Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 5.9, Problem 5.35P
Interpretation Introduction
Interpretation:
The effect of catalyst
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Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
(i) H2(g) + NO(g) à H2O(g) + N(g) Ea = 436 kJ ∆H = –491 kJ
(ii) N(g) + NO(g) à N2(g) + O(g) Ea = 625 kJ ∆H = –312 kJ
(iii) O(g) + H2(g) à H2O(g) Ea = 1690 kJ ∆H = +131 kJ
Draw the potential energy diagram for the reaction. Assume the potential energy of the reactants was 1400 kJ
How rate of a single step reaction is controlled by its energy of activation? How the rate such a reaction is determined from H˚ value with its positive and negative nature?
Chapter 5 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 5.1 - Use the molecular art to identify the process as a...Ch. 5.1 - Use the molecular at to identify the process as a...Ch. 5.1 - Prob. 5.3PCh. 5.1 - Prob. 5.4PCh. 5.1 - Write a chemical equation from the following...Ch. 5.2 - Prob. 5.6PCh. 5.2 - Prob. 5.7PCh. 5.2 - Prob. 5.8PCh. 5.2 - Prob. 5.9PCh. 5.2 - Prob. 5.10P
Ch. 5.3 - Prob. 5.11PCh. 5.3 - Prob. 5.12PCh. 5.3 - How many molecules are contained in each of the...Ch. 5.3 - Prob. 5.14PCh. 5.4 - Prob. 5.15PCh. 5.4 - Prob. 5.16PCh. 5.4 - Prob. 5.18PCh. 5.4 - Prob. 5.19PCh. 5.5 - Use the balanced equation for the reaction of N2...Ch. 5.5 - Prob. 5.21PCh. 5.6 - Using the balanced equation for fermentation...Ch. 5.6 - Prob. 5.23PCh. 5.6 - Prob. 5.24PCh. 5.6 - Prob. 5.25PCh. 5.7 - Prob. 5.26PCh. 5.7 - Prob. 5.27PCh. 5.7 - Prob. 5.28PCh. 5.7 - Early pacemakers generated an electrical impulse...Ch. 5.8 - Prob. 5.30PCh. 5.8 - Prob. 5.31PCh. 5.8 - Prob. 5.32PCh. 5.8 - Prob. 5.33PCh. 5.9 - Prob. 5.34PCh. 5.9 - Prob. 5.35PCh. 5.9 - Prob. 5.36PCh. 5.10 - Prob. 5.37PCh. 5.10 - In which direction is the equilibrium shifted with...Ch. 5 - Use the molecular art to identify the process as a...Ch. 5 - Prob. 5.40UKCCh. 5 - Prob. 5.41UKCCh. 5 - Prob. 5.42UKCCh. 5 - Prob. 5.43UKCCh. 5 - Prob. 5.44UKCCh. 5 - Prob. 5.45UKCCh. 5 - Spinach, cabbage, and broccoli are excellent...Ch. 5 - Prob. 5.47UKCCh. 5 - Prob. 5.48UKCCh. 5 - Prob. 5.49UKCCh. 5 - Rechargeable nickelcadmium batteries are used in...Ch. 5 - Prob. 5.51UKCCh. 5 - Prob. 5.52UKCCh. 5 - Prob. 5.53UKCCh. 5 - Prob. 5.54UKCCh. 5 - Prob. 5.55APCh. 5 - Prob. 5.56APCh. 5 - Prob. 5.57APCh. 5 - Prob. 5.58APCh. 5 - Prob. 5.59APCh. 5 - Prob. 5.60APCh. 5 - Prob. 5.61APCh. 5 - Prob. 5.62APCh. 5 - Prob. 5.63APCh. 5 - Consider the reaction, 2 NO + 2 CO N2 + 2 CO2....Ch. 5 - Prob. 5.65APCh. 5 - Prob. 5.66APCh. 5 - Prob. 5.67APCh. 5 - Prob. 5.68APCh. 5 - Prob. 5.69APCh. 5 - Prob. 5.70APCh. 5 - Prob. 5.71APCh. 5 - Prob. 5.72APCh. 5 - Prob. 5.73APCh. 5 - Prob. 5.74APCh. 5 - Prob. 5.75APCh. 5 - Prob. 5.76APCh. 5 - Prob. 5.77APCh. 5 - Prob. 5.78APCh. 5 - Prob. 5.79APCh. 5 - Prob. 5.80APCh. 5 - Prob. 5.81APCh. 5 - Prob. 5.82APCh. 5 - Prob. 5.83APCh. 5 - Prob. 5.84APCh. 5 - Prob. 5.85APCh. 5 - Prob. 5.86APCh. 5 - Prob. 5.87APCh. 5 - Prob. 5.88APCh. 5 - Prob. 5.89APCh. 5 - Prob. 5.90APCh. 5 - Prob. 5.91APCh. 5 - Prob. 5.92APCh. 5 - Prob. 5.93APCh. 5 - Prob. 5.94APCh. 5 - Prob. 5.95APCh. 5 - Prob. 5.96APCh. 5 - Prob. 5.97APCh. 5 - Prob. 5.98APCh. 5 - Prob. 5.99APCh. 5 - Prob. 5.100APCh. 5 - Prob. 5.101APCh. 5 - Prob. 5.102APCh. 5 - Prob. 5.103CP
