Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 5, Problem 51P
Which bond is stronger? Briefly explain why.
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Answer the questions in the table below about the shape of the phosphorus pentabromide (PBr,) molecule.
How many electron groups are around the central phosphorus
atom?
Note: one "electron group" means one lone pair, one single bond,
one double bond, or one triple bond.
What phrase best describes the arrangement of these electron
groups around the central phosphorus atom?
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(choose one)
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. The bond lengths of carbon-carbon, carbon-nitrogen, carbon-oxygen, and
nitrogen-nitrogen single, double, and triple bonds are listed in Table 8.4. Plot bond
enthalpy versus bond length listed in Table 8.5 for these bonds.
(a) Is this statement true: "The longer the bond, the stronger the bond"?
(b) Based on your chart, order the relative strengths of C-C, C-N, C-O, and
N-N bonds from weakest to strongest.
Lewis structure of H2S. Any polar bonds in molecule? Polar or non polar?
Chapter 5 Solutions
Organic Chemistry (8th Edition)
Ch. 5.1 - What is the molecular formula for each of the...Ch. 5.1 - Prob. 4PCh. 5.1 - Determine the degree of unsaturation and then draw...Ch. 5.1 - Prob. 6PCh. 5.2 - What is each compounds systematic name?Ch. 5.2 - Prob. 8PCh. 5.2 - Draw the structure for each of the following: a....Ch. 5.3 - How many carbons are in the planar double-bond...Ch. 5.3 - Prob. 12PCh. 5.5 - Prob. 13P
Ch. 5.5 - Prob. 14PCh. 5.5 - Prob. 16PCh. 5.5 - Prob. 17PCh. 5.6 - a. Which of the monosubstituted cyclohexanes in...Ch. 5.6 - a. Calculate the percentage of isopropylcylohexane...Ch. 5.6 - a. for which reaction in each set will S be more...Ch. 5.6 - a. For a reaction with H = 12 kcal/ mol and S =...Ch. 5.8 - Prob. 23PCh. 5.9 - Prob. 24PCh. 5.9 - How many different alkenes can be hydrogenated to...Ch. 5.9 - The same alkane is obtained from the catalytic...Ch. 5.9 - Prob. 27PCh. 5.9 - Rank the following compounds from most stable to...Ch. 5.10 - Prob. 29PCh. 5.10 - Prob. 30PCh. 5.11 - The rate constant for a reaction can be increased...Ch. 5.11 - Prob. 33PCh. 5.11 - a. Which reaction has a greater equilibrium...Ch. 5.12 - Draw a reaction coordinate diagram for a two-step...Ch. 5.12 - a. Which step in the reaction coordinate diagram...Ch. 5.12 - Draw a reaction coordinate diagram for the...Ch. 5.13 - Prob. 38PCh. 5 - What is each compounds systematic name?Ch. 5 - Prob. 40PCh. 5 - Draw the structure of a hydrocarbon that has six...Ch. 5 - Draw the condensed structure for each of the...Ch. 5 - Prob. 43PCh. 5 - Prob. 44PCh. 5 - Prob. 45PCh. 5 - Name the following:Ch. 5 - Prob. 47PCh. 5 - Prob. 48PCh. 5 - Prob. 49PCh. 5 - In a reaction in which reactant A is in...Ch. 5 - Which bond is stronger? Briefly explain why.Ch. 5 - Prob. 52PCh. 5 - Prob. 53PCh. 5 - By following the curved red arrows, draw the...Ch. 5 - Prob. 55PCh. 5 - Prob. 56PCh. 5 - Draw structures for the following: a....Ch. 5 - Prob. 58PCh. 5 - a. Which of the following reactions has the larger...Ch. 5 - Prob. 60PCh. 5 - a. What is the equilibrium constant for a reaction...Ch. 5 - Prob. 62PCh. 5 - Prob. 63PCh. 5 - Given that the free energy of the twist-boat...Ch. 5 - Prob. 65PCh. 5 - Prob. 1PCh. 5 - Prob. 2PCh. 5 - Prob. 3PCh. 5 - Prob. 4PCh. 5 - Prob. 5PCh. 5 - Prob. 6PCh. 5 - Draw curved arrows to show the movement of the...Ch. 5 - Prob. 8PCh. 5 - Prob. 9PCh. 5 - Prob. 10P
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- Tribromide, Br3, and triiodide, I3, ions are often found in aqueous solutions, but trifluoride ion, F3, is so rare that its bond strength was only measured in 2000. Explain.arrow_forwardOn the basis of the electronegativity values given in Fig. 12.3. indicate which is the more polar bond in each of the following pairs. msp;a.OClorOBrc.PSorPOb.NOorNFd.HOorHNarrow_forwardThe cyclohexane carboxylate anion has a Lewis structure Pushing a pair of unshared electrons away from the negatively charged oxygen atom and, at the same time, pushing a pair of pi electrons toward the other oxygen will generate a second resonance structure. Thus,arrow_forward
- hy do atoms form bonds with one another? What can make a molecule favored compared with the lone atoms?arrow_forwardExplain why nonmetal atoms in Period 3 and beyond can accommodate greater than an octet of electrons and those in Period 2 cannot do so.arrow_forwardExplain how and bonds are similar and how they are different.arrow_forward
- On the basis of the electronegativity values given in Fig. 12.3, indicate which is the more polar bond in each of the following pairs. msp;a.HForHClc.HBrorHClb.HClorHId.HIorHBrarrow_forwardComplete the table on next page.arrow_forwardthe formal charges on all the atoms in the following Lewis diagrams. Which one would best represent bonding in the molecule Cl2O ?arrow_forward
- What aspect of the following Lewis structure indicates that the concept of coordinate covalency is needed to explain the bonding in the molecule?arrow_forwardChloromethane has the Lewis structure _______________________________ The carbon atom is sharing 4 electron pairs. In each shared pair the carbon atom “owns” 1 electron. The number of electrons that “belong” to carbon is ___. Carbon, being a Group ___ element would have 4 , outer shell electrons in the unbonded, neutral state. Therefore, the carbon atom in chloromethane has a formal charge of zero.arrow_forwardWhy are some bonds ionic and some covalent?arrow_forward
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