Chemistry
9th Edition
ISBN: 9781133611097
Author: Steven S. Zumdahl
Publisher: Cengage Learning
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Chapter 20, Problem 46E
Interpretation Introduction
Interpretation: The comparison of the Lewis structures with the molecular orbital view of the bonding in
Concept introduction: When the atomic orbitals overlap with each other in the region where density of electrons is high, then molecular orbitals are formed. Overlap of the atomic orbitals determines the efficiency of the interaction between the atomic orbitals.
Energy of bonding molecular orbitals is less than the nonbonding molecular orbitals.
To determine: The comparison of the Lewis structures with the molecular orbital view of the bonding in
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Chapter 20 Solutions
Chemistry
Ch. 20 - What are the two most abundant elements by mass in...Ch. 20 - Prob. 2RQCh. 20 - Prob. 3RQCh. 20 - What is the valence electron configuration for the...Ch. 20 - Prob. 5RQCh. 20 - Prob. 6RQCh. 20 - Table 19-14 lists some common nitrogen compounds...Ch. 20 - Prob. 8RQCh. 20 - Prob. 9RQCh. 20 - Prob. 10RQ
Ch. 20 - Prob. 1QCh. 20 - Prob. 2QCh. 20 - Prob. 3QCh. 20 - Diagonal relationships in the periodic table exist...Ch. 20 - Prob. 6QCh. 20 - Prob. 7QCh. 20 - Prob. 8QCh. 20 - All the Group 1A (1) and 2A (2) metals are...Ch. 20 - Prob. 10QCh. 20 - Prob. 13ECh. 20 - Prob. 14ECh. 20 - Prob. 15ECh. 20 - Prob. 16ECh. 20 - Prob. 17ECh. 20 - Prob. 18ECh. 20 - Prob. 19ECh. 20 - Prob. 20ECh. 20 - Prob. 21ECh. 20 - Electrolysis of an alkaline earth metal chloride...Ch. 20 - Prob. 24ECh. 20 - Prob. 25ECh. 20 - Prob. 26ECh. 20 - Boron hydrides were once evaluated for possible...Ch. 20 - Prob. 28ECh. 20 - Prob. 29ECh. 20 - Prob. 30ECh. 20 - Prob. 31ECh. 20 - Prob. 32ECh. 20 - Prob. 33ECh. 20 - Prob. 34ECh. 20 - The following illustration shows the orbitals used...Ch. 20 - Prob. 36ECh. 20 - Silicon is produced for the chemical and...Ch. 20 - Prob. 38ECh. 20 - The compound Pb3O4 (red lead) contains a mixture...Ch. 20 - Prob. 40ECh. 20 - Prob. 41ECh. 20 - Prob. 42ECh. 20 - Prob. 43ECh. 20 - Prob. 44ECh. 20 - Prob. 45ECh. 20 - Prob. 46ECh. 20 - Prob. 47ECh. 20 - Prob. 48ECh. 20 - Prob. 49ECh. 20 - Phosphate buffers are important in regulating the...Ch. 20 - Prob. 51ECh. 20 - Trisodium phosphate (TSP) is an effective grease...Ch. 20 - Prob. 53ECh. 20 - Prob. 54ECh. 20 - Prob. 55ECh. 20 - Complete and balance each of the following...Ch. 20 - Prob. 57ECh. 20 - Prob. 58ECh. 20 - How can the paramagnetism of O2 be explained using...Ch. 20 - Describe the bonding in SO2 and SO3 using the...Ch. 20 - Write the Lewis structure for O2F2. Predict the...Ch. 20 - Give the Lewis structure, molecular structure, and...Ch. 20 - Prob. 63ECh. 20 - Prob. 64ECh. 20 - Prob. 65ECh. 20 - Prob. 66ECh. 20 - Prob. 67ECh. 20 - Prob. 68ECh. 20 - Prob. 69ECh. 20 - Prob. 70ECh. 20 - Prob. 71ECh. 20 - Prob. 72ECh. 20 - Prob. 73AECh. 20 - The inert-pair effect is sometimes used to explain...Ch. 20 - How could you determine experimentally whether the...Ch. 20 - Prob. 76AECh. 20 - Prob. 77AECh. 20 - Prob. 78AECh. 20 - Prob. 79AECh. 20 - Draw Lewis structures for the AsCl4+ and AsCl6...Ch. 20 - Prob. 81AECh. 20 - Prob. 82AECh. 20 - Prob. 83AECh. 20 - What is a disproportionation reaction? Use the...Ch. 20 - Sulfur forms a wide variety of compounds in which...Ch. 20 - Prob. 86AECh. 20 - Prob. 87CWPCh. 20 - Prob. 88CWPCh. 20 - Prob. 89CWPCh. 