Chemistry: Atoms First
Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 6, Problem 6.50QP

a)

Interpretation Introduction

Interpretation:

The Lewis structure for the given molecule has to be drawn.

Concept Introduction:

Octet Rule:

The octet rule states that the noble gas electron configuration is attained by the element, when the element either loses or gains or shares its atoms. The formulas for the compounds that contain specific elements can be predicted with the help of Octet rule. The octet rule holds good for those compounds that are made of elements present in second period and hence the important study on organic compounds that mainly consists of Carbon, Nitrogen and Oxygen atoms can be done with the help of Octet rule. The loss gain or sharing electrons of particular atom is dependent on properties of atoms that are determined by the number of subatomic particles inside in the atom.

Lewis structure:

The Lewis structure otherwise known as Lewis dot diagrams or electron dot structures that show the bond between atoms and lone pairs of electrons that are present in the molecule. Lewis structure represents each atom and their position in structure using the chemical symbol. Excess electrons forms the lone pair are given by pair of dots, and are located next to the atom.

b)

Interpretation Introduction

Interpretation:

The Lewis structure for the given molecule has to be drawn.

Concept Introduction:

Octet Rule:

The octet rule states that the noble gas electron configuration is attained by the element, when the element either loses or gains or shares its atoms. The formulas for the compounds that contain specific elements can be predicted with the help of Octet rule. The octet rule holds good for those compounds that are made of elements present in second period and hence the important study on organic compounds that mainly consists of Carbon, Nitrogen and Oxygen atoms can be done with the help of Octet rule. The loss gain or sharing electrons of particular atom is dependent on properties of atoms that are determined by the number of subatomic particles inside in the atom.

Lewis structure:

The Lewis structure otherwise known as Lewis dot diagrams or electron dot structures that show the bond between atoms and lone pairs of electrons that are present in the molecule. Lewis structure represents each atom and their position in structure using the chemical symbol. Excess electrons forms the lone pair are given by pair of dots, and are located next to the atom.

c)

Interpretation Introduction

Interpretation:

The Lewis structure for the given molecule has to be drawn.

Concept Introduction:

Octet Rule:

The octet rule states that the noble gas electron configuration is attained by the element, when the element either loses or gains or shares its atoms. The formulas for the compounds that contain specific elements can be predicted with the help of Octet rule. The octet rule holds good for those compounds that are made of elements present in second period and hence the important study on organic compounds that mainly consists of Carbon, Nitrogen and Oxygen atoms can be done with the help of Octet rule. The loss gain or sharing electrons of particular atom is dependent on properties of atoms that are determined by the number of subatomic particles inside in the atom.

Lewis structure:

The Lewis structure otherwise known as Lewis dot diagrams or electron dot structures that show the bond between atoms and lone pairs of electrons that are present in the molecule. Lewis structure represents each atom and their position in structure using the chemical symbol. Excess electrons forms the lone pair are given by pair of dots, and are located next to the atom.

d)

Interpretation Introduction

Interpretation:

The Lewis structure for the given molecule has to be drawn.

Concept Introduction:

Octet Rule:

The octet rule states that the noble gas electron configuration is attained by the element, when the element either loses or gains or shares its atoms. The formulas for the compounds that contain specific elements can be predicted with the help of Octet rule. The octet rule holds good for those compounds that are made of elements present in second period and hence the important study on organic compounds that mainly consists of Carbon, Nitrogen and Oxygen atoms can be done with the help of Octet rule. The loss gain or sharing electrons of particular atom is dependent on properties of atoms that are determined by the number of subatomic particles inside in the atom.

Lewis structure:

The Lewis structure otherwise known as Lewis dot diagrams or electron dot structures that show the bond between atoms and lone pairs of electrons that are present in the molecule. Lewis structure represents each atom and their position in structure using the chemical symbol. Excess electrons forms the lone pair are given by pair of dots, and are located next to the atom.

e)

Interpretation Introduction

Interpretation:

The Lewis structure for the given molecule has to be drawn.

Concept Introduction:

Octet Rule:

The octet rule states that the noble gas electron configuration is attained by the element, when the element either loses or gains or shares its atoms. The formulas for the compounds that contain specific elements can be predicted with the help of Octet rule. The octet rule holds good for those compounds that are made of elements present in second period and hence the important study on organic compounds that mainly consists of Carbon, Nitrogen and Oxygen atoms can be done with the help of Octet rule. The loss gain or sharing electrons of particular atom is dependent on properties of atoms that are determined by the number of subatomic particles inside in the atom.

