Biochemistry: Concepts and Connections (2nd Edition)
Biochemistry: Concepts and Connections (2nd Edition)
2nd Edition
ISBN: 9780134641621
Author: Dean R. Appling, Spencer J. Anthony-Cahill, Christopher K. Mathews
Publisher: PEARSON
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Chapter 3, Problem 10P

Suppose a reaction has Δ Ho and Δ So values independent of temperature (i.e., assume these values are constant over some range of temperature). Show from this, and the equations given in this chapter, that ln K = -ΔH o RT + ΔS o R where K is the equilibrium constant. How could you use values of K determined at different temperatures to determine ΔH o for the reaction? (Hint. Recall that you are treating ΔH o and ΔS o as constants.)

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For a particular reaction, AH° = −16.1 kJ/mol and AS° = −21.8 J/(mol·K). Assuming these values change very little with temperature, at what temperature does the reaction change from nonspontaneous to spontaneous in the forward direction? OT= Is the reaction in the forward direction spontaneous at temperatures greater than or less than the calculated temperature? less than greater than K
For the following first-order liquid-phase reversible reaction, where initially only reactant A is present: k₁ AR, k2 Equilibrium constant: K 1) Express the equilibrium conversion rate, Xe, using K, and demonstrate that Xe can be determined using thermodynamic data. 2) Show how the rate constants kl and k2 can be determined experimentally.
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