Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
8th Edition
ISBN: 9780134015187
Author: John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. Peterson
Publisher: PEARSON
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Chapter 6.5, Problem 6.1CIAP
Dietary iron forms a 1:1 complex with hemoglobin (Hb), which is responsible for O2 transport in the body based on the following equation:
How many moles of oxygen could be transported by the hemoglobin complex formed from 8 mg of dietary iron?
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The 2-3 phosphoglycerate (BFG) binds to the central gap formed by the hemoglobin monomers (a2b2) facilitating the reversible release of oxygen. Approximate relationships between BFG concentrations in red blood cells and Pos in hemoglobin are in the table.a) Draw the reaction schemeb) Write the forces that condition the union between hemoglobin and BFG
A 46
1- 1,3-Bisphosphoglycerate (1,3-BPG) is a phosphoryl group donor during the
synthesis of ATP in the reaction:
1,3-BPG + ADP → 3-Phosphoglycerate + ATP
In human erythrocytes, the steady-state concentration of ATP is 2.24 mM, that
of ADP is 0.25 mM, and that of 3-Phosphoglycerate is 0.15 mM. Calculate the
concentration of 1,3-BPG at 25 °C, assuming that the above reaction is at the
Equilibrium in the cell, and that the AG° of the reaction is -18.9 kJ/mol. Use
R=8.315 J/mol.K and show your work.
2- In fact, the above reaction is maintained in a non-Equilibrium steady state in
human erythrocytes; and the AG’ of the reaction is equal to -3.7 kJ/mol in these
conditions. Calculate the concentration of 1,3-BPG at 25 °C in this non-
Equilibrium steady state. Show your work.
Chapter 6 Solutions
Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
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Ch. 6.4 - The tungsten metal used for filaments in light...Ch. 6.5 - What is the theoretical yield of ethyl chloride in...Ch. 6.5 - The reaction of ethylene oxide with water to give...Ch. 6.5 - Prob. 6.14KCPCh. 6.5 - Dietary iron forms a 1:1 complex with hemoglobin...Ch. 6.5 - Prob. 6.2CIAPCh. 6.5 - Prob. 6.3CIAPCh. 6 - Methionine, an amino acid used by organisms to...Ch. 6 - Prob. 6.16UKCCh. 6 - Prob. 6.17UKCCh. 6 - Prob. 6.18UKCCh. 6 - Prob. 6.19UKCCh. 6 - Prob. 6.20APCh. 6 - What is the difference between molecular weight...Ch. 6 - Prob. 6.22APCh. 6 - Prob. 6.23APCh. 6 - How many calcium atoms are in 16.2 g of calcium?Ch. 6 - What is the mass in grams of 2.68 1022 atoms of...Ch. 6 - Calculate the molar mass of each of the following...Ch. 6 - Prob. 6.27APCh. 6 - Prob. 6.28APCh. 6 - Caffeine has the formula C8H10N4O2. If an average...Ch. 6 - How many moles of aspirin, C9H8O4, are in a 500 mg...Ch. 6 - What is the molar mass of diazepam (Valium),...Ch. 6 - Calculate the molar masses of the following...Ch. 6 - How many moles are present in a 4.50 g sample of...Ch. 6 - How many grams are present in a 0.075 mol sample...Ch. 6 - The principal component of many kidney stones is...Ch. 6 - Prob. 6.36APCh. 6 - Ethyl acetate reacts with H2 in the presence of a...Ch. 6 - Prob. 6.38APCh. 6 - Ammonia, NH3, is prepared for use as a fertilizer...Ch. 6 - Hydrazine, N2H4, a substance used as rocket fuel,...Ch. 6 - Prob. 6.41APCh. 6 - Magnesium metal burns in oxygen to form magnesium...Ch. 6 - Titanium metal is obtained from the mineral...Ch. 6 - Prob. 6.44APCh. 6 - Prob. 6.45APCh. 6 - Prob. 6.47APCh. 6 - Prob. 6.48APCh. 6 - Once made by heating wood in the absence of air,...Ch. 6 - In Problem 6.40, hydrazine reacted with oxygen...Ch. 6 - Dichloromethane, CH2Cl2, the solvent used to...Ch. 6 - Cisplatin [Pt(NH3)2Cl2], a compound used in cancer...Ch. 6 - Prob. 6.53APCh. 6 - Prob. 6.54APCh. 6 - Prob. 6.55CPCh. 6 - Prob. 6.56CPCh. 6 - Prob. 6.57CPCh. 6 - Prob. 6.58CPCh. 6 - Prob. 6.59CPCh. 6 - Prob. 6.60CPCh. 6 - Gaseous ammonia reacts with oxygen in the presence...Ch. 6 - Sodium hypochlorite, the primary component in...Ch. 6 - Barium sulfate is an insoluble ionic compound...Ch. 6 - The last step in the production of nitric acid is...Ch. 6 - Acetylsalicylic acid, the active ingredient in...Ch. 6 - Jewelry and tableware can be silver-plated by...Ch. 6 - Elemental phosphorus exists as molecules of P4. It...Ch. 6 - Lithium oxide is used aboard the International...Ch. 6 - Prob. 6.69CPCh. 6 - Prob. 6.70GPCh. 6 - Obtain a bottle of aspirin and identify the amount...Ch. 6 - Lovastatin, a drug used to lower serum...Ch. 6 - Pyrite, also known as fools gold, is used...
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