Lewis structure:

The Lewis structure otherwise known as Lewis dot diagrams or electron dot structures that show the bond between atoms and lone pairs of electrons that are present in the molecule. Lewis structure represents each atom and their position in structure using the chemical symbol. Excess electrons forms the lone pair are given by pair of dots, and are located next to the atom.

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Common exceptions to the octet rule are compounds and polyatomic ions with central atoms having more than 8 electrons around them. Phosphorus pentafluoride, PF5; sulfur tetrafluoride, SF4; xenon tetrafluoride, XeF4; and tri-iodide ion, I3, are all examples of exceptions to the octet rule. (a) Draw the Lewis structures of these substances.(b) For which elements in these substances can theatoms have more than 8 electrons around them?(c) How can the atoms of the elements youidentified in Part (b) be surrounded by morethan 8 electrons?
An important starting material for the manufacture ofpolyphosphazenes is the cyclic molecule (NPCl₂)₃. The mol-ecule has a symmetrical six-membered ring of alternating N and P atoms, with the Cl atoms bonded to the P atoms. The nitrogen-phosphorus bond length is significantly less than that expectedfor an N−P single bond.(a) Draw a likely Lewis structure for the molecule.(b) How many lone pairs of electrons do the ring atoms have?(c) What is the order of the nitrogen-phosphorus bond?
Ortho-Dichlorobenzene, C6H4Cl2, is obtained when two ofthe adjacent hydrogen atoms in benzene are replaced withCl atoms. A skeleton of the molecule is shown here. (a) Completea Lewis structure for the molecule using bonds andelectron pairs as needed. (b) Are there any resonance structuresfor the molecule? If so, sketch them. (c) Are the resonancestructures in (a) and (b) equivalent to one another asthey are in benzene?

