Principles of General, Organic, Biological Chemistry
2nd Edition
ISBN: 9780073511191
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Chapter 5.8, Problem 5.32P
Interpretation Introduction
Interpretation:
The energy change diagram of the reaction with
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2) Complete the reaction:
NO.
LOH
FECLT
Calculate the ΔH (in kcal/mol) for the reactions (use table above):
a) H2 + O2 → 2 H2O
b) CH4 + 2 O2 → CO2 + 2 H2O
c) 6 CO2 + 6 H2O → C6H16O6 + 6 O2
If the concentration of a reactant increases while a reaction in progress, how does it
affect the rate of reaction? (K:1)
Select one:
It does not have any effect on the rate of reaction
Rate of the reaction decreases
Rate of the reaction first decreases and then increases.
Rate of the reaction first increases and then decreases.
O Rate of reaction increases
Chapter 5 Solutions
Principles of General, Organic, Biological Chemistry
Ch. 5.1 - Use the molecular art to identify the process as a...Ch. 5.1 - Use the molecular at to identify the process as a...Ch. 5.1 - Prob. 5.3PCh. 5.1 - Prob. 5.4PCh. 5.1 - Write a chemical equation from the following...Ch. 5.2 - Prob. 5.6PCh. 5.2 - Prob. 5.7PCh. 5.2 - Prob. 5.8PCh. 5.2 - Prob. 5.9PCh. 5.2 - Prob. 5.10P
Ch. 5.3 - Prob. 5.11PCh. 5.3 - Prob. 5.12PCh. 5.3 - How many molecules are contained in each of the...Ch. 5.3 - Prob. 5.14PCh. 5.4 - Prob. 5.15PCh. 5.4 - Prob. 5.16PCh. 5.4 - Prob. 5.18PCh. 5.4 - Prob. 5.19PCh. 5.5 - Use the balanced equation for the reaction of N2...Ch. 5.5 - Prob. 5.21PCh. 5.6 - Using the balanced equation for fermentation...Ch. 5.6 - Prob. 5.23PCh. 5.6 - Prob. 5.24PCh. 5.6 - Prob. 5.25PCh. 5.7 - Prob. 5.26PCh. 5.7 - Prob. 5.27PCh. 5.7 - Prob. 5.28PCh. 5.7 - Early pacemakers generated an electrical impulse...Ch. 5.8 - Prob. 5.30PCh. 5.8 - Prob. 5.31PCh. 5.8 - Prob. 5.32PCh. 5.8 - Prob. 5.33PCh. 5.9 - Prob. 5.34PCh. 5.9 - Prob. 5.35PCh. 5.9 - Prob. 5.36PCh. 5.10 - Prob. 5.37PCh. 5.10 - In which direction is the equilibrium shifted with...Ch. 5 - Use the molecular art to identify the process as a...Ch. 5 - Prob. 5.40UKCCh. 5 - Prob. 5.41UKCCh. 5 - Prob. 5.42UKCCh. 5 - Prob. 5.43UKCCh. 5 - Prob. 5.44UKCCh. 5 - Prob. 5.45UKCCh. 5 - Spinach, cabbage, and broccoli are excellent...Ch. 5 - Prob. 5.47UKCCh. 5 - Prob. 5.48UKCCh. 5 - Prob. 5.49UKCCh. 5 - Rechargeable nickelcadmium batteries are used in...Ch. 5 - Prob. 5.51UKCCh. 5 - Prob. 5.52UKCCh. 5 - Prob. 5.53UKCCh. 5 - Prob. 5.54UKCCh. 5 - Prob. 5.55APCh. 5 - Prob. 5.56APCh. 5 - Prob. 5.57APCh. 5 - Prob. 5.58APCh. 5 - Prob. 5.59APCh. 5 - Prob. 5.60APCh. 5 - Prob. 5.61APCh. 5 - Prob. 5.62APCh. 5 - Prob. 5.63APCh. 5 - Consider the reaction, 2 NO + 2 CO N2 + 2 CO2....Ch. 5 - Prob. 5.65APCh. 5 - Prob. 5.66APCh. 5 - Prob. 5.67APCh. 5 - Prob. 5.68APCh. 5 - Prob. 5.69APCh. 5 - Prob. 5.70APCh. 5 - Prob. 5.71APCh. 5 - Prob. 5.72APCh. 5 - Prob. 5.73APCh. 5 - Prob. 5.74APCh. 5 - Prob. 5.75APCh. 5 - Prob. 5.76APCh. 5 - Prob. 5.77APCh. 5 - Prob. 5.78APCh. 5 - Prob. 5.79APCh. 5 - Prob. 5.80APCh. 5 - Prob. 5.81APCh. 5 - Prob. 5.82APCh. 5 - Prob. 5.83APCh. 5 - Prob. 5.84APCh. 5 - Prob. 5.85APCh. 5 - Prob. 5.86APCh. 5 - Prob. 5.87APCh. 5 - Prob. 5.88APCh. 5 - Prob. 5.89APCh. 5 - Prob. 5.90APCh. 5 - Prob. 5.91APCh. 5 - Prob. 5.92APCh. 5 - Prob. 5.93APCh. 5 - Prob. 5.94APCh. 5 - Prob. 5.95APCh. 5 - Prob. 5.96APCh. 5 - Prob. 5.97APCh. 5 - Prob. 5.98APCh. 5 - Prob. 5.99APCh. 5 - Prob. 5.100APCh. 5 - Prob. 5.101APCh. 5 - Prob. 5.102APCh. 5 - Prob. 5.103CP
