Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
8th Edition
ISBN: 9780134015187
Author: John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. Peterson
Publisher: PEARSON
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Chapter 23, Problem 23.24UKC
According to the fluid-mosaic model (Figure 23.7), the cell membrane is held together mostly by hydrophobic interactions. Considering the forces applied, why does the cell membrane not rupture as you move, press against objects, etc.?
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In an experiment, a 0.001 (mole fraction) solution of polysaccharide in water is made and is placed in the compartment A (see Figure below). Compartment B is filled with pure water. The two compartments are separated by a porous semi-permeable membrane that allows the exchange of water molecules between the two compartments, but not that of the larger polysaccharide molecules
a) Show that the chemical potential of water in compartment A is lower than that in compartment B by 2.48 J/mol.
b) As a result of this chemical potential difference, water molecules will move from compartment B to compartment A. This causes the pressure in compartment A, relative to that in B, to increase. How would this affect the chemical potential of water in compartment B? When would the diffusion of water from B to A cease (i.e. equilibrium is achieved)?
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The intracellular salt content of a red blood cell is about 150 mM. The cell is put in a 500 mM salt beaker. (a) Describe what will happen to the cell in terms of osmosis if the cell membrane is permeable to water but not to ions. (b) Which direction would solutes diff use if the membrane was permeable to ions: into or out of the cell?
Chapter 23 Solutions
Fundamentals of General, Organic, and Biological Chemistry (8th Edition)
Ch. 23.1 - Use Figure 23.1 to identify the family of lipids...Ch. 23.2 - Prob. 23.2PCh. 23.2 - Prob. 23.3PCh. 23.2 - Prob. 23.4KCPCh. 23.3 - Prob. 23.1CIAPCh. 23.3 - Prob. 23.2CIAPCh. 23.3 - Prob. 23.3CIAPCh. 23.3 - Prob. 23.5PCh. 23.3 - Prob. 23.6PCh. 23.3 - Prob. 23.7KCP
Ch. 23.4 - Prob. 23.8PCh. 23.4 - Prob. 23.9PCh. 23.4 - Prob. 23.10PCh. 23.4 - Prob. 23.11PCh. 23.5 - Prob. 23.12PCh. 23.5 - Draw the structure of the sphingomyelin that...Ch. 23.5 - Draw the structure of the glycerophospholipid that...Ch. 23.5 - Prob. 23.16PCh. 23.7 - Prob. 23.17KCPCh. 23.7 - Prob. 23.4CIAPCh. 23.7 - Prob. 23.6CIAPCh. 23.7 - Prob. 23.7CIAPCh. 23.7 - Prob. 23.8CIAPCh. 23.7 - Prob. 23.18PCh. 23.7 - Prob. 23.19PCh. 23.7 - Prob. 23.20KCPCh. 23 - The fatty acid composition of three...Ch. 23 - Prob. 23.23UKCCh. 23 - According to the fluid-mosaic model (Figure 23.7),...Ch. 23 - Dipalmitoylphosphatidylcholine (DPPC) is a...Ch. 23 - Prob. 23.26APCh. 23 - Prob. 23.27APCh. 23 - Prob. 23.28APCh. 23 - Prob. 23.29APCh. 23 - Differentiate between saturated, monounsaturated,...Ch. 23 - Are the carboncarbon double bonds in naturally...Ch. 23 - Prob. 23.32APCh. 23 - Prob. 23.33APCh. 23 - Which of these fatty acids has the lower melting...Ch. 23 - Which of these fatty acids has the higher melting...Ch. 23 - Prob. 23.36APCh. 23 - Prob. 23.37APCh. 23 - Prob. 23.38APCh. 23 - Prob. 23.39APCh. 23 - What function does a wax serve in a plant or...Ch. 23 - Prob. 23.41APCh. 23 - Prob. 23.42APCh. 23 - What kind of lipid is spermacetia fat, a wax, or a...Ch. 23 - Prob. 23.44APCh. 23 - Prob. 23.45APCh. 23 - Prob. 23.46APCh. 23 - Prob. 23.47APCh. 23 - Prob. 23.48APCh. 23 - Prob. 23.50APCh. 23 - Prob. 23.52APCh. 23 - Prob. 23.53APCh. 23 - Describe the difference between a triacylglycerol...Ch. 23 - Why are glycerophospholipids, rather than...Ch. 23 - Prob. 23.56APCh. 23 - Prob. 23.57APCh. 23 - Why are glycerophospholipids more soluble in water...Ch. 23 - Prob. 23.59APCh. 23 - Prob. 23.60APCh. 23 - Prob. 23.61APCh. 23 - Draw the structure of a glycerophospholipid that...Ch. 23 - Prob. 23.63APCh. 23 - What is a major function of cholesterol in your...Ch. 23 - Prob. 23.65APCh. 23 - Prob. 23.66APCh. 23 - Prob. 23.67APCh. 23 - Explain how a micelle differs from a membrane...Ch. 23 - Prob. 23.69APCh. 23 - Prob. 23.70APCh. 23 - Prob. 23.71APCh. 23 - Prob. 23.72APCh. 23 - Prob. 23.73APCh. 23 - Prob. 23.74APCh. 23 - Prob. 23.75APCh. 23 - Draw the structure of a triacylglycerol made from...Ch. 23 - Prob. 23.79CPCh. 23 - Prob. 23.80CPCh. 23 - Explain why cholesterol is not saponifiable.Ch. 23 - Draw cholesterol acetate. Is this molecule...Ch. 23 - Prob. 23.83CPCh. 23 - Prob. 23.84CPCh. 23 - Prob. 23.85CPCh. 23 - Prob. 23.86CPCh. 23 - Prob. 23.88GP
