General, Organic, and Biological Chemistry - 4th edition
4th Edition
ISBN: 9781259883989
Author: by Janice Smith
Publisher: McGraw-Hill Education
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Question
Chapter 6, Problem 24P
Interpretation Introduction
Interpretation:
The bonds need to be arranged in order of increasing strength.
Concept introduction:
It is equal to the bond energy, that is, the amount of energy required to make the bond. It is equal to the sum of bond dissociation energies of all the bonds present in the molecule.
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L. Using Table 1, calculate AH; for each of the following reactions. Tell if each is exothermic or
endothermic.
a. 2 NO(g) + 0:(8) → 2 NO:(g)
b. 2 C,Hlg) + 70:(g) → 4 CO.(g) + 6 H;0(g)
c. N:(g) + 3 H:(g) - 2 NH:(g)
d. 2 CH;OH(1) + 3 0:(g) → 2 CO:(g) + 4 H;0(g)
e. 2 SO:(g) + 0:(8) + 2 S0,(g)
f. 2 CH«(g) + 30:(8) → 2 CO:(g) + 2 H;0(g)
& 2 CO(g) + O:(8) → 2 CO:(g)
h. N;(8) + O:[g) → 2 NO(8)
II. Calculate AH, for each of the following (using Table 1).
i CHxo from the reaction
2 C;H:(B) + 5 0:(g) → 4 CO:(g) + 2 H;0(g) + 600kcal
i CHo from the reaction
CH«(g) • 2 0:(g)
CO:(g) + 2 H;0(g) + 192 kcal
III. Given the following reactions
k S+ 0: - So: 71.0 kcal
2 so, + 0: - 2 s0, + 47.0 kcal
Calculate AH, for 2 S + 3 0: - 2 SO,
L 2C + 0, - 2 co + 52.8 kcal
2 co + 0; - 2 CO; + 125 kcal
Calculate AlH, for C + 0z - co:
IV. Calculate AH, AS and AG at 25 C, and tell if the reaction will go spontaneously (use Table 1
and 2)
m. N:(g) + 3 H:(R) → 2 NH:(8)
n. 2 CO(g) + 0:(g) - 2 CO:(8)
a 2 CH:(g) +
5 0:(8)…
The product(s) that can be formed in the given
reaction is/are
Br, H,0
NaCl
Br
Br
Br
CI
Br
Perform the conversions between energy units.
663 kJ=663 kJ=
JJ
2655 kcal=2655 kcal=
kJkJ
9.49×106 J=9.49×106 J=
kcal
Chapter 6 Solutions
General, Organic, and Biological Chemistry - 4th edition
Ch. 6.1 - Prob. 6.1PPCh. 6.1 - Prob. 6.1PCh. 6.1 - Prob. 6.2PPCh. 6.1 - Prob. 6.2PCh. 6.2 - Using the values in Table 6.2, give H for each...Ch. 6.2 - Prob. 6.4PPCh. 6.2 - Answer the following questions using the given...Ch. 6.2 - Given the H and balanced equation in Sample...Ch. 6.2 - Prob. 6.6PPCh. 6.3 - Prob. 6.7PP
Ch. 6.4 - Consider the reaction of ozone (O3) with nitrogen...Ch. 6.4 - Draw an energy diagram for an uncatalyzed...Ch. 6.5 - Identify the forward and reverse reactions in each...Ch. 6.5 - Write the expression for the equilibrium constant...Ch. 6.5 - Consider the reversible reaction AB, with K=1....Ch. 6.5 - Given each equilibrium constant, state whether the...Ch. 6.5 - Consider the following reaction:...Ch. 6.5 - Using the equilibrium mixture of reactants and...Ch. 6.5 - Calculate the equilibrium constant for each...Ch. 6.5 - Consider the representation depicted in the...Ch. 6.6 - Prob. 6.13PPCh. 6.6 - Prob. 6.14PPCh. 6.6 - wThe conversion of H2O to H2 and O2 is an...Ch. 6.6 - The reaction of O2 with NO to form NO2 and O2 is...Ch. 6.6 - wIn which direction is the equilibrium shifted in...Ch. 6.6 - Label each statement about the following...Ch. 6 - Prob. 11PCh. 6 - Prob. 12PCh. 6 - Prob. 13PCh. 6 - Prob. 14PCh. 6 - Prob. 15PCh. 6 - Prob. 16PCh. 6 - Prob. 17PCh. 6 - Prob. 18PCh. 6 - Prob. 19PCh. 6 - Prob. 20PCh. 6 - Prob. 21PCh. 6 - Prob. 22PCh. 6 - Prob. 23PCh. 6 - Prob. 24PCh. 6 - Prob. 25PCh. 6 - Prob. 26PCh. 6 - Prob. 27PCh. 6 - Ammonia ( NH3 ) decomposes to hydrogen and...Ch. 6 - Prob. 29PCh. 6 - Ethanol ( C2H6O ), a gasoline additive, is formed...Ch. 6 - Prob. 31PCh. 6 - Prob. 32PCh. 6 - Prob. 33PCh. 6 - Prob. 34PCh. 6 - Draw an energy diagram for the following reaction...Ch. 6 - Prob. 36PCh. 6 - State two reasons why increasing temperature...Ch. 6 - Why does decreasing concentration decrease the...Ch. 6 - Prob. 39PCh. 6 - Prob. 40PCh. 6 - Which of the following affect the rate of a...Ch. 6 - Prob. 42PCh. 6 - How does a catalyst affect each of the following:...Ch. 6 - What is the difference between a catalyst and an...Ch. 6 - Prob. 45PCh. 6 - Consider the representation depicted in the...Ch. 6 - For each value, are the reactants or products...Ch. 6 - Prob. 48PCh. 6 - Prob. 49PCh. 6 - Prob. 50PCh. 6 - Prob. 51PCh. 6 - Consider three different equilibrium mixtures...Ch. 6 - Write an expression for the equilibrium constant...Ch. 6 - Write an expression for the equilibrium constant...Ch. 6 - Prob. 55PCh. 6 - Use each expression for the equilibrium constant...Ch. 6 - Prob. 57PCh. 6 - Consider the following reaction:...Ch. 6 - Prob. 59PCh. 6 - Which of the following representations ([1][3]) of...Ch. 6 - Consider the following reaction....Ch. 6 - Consider the following reaction. H2(g)+I2(g)2HI(g)...Ch. 6 - Prob. 63PCh. 6 - Prob. 64PCh. 6 - Consider the reaction of N2(g)+O2(g)2NO(g). What...Ch. 6 - Consider the reaction of H2(g)+F2(g)2HF(g). What...Ch. 6 - Prob. 67PCh. 6 - Consider the reversible reaction ABA+B, shown at...Ch. 6 - Consider the endothermic conversion of oxygen to...Ch. 6 - Consider the exothermic reaction:...Ch. 6 - Consider the exothermic reaction:...Ch. 6 - Consider the endothermic reaction:...Ch. 6 - Consider the gas-phase reaction of ethylene...Ch. 6 - Methanol (CHO), which is used as a fuel in race...Ch. 6 - Prob. 75PCh. 6 - How does a catalytic converter clean up automobile...Ch. 6 - Prob. 77PCh. 6 - The reaction of salicylic acid with acetic acid...Ch. 6 - Prob. 79PCh. 6 - Prob. 80PCh. 6 - Prob. 81PCh. 6 - Prob. 82PCh. 6 - Prob. 83CPCh. 6 - Prob. 84CP
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