When aniline is treated with fuming sulfuric acid, meta-product is formed. The reason for this change has to be found. Concept Introduction : An amino group is an ortho-para director. An electrophilic aromatic substitution reaction takes place at ortho- and para- positions when a new group is introduced to benzene ring which contains amino group. An ammonium group is a meta-director. An electrophilic aromatic substitution reaction takes place at meta-position when a new group is introduced to benzene ring which contains ammonium group. Protonated form of ammonia or amino group is called ammonium ion. To find: The reason for the formation of meta-product in the given reaction Find the nature of direction in amino and ammonium groups

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Answer 1

Question

Chapter 22, Problem 50PP

Interpretation Introduction

Interpretation: When aniline is treated with fuming sulfuric acid, meta-product is formed. The reason for this change has to be found.

Concept Introduction:

An amino group is an ortho-para director. An electrophilic aromatic substitution reaction takes place at ortho- and para- positions when a new group is introduced to benzene ring which contains amino group. An ammonium group is a meta-director. An electrophilic aromatic substitution reaction takes place at meta-position when a new group is introduced to benzene ring which contains ammonium group. Protonated form of ammonia or amino group is called ammonium ion.

To find: The reason for the formation of meta-product in the given reaction

Find the nature of direction in amino and ammonium groups

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Answer 2

Question

Chapter 22, Problem 50PP

Interpretation Introduction

Interpretation: When aniline is treated with fuming sulfuric acid, meta-product is formed. The reason for this change has to be found.

Concept Introduction:

An amino group is an ortho-para director. An electrophilic aromatic substitution reaction takes place at ortho- and para- positions when a new group is introduced to benzene ring which contains amino group. An ammonium group is a meta-director. An electrophilic aromatic substitution reaction takes place at meta-position when a new group is introduced to benzene ring which contains ammonium group. Protonated form of ammonia or amino group is called ammonium ion.

To find: The reason for the formation of meta-product in the given reaction

Find the nature of direction in amino and ammonium groups

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Answer 3

Question

Chapter 22, Problem 50PP

Interpretation Introduction

Interpretation: When aniline is treated with fuming sulfuric acid, meta-product is formed. The reason for this change has to be found.

Concept Introduction:

An amino group is an ortho-para director. An electrophilic aromatic substitution reaction takes place at ortho- and para- positions when a new group is introduced to benzene ring which contains amino group. An ammonium group is a meta-director. An electrophilic aromatic substitution reaction takes place at meta-position when a new group is introduced to benzene ring which contains ammonium group. Protonated form of ammonia or amino group is called ammonium ion.

To find: The reason for the formation of meta-product in the given reaction

Find the nature of direction in amino and ammonium groups

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Answer 4

Question

Chapter 22, Problem 50PP

Interpretation Introduction

Interpretation: When aniline is treated with fuming sulfuric acid, meta-product is formed. The reason for this change has to be found.

Concept Introduction:

An amino group is an ortho-para director. An electrophilic aromatic substitution reaction takes place at ortho- and para- positions when a new group is introduced to benzene ring which contains amino group. An ammonium group is a meta-director. An electrophilic aromatic substitution reaction takes place at meta-position when a new group is introduced to benzene ring which contains ammonium group. Protonated form of ammonia or amino group is called ammonium ion.

To find: The reason for the formation of meta-product in the given reaction

Find the nature of direction in amino and ammonium groups

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Answer 5

Chapter 22, Problem 50PP

Interpretation Introduction

Interpretation: When aniline is treated with fuming sulfuric acid, meta-product is formed. The reason for this change has to be found.

Concept Introduction:

An amino group is an ortho-para director. An electrophilic aromatic substitution reaction takes place at ortho- and para- positions when a new group is introduced to benzene ring which contains amino group. An ammonium group is a meta-director. An electrophilic aromatic substitution reaction takes place at meta-position when a new group is introduced to benzene ring which contains ammonium group. Protonated form of ammonia or amino group is called ammonium ion.

To find: The reason for the formation of meta-product in the given reaction

Find the nature of direction in amino and ammonium groups

Answer 6

Chapter 22, Problem 50PP

Interpretation Introduction

Interpretation: When aniline is treated with fuming sulfuric acid, meta-product is formed. The reason for this change has to be found.

Concept Introduction:

An amino group is an ortho-para director. An electrophilic aromatic substitution reaction takes place at ortho- and para- positions when a new group is introduced to benzene ring which contains amino group. An ammonium group is a meta-director. An electrophilic aromatic substitution reaction takes place at meta-position when a new group is introduced to benzene ring which contains ammonium group. Protonated form of ammonia or amino group is called ammonium ion.

To find: The reason for the formation of meta-product in the given reaction

Find the nature of direction in amino and ammonium groups

Answer 7

Chapter 22, Problem 50PP

Interpretation Introduction

Interpretation: When aniline is treated with fuming sulfuric acid, meta-product is formed. The reason for this change has to be found.

Concept Introduction:

An amino group is an ortho-para director. An electrophilic aromatic substitution reaction takes place at ortho- and para- positions when a new group is introduced to benzene ring which contains amino group. An ammonium group is a meta-director. An electrophilic aromatic substitution reaction takes place at meta-position when a new group is introduced to benzene ring which contains ammonium group. Protonated form of ammonia or amino group is called ammonium ion.

To find: The reason for the formation of meta-product in the given reaction

Find the nature of direction in amino and ammonium groups

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 22.2 - Prob. 1LTS Ch. 22.2 - Prob. 1PTS Ch. 22.2 - Prob. 2PTS Ch. 22.3 - Prob. 4CC Ch. 22.3 - Prob. 5CC Ch. 22.3 - Prob. 6CC Ch. 22.3 - Prob. 7CC Ch. 22.3 - Prob. 8CC Ch. 22.3 - Prob. 9CC Ch. 22.4 - Prob. 10CC

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Chapter 22 Solutions