General, Organic, and Biological Chemistry (3rd Edition)
3rd Edition
ISBN: 9780134042428
Author: Laura D. Frost, S. Todd Deal
Publisher: PEARSON
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Question
Chapter 7, Problem 7.70AP
Summary Introduction
To determine:
The decreasing order of boiling point with the appropriate reasons for the given four compounds.
Introduction:
The boiling point attained if the molecules of any compound have enough energy to change its liquid state to gaseous state. It is the temperature when the vapor pressure of the liquid is equals to the atmospheric pressure.
If the attractive forces between the molecules of a compound are stronger or the polarity of a compound is higher than the boiling point of this compound is also higher.
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The IR (infrared) spectra of two pure compounds (0.010 M compound A in solvent and 0.010 M compound B in solvent) are
given. The pathlength of the cell is 1.00 cm. The y-axis in the spectra is transmittance rather than absorption, so that the
wavenumbers at which there is a dip in the curve correspond to absorption peaks.
A mixture of A and B in unknown concentrations gave a percent transmittance of 49.8% at 2976 cm¹ and 44.9% at 3030 cm-1
Wavenumber
0.010 M A
0.010 M B
Unknown
3030 cm-1
35.0%
93.0%
44.9%
2976 cm-¹
76.0%
42.0%
49.8%
What are the concentrations of A and B in the unknown sample?
Transmittance (%)
100
90
80
70
60
50
40
2976 cm-1
30
3030 cm-1
20
Pure A
10
Pure B
0
3040
2990
Wavenumber (cm-1)
2940
2890
synthesize
1-propyne starting with propane.
Chapter 7 Solutions
General, Organic, and Biological Chemistry (3rd Edition)
Ch. 7 - Prob. 7.1PPCh. 7 - Prob. 7.2PPCh. 7 - Prob. 7.3PPCh. 7 - Given that only polar molecules can participate as...Ch. 7 - Prob. 7.5PPCh. 7 - Prob. 7.6PPCh. 7 - An ion-dipole attraction often occurs when ionic...Ch. 7 - Prob. 7.8PPCh. 7 - Prob. 7.9PPCh. 7 - Prob. 7.10PP
Ch. 7 - Prob. 7.11PPCh. 7 - Prob. 7.12PPCh. 7 - Prob. 7.13PPCh. 7 - Prob. 7.14PPCh. 7 - Prob. 7.15PPCh. 7 - Prob. 7.16PPCh. 7 - Prob. 7.17PPCh. 7 - Prob. 7.18PPCh. 7 - Nitrous oxide, N2O, or laughing gas, is a common...Ch. 7 - An Ambu bag is used in emergency resuscitation....Ch. 7 - Prob. 7.21PPCh. 7 - Prob. 7.22PPCh. 7 - Prob. 7.23PPCh. 7 - As a cylinder of compressed gas empties, the...Ch. 7 - Prob. 7.25PPCh. 7 - Prob. 7.26PPCh. 7 - Prob. 7.27PPCh. 7 - Prob. 7.28PPCh. 7 - Prob. 7.29PPCh. 7 - Prob. 7.30PPCh. 7 - Prob. 7.31PPCh. 7 - Prob. 7.32PPCh. 7 - Prob. 7.33PPCh. 7 - Prob. 7.34PPCh. 7 - Prob. 7.35PPCh. 7 - What component molecules make up a triglyceride?Ch. 7 - Prob. 7.37PPCh. 7 - Prob. 7.38PPCh. 7 - Prob. 7.39PPCh. 7 - Prob. 7.40PPCh. 7 - Prob. 7.41PPCh. 7 - Prob. 7.42PPCh. 7 - Prob. 7.43APCh. 7 - Prob. 7.44APCh. 7 - Prob. 7.45APCh. 7 - Prob. 7.46APCh. 7 - Prob. 7.47APCh. 7 - Prob. 7.48APCh. 7 - Prob. 7.49APCh. 7 - Prob. 7.50APCh. 7 - Prob. 7.51APCh. 7 - Prob. 7.52APCh. 7 - Prob. 7.53APCh. 7 - Prob. 7.54APCh. 7 - A beach ball is filled with 10.0 L of air in a...Ch. 7 - Prob. 7.56APCh. 7 - Prob. 7.57APCh. 7 - Liquid nitrogen is an extremely cold liquid (196...Ch. 7 - A full cylinder of compressed gas is moved to a...Ch. 7 - Prob. 7.60APCh. 7 - Your friend breathes in 1.5 L of helium from a...Ch. 7 - Prob. 7.62APCh. 7 - Prob. 7.63APCh. 7 - Prob. 7.64APCh. 7 - Predict which member of each of the following...Ch. 7 - Predict which member of each of the following...Ch. 7 - A stain on your shirt will not come out when you...Ch. 7 - Prob. 7.68APCh. 7 - Prob. 7.69APCh. 7 - Prob. 7.70APCh. 7 - Prob. 7.71APCh. 7 - Prob. 7.72APCh. 7 - Prob. 7.73APCh. 7 - Prob. 7.74APCh. 7 - Prob. 7.75APCh. 7 - Prob. 7.76APCh. 7 - Prob. 7.77APCh. 7 - Prob. 7.78APCh. 7 - Prob. 7.79APCh. 7 - Soap, phospholipids, and cholesterol are all...Ch. 7 - Describe other components present in a cell...Ch. 7 - Prob. 7.82APCh. 7 - Prob. 7.83CPCh. 7 - Desflurane and sevoflurane are common inhalation...Ch. 7 - Prob. 7.85CPCh. 7 - Prob. 7.86CPCh. 7 - Prob. 7.87CPCh. 7 - Getem Clean, Inc. has hired you as chief chcmnt...Ch. 7 - Prob. 7.89CPCh. 7 - Prob. 1IA.1QCh. 7 - Prob. 1IA.2QCh. 7 - Prob. 1IA.3QCh. 7 - Prob. 1IA.4QCh. 7 - Prob. 1IA.5QCh. 7 - Prob. 1IA.6QCh. 7 - Prob. 1IA.7QCh. 7 - Prob. 2IA.1QCh. 7 - Prob. 2IA.2QCh. 7 - Prob. 2IA.3QCh. 7 - Prob. 2IA.4QCh. 7 - Prob. 2IA.5QCh. 7 - Prob. 2IA.6QCh. 7 - Prob. 2IA.7QCh. 7 - Devise a rule to predict the solubility of an...Ch. 7 - Prob. 1ICCh. 7 - Prob. 2ICCh. 7 - Prob. 3IC
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