Physical Chemistry
Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 21, Problem 21.14E
Interpretation Introduction

Interpretation:

The number of formula units of ZnSe in a unit cell is to be calculated. The type of cubic unit cell of ZnSe is to be identified.

Concept introduction:

A unit cell of the crystal is the three-dimensional arrangement of the atoms present in the crystal. The unit cell is the smallest and simplest unit of the crystal which on repetition forms an entire crystal. Unit cell can be a cubic unit cell or hexagonal unit cell. The classification of a unit cell depends on the lattice site occupied by the atoms.

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Students have asked these similar questions
1)Pure gold has a density of 19.32 g/cm3, and the atoms are packed in a face-centered cubic crystal lattice. What is the radius of a gold atom in pm? 2)The cubic unit cell parameter (a) of polonium (α-Po) is 335 pm. Use the Goldschmidt correction (Table 1) to calculate a metallic radius for this element.
Copper (Cu) has an fcc structure, where the mass of a Cu atom is 63 in atomic mass units. The density of Cu is 8.9x10³ kgm-³. Tungsten (W) typically has a bcc structure, where the mass of a W atom is 184 in atomic mass units. The density of W is 19.3x10³ kgm-³. (i) Use the above data to find the radius of a Cu atom, and of a W atom. (ii) Which atom has the larger radius, and why? You may use the fact that 1 atomic mass unit is equivalent to 1.66 × 10-27 kg.
Tantalum is a rare, hard, blue-gray, lustrous transition metal that is highly corrosion-resistant. It has a density of 17.6 grams per cubic centimeter and a molecular weight of 185.23 g/mol. What is the atomic radius of Ta if it adopts the body centered cubic unit structure? Express answer in scientific notation (e.g. 3.47e-23).

Chapter 21 Solutions

Physical Chemistry

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