Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 28.11, Problem 11P
Interpretation Introduction
Interpretation: The repeating unit of Nomex has to be stated.
Concept introduction:
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7.) Draw an arrow pushing mechanism for termination by disproportionation of polystyrene.
NC
Ph Ph
NC
Ph
Ph
Multiple Choice question
a peptide bond forms when an amino group attacks .......... group ?
(a) N-glycosidic
(b) sulfhydril
(c) acyl
(d) enol
(e) phosphate
29.
30.
Which of the following classes of organic compounds does not contain oxygen?
a. aldehydes
b. amines
c. amino acids
The sequence of reactions shown here is best described as which of the following?
H₂C=CH₂
CH₂CH₂OH
d. ethers
e. amides
1.
* CH3CH3-
2.
→→CH₂CH₂Br
3.
a. (1) Dehydration; (2)substitution; (3) hydrogenation
b. (1) Hydrogenation; (2) dehydration; (3) substitution
c. (1) Hydrogenation; (2) substitution; (3) dehydration
d. (1) Substitution; (2) hydrogenation; (3) dehydration
e. (1) Dehydration; (2) hydrogenation; (3) substitution
Chapter 28 Solutions
Organic Chemistry - Standalone book
Ch. 28.2 - Prob. 1PCh. 28.3 - Prob. 2PCh. 28.3 - Prob. 3PCh. 28.4 - Prob. 4PCh. 28.7 - Problem 28.5 (a) Write a chemical equation for the...Ch. 28.7 - Prob. 6PCh. 28.8 - Prob. 7PCh. 28.9 - Problem 28.8 How will the average chain length of...Ch. 28.9 - Prob. 9PCh. 28.11 - Prob. 10P
Ch. 28.11 - Prob. 11PCh. 28.12 - Prob. 12PCh. 28.13 - Prob. 13PCh. 28.14 - Prob. 14PCh. 28 - Prob. 15PCh. 28 - Prob. 16PCh. 28 - Prob. 17PCh. 28 - Prob. 18PCh. 28 - Prob. 19PCh. 28 - Prob. 20PCh. 28 - Of the following monomers, which one would undergo...Ch. 28 - Prob. 22PCh. 28 - Polymerization of styrene can occur by a...Ch. 28 - Styrene undergoes anionic polymerization at a...Ch. 28 - Prob. 25PCh. 28 - Prob. 26PCh. 28 - Prob. 27PCh. 28 - Prob. 28PCh. 28 - Prob. 29PCh. 28 - Prob. 30PCh. 28 - Prob. 31PCh. 28 - Prob. 32DSPCh. 28 - Prob. 33DSPCh. 28 - Prob. 34DSPCh. 28 - Prob. 35DSPCh. 28 - Prob. 36DSPCh. 28 - Prob. 37DSPCh. 28 - Prob. 38DSP
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- 28. 1 || -C-N- The functional group above is referred to as a(n) O amine O amide O acid anhydride Oester 29. The chemical "messengers" between nerve cells that transmit nearrow_forward32) What is the full structure of the naturally occurring polypeptide from protein that contains: C-V-D-V-A-C and draw the appropriate amide (polypeptide) bonds and or complete structure? Chap 26 new/relateoarrow_forward22.46 (a&d only)arrow_forward
- How many different tetrapeptides can be made under the following conditions? Q.) The tetrapeptide contains one unit each of Asp, Glu, Pro, and Phe.arrow_forwardIdentify the class of polymer, based on functional groups, for the polymers in Problems 26.43 and 26.48.arrow_forwardUrylon fibers are used in premium fishing nets because the polymer is relatively stable to UV light and aqueous acid and base. Urylon has the structure shown. What functional group is contained in the Urylon structure?arrow_forward
- Which isomer—(R)-alanine or (S)-alanine—is d-alanine? a. Which isomer—(R)-aspartate or (S)-aspartate—is d-aspartate? b. Can a general statement be made relating R and S to d and l?arrow_forward2. In the synthesis of peptides, carboxylic acids are condensed with amines in the present of a reagent such as dicyclohexylcarbodiimide (DCC) [Section 25.6]. a. Propose a mechanism for the following, using curved arrow notation. H₂N. glycine OH H₂N 요. glycine OH DCC H₂N. N H gly-gly LOHarrow_forwardThe strongest non-covalent interactions are A) van der Waals interactions B) London dispersion forces C) hydrogen bonds D) dipole-dipole interactions E) ionic interactions Which of the following amino acids has a positively charged side chain? A) Glu B) Ala C) Lys D) Leu E) His Disulfide bonds form between two residues of which amino acid? A) Met B) Ser C) Asn D) Thr E) Cys. Based upon its side chain, how is the amino acid Ser classified? A) non-polar B) polar C) positively charged D) negatively charged E) none of these choicesarrow_forward
- The amino acid (S)-alanine has the physical characteristics listed under the structure. ÇOOH a. What is the melting point of (R)-alanine? b. How does the melting point of a racemic mixture of (R)- and (S)-alanine compare to the melting point of (S)-alanine? c. What is the specific rotation of (A)-alanine, recorded under the same conditions as the reported rotation of (S)-alanine? d. What is the optical rotation of a racemic mixture of (R)- and (S)-alanine? e. Label each of the following as optically active or inactive: a solution of pure (S)-alanine; an equal mixture of (R)- and (S)-alanine; a solution that contains 75% (S)- and 25% (R)-alanine. CH NH2 (S)-alanine [a) = +8.5 mp = 297 °Carrow_forward22-47 How many different tetrapeptides can be made (a) if the peptides contain the residues of asparagine, proline, serine, and metbionine and (b) if all 20 amino acids can be used?arrow_forwardProteins are polymers made up of monomers called amino acids.: 1. Amino Acid Structure H. H-N-C-C-OH Amino Carboxyl Group Group Side Chain a) Draw the rcaction that links two amino acids together for the polymerization of proteins. Carrow_forward
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