Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 3, Problem 3.7P
Interpretation Introduction
(a)
Interpretation:
The curved-arrow mechanism, nucleophile, the nucleophilic center, the electrophile, the electrophilic center, and the leaving group are to be stated for the given reaction. The analogous Brønsted acid-base reaction and the Brønsted acid and Brønsted base of the final product are to be stated.
Concept introduction:
Brønsted bases are those species which accept a proton. They are also known as proton acceptor. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. They are also known as proton donor. Acid loses a proton and forms conjugate base. The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow. Bronsted acid-base reactions are those reactions in which electron pair displacement takes place and electrophilic center is a proton.
Interpretation Introduction
(b)
Interpretation:
The curved-arrow mechanism, nucleophile, the nucleophilic center, the electrophile, the electrophilic center, and the leaving group are to be stated for the given reaction. The analogous Brønsted acid-base reaction and the Brønsted acid and Brønsted base of the final product are to be stated.
Concept introduction:
Brønsted bases are those species which accept a proton. They are also known as proton acceptor. Base accepts a proton and forms conjugate acid. Brønsted acids are those species which donate a proton. They are also known as proton donor. Acid loses a proton and forms conjugate base. The curved-arrow notation is used to show the transfer of electrons from one atom to another. The curved arrow has two barbs (head and tail) which represent the direction of electron flow. Bronsted acid-base reactions are those reactions in which electron pair displacement takes place and electrophilic center is a proton.
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6. Consider the following exothermic reaction below.
2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq)
a. If Cul is added, there will be a shift left/shift right/no shift (circle one).
b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one).
c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one).
d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle
one). Hint: one of the reaction species is more soluble in hexane than in water.
e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one).
f. Which of the changes above will change the equilibrium constant, K?
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Chapter 3 Solutions
Organic Chemistry
Ch. 3 - Prob. 3.1PCh. 3 - Prob. 3.2PCh. 3 - Prob. 3.3PCh. 3 - Prob. 3.4PCh. 3 - Prob. 3.5PCh. 3 - Prob. 3.6PCh. 3 - Prob. 3.7PCh. 3 - Prob. 3.8PCh. 3 - Prob. 3.9PCh. 3 - Prob. 3.10P
Ch. 3 - Prob. 3.11PCh. 3 - Prob. 3.12PCh. 3 - Prob. 3.13PCh. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Prob. 3.16PCh. 3 - Prob. 3.17PCh. 3 - Prob. 3.18PCh. 3 - Prob. 3.19PCh. 3 - Prob. 3.20PCh. 3 - Prob. 3.21PCh. 3 - Prob. 3.22PCh. 3 - Prob. 3.24PCh. 3 - Prob. 3.25PCh. 3 - Prob. 3.26PCh. 3 - Prob. 3.27PCh. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - Prob. 3.30PCh. 3 - Prob. 3.31PCh. 3 - Prob. 3.32APCh. 3 - Prob. 3.33APCh. 3 - Prob. 3.34APCh. 3 - Prob. 3.35APCh. 3 - Prob. 3.36APCh. 3 - Prob. 3.37APCh. 3 - Prob. 3.38APCh. 3 - Prob. 3.39APCh. 3 - Prob. 3.40APCh. 3 - Prob. 3.41APCh. 3 - Prob. 3.42APCh. 3 - Prob. 3.43APCh. 3 - Prob. 3.44APCh. 3 - Prob. 3.45APCh. 3 - Prob. 3.46APCh. 3 - Prob. 3.47APCh. 3 - Prob. 3.48APCh. 3 - Prob. 3.49APCh. 3 - Prob. 3.50APCh. 3 - Prob. 3.51APCh. 3 - Prob. 3.52APCh. 3 - Prob. 3.53APCh. 3 - Prob. 3.54APCh. 3 - Prob. 3.55APCh. 3 - Prob. 3.56APCh. 3 - Prob. 3.57APCh. 3 - Prob. 3.58APCh. 3 - Prob. 3.59APCh. 3 - Prob. 3.60AP
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