Chapter 6 Solutions

Chemistry: Atoms First

Ch. 6.2 - Prob. 3PPBCh. 6.2 - Prob. 6.2.1SRCh. 6.2 - Prob. 6.2.2SRCh. 6.2 - Using data from Table 6.2, calculate the magnitude...Ch. 6.2 - Prob. 6.2.4SRCh. 6.3 - Draw the Lewis structure for carbon disulfide...Ch. 6.3 - Prob. 4PPACh. 6.3 - Prob. 4PPBCh. 6.3 - Prob. 4PPCCh. 6.3 - Prob. 6.3.1SRCh. 6.3 - Prob. 6.3.2SRCh. 6.4 - The widespread use of fertilizers has resulted in...Ch. 6.4 - Prob. 5PPACh. 6.4 - Prob. 5PPBCh. 6.4 - Prob. 5PPCCh. 6.4 - Formaldehyde (CH2O), which can be used 10 preserve...Ch. 6.4 - Prob. 6PPACh. 6.4 - Prob. 6PPBCh. 6.4 - Prob. 6PPCCh. 6.4 - Prob. 6.4.1SRCh. 6.4 - Prob. 6.4.2SRCh. 6.5 - Prob. 6.7WECh. 6.5 - Prob. 7PPACh. 6.5 - Prob. 7PPBCh. 6.5 - Prob. 7PPCCh. 6.5 - How many resonance structures can be drawn for the...Ch. 6.5 - Indicate which of the following are resonance...Ch. 6.6 - Prob. 6.8WECh. 6.6 - Prob. 8PPACh. 6.6 - Prob. 8PPBCh. 6.6 - Prob. 8PPCCh. 6.6 - Prob. 6.9WECh. 6.6 - Prob. 9PPACh. 6.6 - Prob. 9PPBCh. 6.6 - Elements in the same group exhibit similar...Ch. 6.6 - Draw three resonance structures for the hydrogen...Ch. 6.6 - Draw two resonance structures for each speciesone...Ch. 6.6 - Prob. 10PPCCh. 6.6 - Prob. 6.6.1SRCh. 6.6 - Which elements cannot have more than an octet of...Ch. 6.6 - How many electrons are around the central atom in...Ch. 6 - Which of the following atoms must always obey the...Ch. 6 - Prob. 6.2KSPCh. 6 - Prob. 6.3KSPCh. 6 - How many lone pairs are on the central atom in the...Ch. 6 - Prob. 6.1QPCh. 6 - Prob. 6.2QPCh. 6 - Prob. 6.3QPCh. 6 - Prob. 6.4QPCh. 6 - Prob. 6.5QPCh. 6 - Prob. 6.6QPCh. 6 - Prob. 6.7QPCh. 6 - Prob. 6.8QPCh. 6 - For each of the following pairs of elements, state...Ch. 6 - Define electronegativity and explain the...Ch. 6 - Prob. 6.11QPCh. 6 - Prob. 6.12QPCh. 6 - Prob. 6.13QPCh. 6 - Prob. 6.14QPCh. 6 - Prob. 6.15QPCh. 6 - Prob. 6.16QPCh. 6 - Arrange the following bonds in order of increasing...Ch. 6 - Prob. 6.18QPCh. 6 - Prob. 6.19QPCh. 6 - Prob. 6.20QPCh. 6 - Prob. 6.21QPCh. 6 - Prob. 6.22QPCh. 6 - Prob. 6.23QPCh. 6 - Prob. 6.24QPCh. 6 - Prob. 6.25QPCh. 6 - Prob. 6.26QPCh. 6 - Prob. 6.27QPCh. 6 - Prob. 6.28QPCh. 6 - Prob. 6.30QPCh. 6 - Prob. 6.31QPCh. 6 - Prob. 6.32QPCh. 6 - Prob. 6.33QPCh. 6 - Prob. 6.34QPCh. 6 - Draw all of the resonance structures for the...Ch. 6 - Prob. 6.36QPCh. 6 - Prob. 6.37QPCh. 6 - Draw three resonance structures for the molecule...Ch. 6 - Draw three reasonable resonance structures for the...Ch. 6 - Indicate which of the following are resonance...Ch. 6 - Prob. 6.41QPCh. 6 - Prob. 6.42QPCh. 6 - Draw a resonance structure of the guanine molecule...Ch. 6 - Prob. 6.44QPCh. 6 - Give three examples of compounds that do not...Ch. 6 - Prob. 6.46QPCh. 6 - Prob. 6.47QPCh. 6 - Prob. 6.48QPCh. 6 - Prob. 6.49QPCh. 6 - Prob. 6.50QPCh. 6 - Prob. 6.51QPCh. 6 - Prob. 6.52QPCh. 6 - Prob. 6.53QPCh. 6 - Draw Lewis structures for the radical species ClF2...Ch. 6 - Prob. 6.55QPCh. 6 - Prob. 6.56QPCh. 6 - Prob. 6.57QPCh. 6 - Prob. 6.58QPCh. 6 - Prob. 6.59QPCh. 6 - Prob. 6.60QPCh. 6 - Give an example of an ion or molecule containing...Ch. 6 - Prob. 6.62QPCh. 6 - Prob. 6.63QPCh. 6 - Prob. 6.64QPCh. 6 - Are the following statements true or false? (a)...Ch. 6 - Prob. 6.66QPCh. 6 - Prob. 6.67QPCh. 6 - Most organic acids can be represented as RCOOH,...Ch. 6 - Prob. 6.69QPCh. 6 - Prob. 6.70QPCh. 6 - Prob. 6.71QPCh. 6 - The following species have been detected in...Ch. 6 - Prob. 6.73QPCh. 6 - Prob. 6.74QPCh. 6 - The triiodide ion (I3) in which the I atoms are...Ch. 6 - Prob. 6.76QPCh. 6 - Prob. 6.77QPCh. 6 - The chlorine nitrate (ClONO2) molecule is believed...Ch. 6 - Prob. 6.79QPCh. 6 - For each of the following organic molecules draw a...Ch. 6 - Prob. 6.81QPCh. 6 - Draw Lewis structures for the following organic...Ch. 6 - Draw Lewis structures for the following four...Ch. 6 - Prob. 6.84QPCh. 6 - Prob. 6.85QPCh. 6 - Draw three resonance structures for (a) the...Ch. 6 - Prob. 6.87QPCh. 6 - Prob. 6.88QPCh. 6 - Prob. 6.89QPCh. 6 - Draw a Lewis structure for nitrogen pentoxide...Ch. 6 - Prob. 6.91QPCh. 6 - Nitrogen dioxide (NO2) is a stable compound....Ch. 6 - Prob. 6.93QPCh. 6 - Vinyl chloride (C2H3Cl) differs from ethylene...Ch. 6 - Prob. 6.95QPCh. 6 - Prob. 6.96QPCh. 6 - In 1999 an unusual cation containing only nitrogen...Ch. 6 - Prob. 6.98QPCh. 6 - Prob. 6.99QPCh. 6 - Electrostatic potential maps for three compounds...
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