Organic Chemistry
Organic Chemistry
2nd Edition
ISBN: 9781118452288
Author: David R. Klein
Publisher: WILEY
Question
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Chapter 7.2, Problem 1CC

(a)

Interpretation Introduction

Interpretation:

The systematic name for the given set of molecules should be identified.

Concept introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule. It can be any alkyl group and carboxy, amino, cyano etc…

Suffix represents the substituent present in the molecule. It can be any alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word represents the longest continuous carbon skeleton present in the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: they are chiral molecules whose mirror images are not superimposable.

R and S nomenclature: It is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

(b)

Interpretation Introduction

Interpretation:

The systematic name for the given set of molecules should be identified.

Concept introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule. It can be any alkyl group and carboxy, amino, cyano etc…

Suffix represents the substituent present in the molecule. It can be any alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word represents the longest continuous carbon skeleton present in the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: they are chiral molecules whose mirror images are not superimposable.

R and S nomenclature: It is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

(c)

Interpretation Introduction

Interpretation:

The systematic name for the given set of molecules should be identified.

Concept introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule. It can be any alkyl group and carboxy, amino, cyano etc…

Suffix represents the substituent present in the molecule. It can be any alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word represents the longest continuous carbon skeleton present in the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: they are chiral molecules whose mirror images are not superimposable.

R and S nomenclature: It is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

(d)

Interpretation Introduction

Interpretation:

The systematic name for the given set of molecules should be identified.

Concept introduction:

Systematic Name: It is a standardized name given for a chemical compound in systematic manner. Any organic molecule can be named by using IUPAC (International Union for Pure and applied chemistry) rules. IUPAC name consists of three parts in major namely Prefix suffix and root word.

Prefix represents the substituent present in the molecule. It can be any alkyl group and carboxy, amino, cyano etc…

Suffix represents the substituent present in the molecule. It can be any alkene, alkyne, alcohol, carboxylic acid, alcohol etc...

Root word represents the longest continuous carbon skeleton present in the organic molecule.

When a molecule consists of cyclic structure, the root word of the molecule is prefixed with cyclo.

Chirality: It refers to a Carbon atom in a molecule that contains four different substituents.

Enantiomers: they are chiral molecules whose mirror images are not superimposable.

R and S nomenclature: It is used to assign the molecule using CIP rules.

The CIP rules are as follows:

Select the chiral carbon and assign the numbers according to the decreasing atomic mass of atoms attached to it.

If the numbering follows clockwise direction then the molecule is termed as R and if it follows anti-clockwise direction then molecule is termed as S.

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Chapter 7 Solutions

Organic Chemistry

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