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Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The reaction of carbon monoxide with hydrogen to form methanol is quite slow at room temperature. As a general rule, reactions go faster at higher temperatures. Suppose that you tried to speed up this reaction by increasing the temperature. (a) Assuming that rH does not change very much as the temperature changes, what effect would increasing the temperature have on rSsurroundings? (b) Assuming that rS for a reaction System does not change much as the temperature changes, what effect would increasing the temperature have on rSuniverse?arrow_forwardIn Chapter 3, we discussed the conversion of biomass into biofuels. One important area of research associated with biofuels is the identification and development of suitable catalysts to increase the rate at which fuels can be produced. Do a web search to find an article describing biofuel catalysts. Then, write one or two sentences describing the reactions being catalyzed, and identify the catalyst as homogeneous or heterogeneous.arrow_forwardBy which of the following mechanisms does a catalyst operate? a. It decreases the activation energy barrier for a reaction. b. It serves as a reactant and is consumed. c. It increases the temperature of a reaction. d. It increases the concentration of reactants.arrow_forward
- . Account for the increase in reaction rate brought about by a catalyst.arrow_forwardThe following equation represents a reversible decomposition: CaCO3(s)CaO(s)+CO2(g) Under what conditions will decomposition in a closed container proceed to completion so that no CaCO3 remains?arrow_forwardCobra venom helps the snake secure food by binding to acetylcholine receptors on the diaphragm of a bite victim, leading to the loss of function of the diaphragm muscle tissue and eventually death. In order to develop more potent antivenins, scientists have studied what happens to the toxin once it has bound the acetylcholine receptors. They have found that the toxin is released from the receptor in a process that can be described by the rate law Rate = k [acetylcholine receptortoxin complex] If the activation energy of this reaction at 37.0C is 26.2 kJ/mol and A = 0.850 s1. what is the rate of reaction if you have a 0.200M solution of receptor-toxin complex at 37.0C?arrow_forward
- . The minimum energy required for molecules to react with each other is called the _______ energy.arrow_forwardOld-fashioned smelling salts consist of ammonium carbonate, (NH4)2CO3. The reaction for the decomposition of ammonium carbonate (NH4)2CO3(s)2NH3(g)+CO(g)+H2O(g) is endothermic. Would the smell of ammonia increase or decrease as the temperature is increased?arrow_forwardSubstances that poison a catalyst pose a major concern for many engineering designs, including those for catalytic converters. One design option is to add materials that react with potential poisons before they reach the catalyst. Among the commonly encountered catalyst poisons are silicon and phosphorus, which typically form phosphate or silicate ions in the oxidizing environment of an engine. Group 2 elements are added to the catalyst to react with these contaminants before they reach the working portion of the catalytic converter. If estimates show that a catalytic converter will be exposed to 625 g of silicon during its lifetime, what mass of beryllium would need to be included in the design?arrow_forward
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