(a) Interpretation: The bond dissociation energy of H − At with H − I is to be compared. Concept introduction: The elements in a modern periodic table are arranged in an increasing order of their atomic number . In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

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Answer 1

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Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

Answer 2

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

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Answer 3

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

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Answer 4

Question

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

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See solution

Answer 5

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 6

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 7

Chapter 3, Problem 3.60AP

Interpretation Introduction

(a)

Interpretation:

The bond dissociation energy of H−At with H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The electron affinity of At and I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The dissociation constant of H−At and H−I is to be compared.

Concept introduction:

The elements in a modern periodic table are arranged in an increasing order of their atomic number. In the modern periodic table, the horizontal rows are known as periods and vertical columns are known as groups. There are 7 periods and 18 groups in modern periodic table.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 3 - Prob. 3.1P Ch. 3 - Prob. 3.2P Ch. 3 - Prob. 3.3P Ch. 3 - Prob. 3.4P Ch. 3 - Prob. 3.5P Ch. 3 - Prob. 3.6P Ch. 3 - Prob. 3.7P Ch. 3 - Prob. 3.8P Ch. 3 - Prob. 3.9P Ch. 3 - Prob. 3.10P

Solution Summary: The author explains that the bond dissociation energy of H- At is less than the strength of bond between two atoms in the chemical reaction.

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