Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN: 9781259696527
Author: J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher: McGraw-Hill Education
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Chapter 7, Problem 7.18P
Interpretation Introduction

Interpretation:

The gas discharge temperature and the work output of the turbine per mole of the gas under the given conditions need to be calculated

Concept Introduction:

  • For an ideal gas under isentropic adiabatic conditions, the temperature and pressure are related as:
  • T2T1=( P 2 P 1)γ-1/γ(1)

    where, γ = Cp/Cv

  • The isentropic efficiency of a turbine is given as:
  • η=Actual work done by turbine Adiabatic Work =W˙aW˙s ----(3)

    where, the rate of work done is given as:

    W˙ = n˙ΔH -----(4)

    n˙ = molar flow rate

    ΔH = change in enthalpy

    Thus, turbine efficiency is given as:

    η =W˙aW˙s=H2a-H1H2s-H1

    (or) η =ΔHactualΔHadiabatic ----(5)

The gas discharge temperature = 593.8C0

Work output of turbine = -8.78 kJ/mol

Given Information:

Inlet pressure, P1 = 10 bar

Inlet Temperature, T1= 950C0

Outlet pressure, P2 = 1.5 bar

Heat capacity, Cp = 32 J.mol-1.K-1

Turbine efficiency, ? = 77% = 0.77

Explanation:

In this case, the combustion products have been assumed to behave as an ideal gas. The discharge temperature can be deduced from equation (1) and the work output can be deduced from equation (4).

The heat capacity ratio for gas turbine, i.e. ? = 1.33

Calculation:

Step 1:

Calculate the discharge/final temperature, T2

Based on equation (1) we have:

T2T1=( P 2 P 1)γ-1/γ

T2950=(1.510)1.33-1/1.33 =0.625

T2=593.8C0

Step 2:

Calculate the actual enthalpy change

The adiabatic enthalpy change is related to the change in temperature through the specific heat capacity, Cp

ΔHadiabatic = Cp(T2-T1) = 32(593.8-950) = -11.4 kJ/mol

Based on equation (5) the actual enthalpy change is:-

 ΔHactual = η×ΔHadiabatic = 0.77×(-11.4) = -8.78 kJ/mol

Step 3:

Calculate the work output of the turbine

Based on equation (4)

 W˙ = n˙ΔHactual 

W˙n˙= work output = ΔHactual = -8.78 kJ/mol

Thus, the gas discharge temperature = 593.8C0

Work output of turbine = -8.78 kJ/mol

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