Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 28, Problem 23P
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(b) 
(c)
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the reaction C3H6 + H2 = C3H8 is:
a) replacement
b) additions
c) polymerization
d) esterification
What kinds of ions govern alkylation and polymerization reactions and how they are initiated?
(a) Draw the structure of polystyrene, the chapter-opening molecule, which is formed by polymerizing the monomer styrene, C6H5CH = CH2. (b) What monomer is used to form poly(vinyl acetate), a polymer used in paints and adhesives?
Chapter 28 Solutions
Organic Chemistry - Standalone book
Ch. 28.2 - Prob. 1PCh. 28.3 - Prob. 2PCh. 28.3 - Prob. 3PCh. 28.4 - Prob. 4PCh. 28.7 - Problem 28.5 (a) Write a chemical equation for the...Ch. 28.7 - Prob. 6PCh. 28.8 - Prob. 7PCh. 28.9 - Problem 28.8 How will the average chain length of...Ch. 28.9 - Prob. 9PCh. 28.11 - Prob. 10P
Ch. 28.11 - Prob. 11PCh. 28.12 - Prob. 12PCh. 28.13 - Prob. 13PCh. 28.14 - Prob. 14PCh. 28 - Prob. 15PCh. 28 - Prob. 16PCh. 28 - Prob. 17PCh. 28 - Prob. 18PCh. 28 - Prob. 19PCh. 28 - Prob. 20PCh. 28 - Of the following monomers, which one would undergo...Ch. 28 - Prob. 22PCh. 28 - Polymerization of styrene can occur by a...Ch. 28 - Styrene undergoes anionic polymerization at a...Ch. 28 - Prob. 25PCh. 28 - Prob. 26PCh. 28 - Prob. 27PCh. 28 - Prob. 28PCh. 28 - Prob. 29PCh. 28 - Prob. 30PCh. 28 - Prob. 31PCh. 28 - Prob. 32DSPCh. 28 - Prob. 33DSPCh. 28 - Prob. 34DSPCh. 28 - Prob. 35DSPCh. 28 - Prob. 36DSPCh. 28 - Prob. 37DSPCh. 28 - Prob. 38DSP
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- The polymerization of propene, CH₂CH=CH₂, can be classified as An addition reaction An elimination reaction A substitution reaction A condensation reactionarrow_forwardThe ε-caprolactone monomer from which the biopolymer polycaprolactone (PCL) is synthesized is depicted below. (a) What is the monomer's function? (b) What is the polymerization mechanism that results in the formation of PCL? (c) Define/Illustrate the homopolymer's repeating unit provided that the functional group is placed at the hydrocarbon chain's terminal position.arrow_forwardDiscuss FOUR (4) differences between addition polymerization and condensation polymerization.arrow_forward
- You were asked to prepare (a) poly(2-hexene) and (b) acrylonitrile Draw the reactants and products. What initiator (cationic or anionic) would you choose for each of them? Explain your answer!arrow_forward7cd (JUST SIMPLY ANSWER THE QUESTION BELOW) 1. Why are olefins (alkanes) good monomers for polymerization reaction? 2. "Co-polymers" consist of two different monomers ("A" and "B") joined in an alternating fashion (ABABAB...). Block co-polymers also consist of two different monomers, but in this case, blocks of polymer containing only A units are joined to blocks of polymer containing only B units (AAAAABBBBB...). How block co-polymers are synthesized?arrow_forwardOlefin polymerization is responsible for producing over 100 million tons per year of plastic material. (a) Briefly describe the type of catalysts used in the transition metal catalysed homogeneous polymerization reactions. (b) How are the catalysts activated? (c) Draw the active catalyst, and indicate how the polymer chain is propagated. (d) Suggest a possible chain termination step. (e) Certain single-site catalysts are capable of selectively forming different types of polypropylene. Describe these different types of polymer, and the characteristics of the catalysts that form them.arrow_forward
- When aniline, C6H5NH2(Kb=7.41010) , reacts with a strong acid, its conjugate acid, C6H5NH3+, is formed. Calculate the pH of a 0.100 M solution of C6H5NH3+ and compare it with the pH of acetic acid (Ka=1.86105) .arrow_forwardTeflon can be made from tetrafluoroethylene by means of a free radical polymerization. In the reaction, termination occurs only by combination and not by disproportionation. Explain this observation.arrow_forwardThe monomer glycine (NH2-CH2-COOH) can undergo condensation polymerization to form polyglycine, in which the structural units are joined by amide linkages.(a) What molecule is split off in the formation of polyglycine?(b) Draw the structure of the repeat unit in polyglycine.arrow_forward
- 2. Obtain an equation describing how the degree of polymerization, which represents the average number of monomer residues in each polymer molecule, changes with time in a condensation polymerization reaction. In this scenario, the reaction follows a rate law given by d[M]/dt = -k[M]3, where [M] signifies the monomer concentration.arrow_forwardWrite the repeating units expected from the following polymerization reactions: (c) O= -O+HOCH₂CH₂OCH₂CH₂OHarrow_forward(c) Compare and contrast the physical properties and mechanical behavior of typical polymers in the following classes of materials: (i) flexible plastics (ii) rigid plastics (iii) fibers (iv) elastomersarrow_forward
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