Organic And Biological Chemistry
Organic And Biological Chemistry
7th Edition
ISBN: 9781305081079
Author: STOKER, H. Stephen (howard Stephen)
Publisher: Cengage Learning,
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Concept explainers

Introduction to Organic Chemistry
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Vinyl Group
Vinyl group is the name given to the functional group of -CH=CH2. It can be seen as an ethene molecule with one less hydrogen in number. Hence it is also called as ethenyl group at times.
Straight Chain Hydrocarbons
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Unsaturated Hydrocarbon
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Conjugated Compounds in Organic Chemistry
The delocalization of electrons in a molecule is called conjugation in organic chemistry. This delocalisation process of electrons leads to the shortenings or elongations of chemical bonds, but at the same time it causes changes in the chemical propertie…
Alpha Carbon And Alpha Protons
The carbon directly attached to the functional group in an organic molecule is referred to as the alpha carbon and the hydrogen attached to an alpha carbon are termed as the alpha hydrogens or alpha protons. These alpha carbon atoms and alpha hydrogen at…
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Chapter 5, Problem 5.145EP

(a)

Interpretation Introduction

Interpretation:

Condensed structural formula for propionyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.145EP , additional homework tip 1

The structure of the acid chloride can be derived from the IUPAC name or common name.  “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained.  Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

(b)

Interpretation Introduction

Interpretation:

Condensed structural formula for 3-methylbutanoyl chloride has to be drawn.

Concept Introduction:

General structure of acid chloride can be represented as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.145EP , additional homework tip 2

The structure of the acid chloride can be derived from the IUPAC name or common name.  “R” group present in the above structure is a part of the parent carboxylic acid from which the acid chloride is obtained.  Name of the acid chloride is obtained by replacing “-oic acid” in the parent carboxylic acid name with “-oyl chloride”.

(c)

Interpretation Introduction

Interpretation:

Condensed structural formula for butyric anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.145EP , additional homework tip 3

The structure of the acid anhydride can be derived from the IUPAC name or common name.  “R, R1” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained.  If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride.  If the acid anhydride is an asymmetric one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

(d)

Interpretation Introduction

Interpretation:

Condensed structural formula for butanoic ethanoic anhydride has to be drawn.

Concept Introduction:

General structure of acid anhydride can be represented as shown below,

Organic And Biological Chemistry, Chapter 5, Problem 5.145EP , additional homework tip 4

The structure of the acid anhydride can be derived from the IUPAC name or common name.  “R, R1” group present in the above structure is a part of the parent carboxylic acid from which the acid anhydride is obtained.  If the acid anhydride is a symmetric one, then the name of acid anhydride is given by replacing the acid in the parent carboxylic acid name with anhydride.  If the acid anhydride is an mixed one, then the name of acid anhydride is given by using the name of individual carboxylic acid in an alphabetical order followed by anhydride.