20 - Prob. 90CWPCh. 20 - Prob. 91CWPCh. 20 - Nitrous oxide (N2O) can be produced by thermal...Ch. 20 - What is the hybridization of the central atom in...Ch. 20 - Prob. 94CWPCh. 20 - Prob. 95CWPCh. 20 - Prob. 96CWPCh. 20 - Prob. 97CPCh. 20 - Prob. 98CPCh. 20 - Lead forms compounds in the +2 and +4 oxidation...Ch. 20 - Prob. 100CPCh. 20 - Prob. 101CPCh. 20 - Prob. 102CPCh. 20 - You travel to a distant, cold planet where the...Ch. 20 - Prob. 104CPCh. 20 - Prob. 105CPCh. 20 - Prob. 106IPCh. 20 - Prob. 107IPCh. 20 - Although nitrogen trifluoride (NF3) is a thermally...Ch. 20 - While selenic acid has the formula H2SeO4 and thus...Ch. 20 - Prob. 110MPCh. 20 - Prob. 111MP
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- Which is the bonding and which is the anti-bonding orbital? Describe the differences in these two orbitals with respect to the number of nodes present, the relative electron density located between the atoms versus that located outside the inter-nuclear region, and the overall size of regions with the same phase. How do you expect the wavelength of the electron to vary between these two orbitals? What about the relative energy of the electron in these two states? Explainarrow_forwardWhen considering the Lewis structure for HF, we might mistakenly conclude that HF contains three lone pairs on the F atom which are degenerate. Explain the nature of these three electron pairs by referring to the molecular orbital energy level diagram.arrow_forwardThe bond angles in the nitrite ion, nitrogen dioxide, and the nitronium ion (NO2+) are 115°, 134°, and 180°, respectively. Explain these values using Lewis structures and VSEPR theory.arrow_forward
- Write the best Lewis dot structure for POCl₃, be sure to give the electronic geometry, molecular geometry, hybridization of the central element, polarity, and bond angle around the central element.arrow_forwardWhy does CO2 have a linear shape with no dipole moment?arrow_forwardDraw the best Lewis dot structure for BrCl₅, being sure to give the electronic geometry, molecular geometry, hybridization of the central element, polarity, and bond angle around the cental element.arrow_forward
- Draw the molecular orbital diagram of the hydroxyl radical, HO•, clearly labeling the MOs as o, o*, T, T*, or nb. What is the bond order? Given that the most stable electronic structures are ones in which all of the bonding and non-bonding orbitals are filled, would you expect HO• to act as an oxidizing or reducing agent? Why?arrow_forwardwhen the reaction occurs BF3 + F- gives BF4 the shape of electron distribution pairs around B changes describe the change in shapes and hybrid atomic orbitals of B used to explain the shapesarrow_forwardExplain why the bond between B and Cl in the molecule BCl3 is shorter than would be expected for a single B—Cl bond.arrow_forward
- Two useful organic compounds that contain Cl atoms are vinyl chloride (CH2=CHCl) and chloroethane (CH3CH2Cl). Vinyl chloride is the starting material used to prepare poly(vinyl chloride), a plastic in insulation, pipes, and bottles. Chloroethane (ethyl chloride) is a local anesthetic. Why is the C–Cl bond in vinyl chloride stronger than the C–Cl bond in chloroethane?arrow_forwardWhat is the hybridization of the central atom in the Lewis structure for XeF2?arrow_forwardSketch a molecular orbital diagram for Ti2. What is the bond order? Diamagnetic or Paramagnetic?arrow_forward
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