ch. 7 - Prob. 51PCh. 7 - What stereoisomers are obtained from the following...Ch. 7 - Prob. 53PCh. 7 - Prob. 54PCh. 7 - Prob. 55PCh. 7 - Prob. 56PCh. 7 - Prob. 57P
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