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Chapter 5 Solutions

Organic And Biological Chemistry

Ch. 5.1 - Prob. 1QQCh. 5.1 - Prob. 2QQCh. 5.1 - Prob. 3QQCh. 5.1 - Prob. 4QQCh. 5.1 - Prob. 5QQCh. 5.2 - Prob. 1QQCh. 5.2 - Prob. 2QQCh. 5.2 - Prob. 3QQCh. 5.2 - Prob. 4QQCh. 5.2 - Prob. 5QQ
Ch. 5.3 - Prob. 1QQCh. 5.3 - Prob. 2QQCh. 5.3 - Prob. 3QQCh. 5.4 - Prob. 1QQCh. 5.4 - Prob. 2QQCh. 5.4 - Prob. 3QQCh. 5.5 - Prob. 1QQCh. 5.5 - Prob. 2QQCh. 5.5 - Prob. 3QQCh. 5.6 - Prob. 1QQCh. 5.6 - Prob. 2QQCh. 5.7 - Which of the following statements about acid...Ch. 5.7 - Prob. 2QQCh. 5.7 - Prob. 3QQCh. 5.8 - Prob. 1QQCh. 5.8 - Prob. 2QQCh. 5.8 - Prob. 3QQCh. 5.8 - Prob. 4QQCh. 5.9 - Prob. 1QQCh. 5.9 - Prob. 2QQCh. 5.10 - Prob. 1QQCh. 5.10 - Prob. 2QQCh. 5.11 - Prob. 1QQCh. 5.11 - Prob. 2QQCh. 5.11 - Prob. 3QQCh. 5.12 - Prob. 1QQCh. 5.12 - Prob. 2QQCh. 5.12 - Prob. 3QQCh. 5.12 - Prob. 4QQCh. 5.13 - Prob. 1QQCh. 5.13 - Prob. 2QQCh. 5.14 - Prob. 1QQCh. 5.14 - Prob. 2QQCh. 5.14 - Prob. 3QQCh. 5.15 - Prob. 1QQCh. 5.15 - Prob. 2QQCh. 5.15 - Prob. 3QQCh. 5.16 - Prob. 1QQCh. 5.16 - Prob. 2QQCh. 5.16 - Prob. 3QQCh. 5.17 - Prob. 1QQCh. 5.17 - Prob. 2QQCh. 5.18 - Prob. 1QQCh. 5.18 - Prob. 2QQCh. 5.18 - Prob. 3QQCh. 5.19 - Prob. 1QQCh. 5.19 - Prob. 2QQCh. 5.19 - Prob. 3QQCh. 5.19 - Prob. 4QQCh. 5.20 - Prob. 1QQCh. 5.20 - Prob. 2QQCh. 5.20 - Prob. 3QQCh. 5.20 - Prob. 4QQCh. 5 - Prob. 5.1EPCh. 5 - Prob. 5.2EPCh. 5 - Prob. 5.3EPCh. 5 - Indicate whether or not each of the compounds in...Ch. 5 - Prob. 5.5EPCh. 5 - Prob. 5.6EPCh. 5 - Prob. 5.7EPCh. 5 - Prob. 5.8EPCh. 5 - Prob. 5.9EPCh. 5 - Prob. 5.10EPCh. 5 - Prob. 5.11EPCh. 5 - Prob. 5.12EPCh. 5 - Prob. 5.13EPCh. 5 - Prob. 5.14EPCh. 5 - Prob. 5.15EPCh. 5 - Assign an IUPAC name to each of the following...Ch. 5 - Prob. 5.17EPCh. 5 - Prob. 5.18EPCh. 5 - Prob. 5.19EPCh. 5 - Prob. 5.20EPCh. 5 - Prob. 5.21EPCh. 5 - Prob. 5.22EPCh. 5 - Prob. 5.23EPCh. 5 - Prob. 5.24EPCh. 5 - Prob. 5.25EPCh. 5 - Prob. 5.26EPCh. 5 - Prob. 5.27EPCh. 5 - Prob. 5.28EPCh. 5 - Prob. 5.29EPCh. 5 - Prob. 5.30EPCh. 5 - Prob. 5.31EPCh. 5 - Prob. 5.32EPCh. 5 - Prob. 5.33EPCh. 5 - Prob. 5.34EPCh. 5 - Prob. 5.35EPCh. 5 - Prob. 5.36EPCh. 5 - Prob. 5.37EPCh. 5 - Prob. 5.38EPCh. 5 - Prob. 5.39EPCh. 5 - Prob. 5.40EPCh. 5 - Determine the maximum number of hydrogen bonds...Ch. 5 - Prob. 5.42EPCh. 5 - Prob. 5.43EPCh. 5 - Prob. 5.44EPCh. 5 - Prob. 5.45EPCh. 5 - Prob. 5.46EPCh. 5 - Prob. 5.47EPCh. 5 - Prob. 5.48EPCh. 5 - Prob. 5.49EPCh. 5 - Prob. 5.50EPCh. 5 - Prob. 5.51EPCh. 5 - Prob. 5.52EPCh. 5 - Prob. 5.53EPCh. 5 - Prob. 5.54EPCh. 5 - Draw structural formulas for the following...Ch. 5 - Prob. 5.56EPCh. 5 - Give the