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- Which reaction is faster, one with Eact = + 35. kcal/mol or one with Eact = + 55 Kcal/mol? Explain.arrow_forward5) An enantioselective reaction has a AAG* = 1.4 kcal/mol. What is the e.r. and % ee of the reaction?arrow_forwardCalculate the ?H (in kcal/mol) for the reactions (use table above): a)H2 + O2 → 2 H2O b) CH4 + 2 O2 → CO2 + 2 H2O c) 6 CO2 + 6 H2O → C6H16O6 + 6 O2arrow_forward
- Calculate the ?H (in kcal/mol) for the reactions (use table on the picture) a) H2 + O2 → 2 H2O b) CH4 + 2 O2 → CO2 + 2 H2O c) 6 CO2 + 6 H2O → C6H16O6 + 6 O2arrow_forwardFollowing are the steps in the industrial synthesis of glycerin. NaOH, H₂O B (C₂H₂O) CH₂=CHCH, Propene Cl₂A (C₂H₂CI) heat C (C₂H,ClO₂) Ca(OH)2, D (C3H6O2) heat Cl₂, H₂O H₂O, HCI OH HOCH₂CHCH₂OH 1,2,3-Propanetriol (glycerol, glycerin)arrow_forward(1) Slick Johnny burns 1.2 Kcal/min when he's completely chilled and fasted. He lives on moonshine whiskey which is about 40% ethanol (assume a g is about an ml). Assuming there isn't much else of nutritional value, how much would he have to drink to maintain his body weight. 0.62 L 0.82 L 0.93 L 1.44 L (2) Assuming ethanol (C2H6O) is completely burned to CO2 and H2O, what would Slick Johnny's RQ be? 0.67 0.74 0.86 0.96arrow_forward
- Calculate the following and answer the question. Addition of 1 mole of H2 to cyclohexene releases -28.6 kcal. Estimate the energy that should be released to add 3 moles of H2 to cyclohexatriene (a) Addition of 3 moles of H2 to benzene (which is the IUPAC name for cyclohexatriene) has been shown to release -49.8 kcal. What conclusions can you make about the stability of benzene based on the difference in the estimated energy and the actual energy released?arrow_forwardB What is the systematic name of the product P of this chemical reaction? + NaOH - OH P + H2O Garrow_forwardBased on the following reaction and enthalpy data: HBF2 + Bel2 → BeF2 + Hgl2 Q R S P Data: H8F2 = 535 kl/mol and 126 kcal mol Bel2 = 577 kl/mol and 138 kcal/mol BeF2 = 1262 kl/mol and 302 kcal/mol Hg12 = 292 kl/mol and 70 kcal/mol From the reactions and data above, it can be concluded that the interaction of each species in a row is. A. P = soft – hard, Q = soft – hard, R = hard – hard, S = soft – soft B. P = soft – hard, Q = hard – soft, R = hard – hard, S = soft – soft C. P = hard - soft, Q = hard – soft, R = soft – soft, S = hard – hard D. P = soft – hard, Q = soft – hard, R = hard – hard, S = hard – softarrow_forward
- In the following diagram, there are four potential energy reactions (1, 2, 3 and 4). State whether or not the reactions (from A to B) are exergonic or endergonic and require or release energy. Provide an explanation for your answers.arrow_forwardComplete the given reactions. Add hydrogen atoms and charges to the appropriate atoms. Reaction A H₂C-CH₂-C -NCH, + NaOH H H₂C-CH₂-C-N-CH₂ + HCI H heat 2 heat Incorrect Reaction B OH Y H₂C 0 Na H₂N CH₂ H₂C OH H₂N CH₂arrow_forwardNot y Given the following reaction: AH° = -118.7 kwatk CHAG)+ 02g) → C(s) + 2H20 2° ) E FI AH° = - 26.4 kcàl 1 C(s) + O 2(g) → CO (), AH° = – 67.7 kcal CO(g) + 2 → CO 2(g) O 20) Consider the combustion of meth ane, determine the AH° using Hess's Law. ΔΗ- CHAG) + 202(g) → CO2G) + 2H20» → CO 2(g) + 2H20u)arrow_forward
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