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- Ms. Sassa, a biology professor, wanted to demonstrate to her students the applicability of a dialyzing membrane (DM) as a model for the cell membrane by enclosing an aqueous solution in a DM bag and immersing in a beaker containing a different solution. Substances available which are permeable to the DM include 0.02 M NaCl, 0.03 M glucose, and 0.01 M glucose. The only substance available which is completely impermeable to the DM is the 0.01 M lactose. Using the substances given and materials such as a beaker, stirring rod, and string, draw ONLY ONE set-up that can be demonstrated by Ms. Sassa that will satisfy ALL of the following conditions: a. No solute will exhibit a net diffusion out of the cell. b. Glucose will exhibit a net diffusion into the cell. c. NaCl will exhibit a zero net movement. d. No net movement of lactose from the inside to outside of the cell. Make sure to label properly the substance inside the beaker and inside the DM bag.arrow_forwardA red blood cell has an internal salt concentration of ∼150 mM. The cell is placed in a beaker of 500 mM salt. Solve, (a) Assuming the cell membrane is permeable to water but not to ions, describe what will happen to the cell in terms of osmosis. (b) If the membrane were permeable to ions, in which direction would solutes diff use: into or out of the cell?arrow_forwardList the following compounds in order of increasing lipid bilayer permeability: RNA, Ca2+, glucose, ethanol, n2, water.arrow_forward
- In an experiment, a 0.001 (mole fraction) solution of polysaccharide in water is made and is placed in the compartment A. Compartment B is filled with pure water. The two compartments are separated by a porous semi-permeable membrane that allows the exchange of water molecules between the two compartments, but not that of the larger polysaccharide molecules. part 1: Show that the chemical potential of water in compartment A is lower than that in compartment B by 2.48 J/mol.arrow_forwardAn osmotic semipermeable membrane that allows only water to pass separates two compartments, A and B. Compartment A contains 0.9% NaCl, and compartment B contains 3% glycerol, C3H8O3. (a) In which compartment will the level of solution rise? (b) Which compartment has the higher osmotic pressure (if either)?arrow_forward(a) Describe permeability of a phospholipid bilayer for the following molecules. Use terms: non-permeable, high permeability, medium permeability. N2, O2, Na+, glucose, sucrose (disaccharide), glycogen, H2O, KCl, K+, Mg2+, glycine and protein (b) Discuss the role of carbonic anhydrase in CO2 transport. (c) Discuss the cause of ‘cold denaturation’ of proteins.arrow_forward
- Below are listed molecules with different chemical characteristics. Knowing that all molecules will eventually diffuse across a phospholipid bilayer, select the list that most accurately predicts the relative rates of diffusion of these molecules (fastest to slowest) across a biological membrane. alanine, propanol, sodium, estrogen sodium, propanol, alanine, estrogen estrogen, propanol, sodium, alanine estrogen, propanol, alanine, sodiumarrow_forwardIn an investigation of osmosis, apple cores were submerged in different molarity solutions to determine the unknown osmolarity of the apple. To determine the molarity five uniform apple cores were massed before submerging them in different molarity solutions. After 24 hours the apple cores were massed again. Then the percent change in mass was determined for the five uniform apple cores in each molarity solution. (b) Identify the osmolarity of the apple.arrow_forwardThe electrochemical gradient across membranes is important in determining movement across membranes for a certain type(s) of solute. Which kind? Both anions and cations Positively charged (cations) Neutral/uncharged solutes Negatively charged (anions)arrow_forward
- If two solutions separated by a semi-permeable membrane are isotonic, can you conclude that they are in chemical equilibrium?arrow_forwardIn an investigation of osmosis, apple cores were submerged in different molarity solutions to determine the unknown osmolarity of the apple. To determine the molarity five uniform apple cores were massed before submerging them in different molarity solutions. After 24 hours the apple cores were massed again. Then the percent change in mass was determined for the five uniform apple cores in each molarity solution. (c) Describe the environmental conditions taking place in each of the six solutions with the apples refer to picture for tablearrow_forwardThe distribution of water is determined by solute concentrations. A hypertonic solution would cause a body cell to shrink in size. Both statements are true. Both statements are false. The first statement is true and the second statement is false. The first statement is false and the second statement is true. Spaced practice question: Consider a membrane protein and its chemistry. Which of the following would describe a channel protein? It is an inorganic compound. It is an example of a globular (functional) protein. It is stable when exposed to an acidic environment. It is an example of a fibrous (structural) protein.arrow_forward
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The Cell Membrane; Author: The Organic Chemistry Tutor;https://www.youtube.com/watch?v=AsffT7XIXbA;License: Standard youtube license