IUPAC name for each of the following...Ch. 5 - Give the IUPAC name for each of the following...Ch. 5 - Prob. 5.59EPCh. 5 - Prob. 5.60EPCh. 5 - Prob. 5.61EPCh. 5 - Prob. 5.62EPCh. 5 - Prob. 5.63EPCh. 5 - Prob. 5.64EPCh. 5 - Prob. 5.65EPCh. 5 - Which three carboxylic acids have salts that are...Ch. 5 - Prob. 5.67EPCh. 5 - Which carboxylic acid has salts that are used to...Ch. 5 - Prob. 5.69EPCh. 5 - Prob. 5.70EPCh. 5 - Prob. 5.71EPCh. 5 - Prob. 5.72EPCh. 5 - Prob. 5.73EPCh. 5 - Prob. 5.74EPCh. 5 - Prob. 5.75EPCh. 5 - Prob. 5.76EPCh. 5 - Prob. 5.77EPCh. 5 - Prob. 5.78EPCh. 5 - Prob. 5.79EPCh. 5 - Prob. 5.80EPCh. 5 - Prob. 5.81EPCh. 5 - Prob. 5.82EPCh. 5 - Prob. 5.83EPCh. 5 - Prob. 5.84EPCh. 5 - Prob. 5.85EPCh. 5 - Prob. 5.86EPCh. 5 - Prob. 5.87EPCh. 5 - Prob. 5.88EPCh. 5 - Prob. 5.89EPCh. 5 - Prob. 5.90EPCh. 5 - Assign common names to each of the esters in...Ch. 5 - Prob. 5.92EPCh. 5 - Prob. 5.93EPCh. 5 - Assign an IUPAC name to each of the following...Ch. 5 - Draw a structural formula for each of the...Ch. 5 - Prob. 5.96EPCh. 5 - Prob. 5.97EPCh. 5 - Prob. 5.98EPCh. 5 - Prob. 5.99EPCh. 5 - Prob. 5.100EPCh. 5 - Prob. 5.101EPCh. 5 - How many carbon atoms are present in a molecule of...Ch. 5 - Prob. 5.103EPCh. 5 - Prob. 5.104EPCh. 5 - Prob. 5.105EPCh. 5 - Prob. 5.106EPCh. 5 - Prob. 5.107EPCh. 5 - Prob. 5.108EPCh. 5 - Prob. 5.109EPCh. 5 - Prob. 5.110EPCh. 5 - Prob. 5.111EPCh. 5 - Prob. 5.112EPCh. 5 - Prob. 5.113EPCh. 5 - Prob. 5.114EPCh. 5 - Prob. 5.115EPCh. 5 - Prob. 5.116EPCh. 5 - Prob. 5.117EPCh. 5 - Prob. 5.118EPCh. 5 - Prob. 5.119EPCh. 5 - Prob. 5.120EPCh. 5 - Prob. 5.121EPCh. 5 - Prob. 5.122EPCh. 5 - Prob. 5.123EPCh. 5 - Prob. 5.124EPCh. 5 - Write the structural formulas of the reaction...Ch. 5 - Prob. 5.126EPCh. 5 - Prob. 5.127EPCh. 5 - Prob. 5.128EPCh. 5 - Prob. 5.129EPCh. 5 - Prob. 5.130EPCh. 5 - Prob. 5.131EPCh. 5 - Prob. 5.132EPCh. 5 - Prob. 5.133EPCh. 5 - Prob. 5.134EPCh. 5 - Prob. 5.135EPCh. 5 - Prob. 5.136EPCh. 5 - Prob. 5.137EPCh. 5 - Prob. 5.138EPCh. 5 - Prob. 5.139EPCh. 5 - Prob. 5.140EPCh. 5 - Prob. 5.141EPCh. 5 - Prob. 5.142EPCh. 5 - Prob. 5.143EPCh. 5 - Prob. 5.144EPCh. 5 - Prob. 5.145EPCh. 5 - Prob. 5.146EPCh. 5 - Prob. 5.147EPCh. 5 - Prob. 5.148EPCh. 5 - Draw a condensed structural formula for the...Ch. 5 - Draw a condensed structural formula for the...Ch. 5 - Prob. 5.151EPCh. 5 - Prob. 5.152EPCh. 5 - Prob. 5.153EPCh. 5 - Prob. 5.154EPCh. 5 - Prob. 5.155EPCh. 5 - Prob. 5.156EPCh. 5 - Prob. 5.157EPCh. 5 - Prob. 5.158EPCh. 5 - Prob. 5.159EPCh. 5 - Prob. 5.160EPCh. 5 - Prob. 5.161EPCh. 5 - Prob. 5.162EPCh. 5 - Prob. 5.163EPCh. 5 - Prob. 5.164EP
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