Organic Chemistry - Standalone book
Organic Chemistry - Standalone book
10th Edition
ISBN: 9780073511214
Author: Francis A Carey Dr., Robert M. Giuliano
Publisher: McGraw-Hill Education
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Chapter 21, Problem 49P
Interpretation Introduction

Interpretation:

The reaction that shows the formation of the given compounds by taking 3pentanone as a starting reagent is to be determined.

Concept Introduction:

The γ-lactones are formed by the intramolecular cyclization of the carboxylic esters.

Epoxides are the cyclic compounds which provide a route for the preparation of γ-lactones.

The compounds containing carbonyl groups are attacked by these epoxides which cause the alkylation at the alpha position of the carbonyl compound.

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(a) How will you convert the following :(i) Propanone to Propan-2-ol                (ii) Ethanal to 2-hydroxy propanoic acid(iii) Toluene to benzoic acid(b) Give simple chemical test to distinguish between :(i) Pentan-2-one and Pentan-3-one       (ii) Ethanal and Propanal
Use a Grignard reaction to prepare the following alcohols.   (a) 2-Methyl-2-propanol (b) 1-Methylcyclohexanol (c) 3-Methyl-3-pentanol (d) 2-Phenyl-2-butanol (e) Benzyl alcohol (f) 4-Methyl-1-pentanol
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Chapter 21 Solutions

Organic Chemistry - Standalone book

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