Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 2, Problem 14PP
Practice Problem 2.14
One way of naming ethers is to name the two alkyl groups attached to the oxygen atom in alphabetical order and add the word ether. If the two alkyl groups are the same, we use the prefix di-, for example, as in dimethyl ether. Write bond-line structural formulas for (a) diethyl ether, (b) ethyl propyl ether, and (c) ethyl isopropyl ether. What name would you give to
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2.25
A certain hydrocarbon has a molecular formula of C5 Hg. Which of the following is not a structural
possibility for this hydrocarbon?
(a) It is a cycloalkane.
(b) It contains one ring and one double bond.
(c) It contains two double bonds and no rings.
(d) It is an alkyne.
(a) What is meant by the term isomer ? (b) Among the four alkanes, ethane, propane, butane, and pentane, which is capable of existing in isomeric forms?
In each pair of compounds, which compound has a higher boiling point? Explain your reasoning.(a) octane or 2,2,3-trimethylpentane
Chapter 2 Solutions
Organic Chemistry
Ch. 2 - Practice Problem 2.1
Propose structures for two...Ch. 2 - Prob. 2PPCh. 2 - Prob. 3PPCh. 2 - Prob. 4PPCh. 2 - Prob. 5PPCh. 2 - Practice Problem 2.6
Using a three-dimensional...Ch. 2 - Practice Problem 2.7
Trichloromethane (, also...Ch. 2 - Prob. 8PPCh. 2 - Prob. 9PPCh. 2 - Practice Problem 2.10
Write bond-line structural...
Ch. 2 - Practice Problem 2.11 Although we shall discuss...Ch. 2 - Practice Problem 2.12 Write bond-line structural...Ch. 2 - Prob. 13PPCh. 2 - Practice Problem 2.14
One way of naming ethers is...Ch. 2 - Practice Problem 2.15 Eugenol is the main...Ch. 2 - Practice Problem 2.16
One way of naming amines is...Ch. 2 - Practice Problem 2.17 Which amines in Practice...Ch. 2 - Prob. 18PPCh. 2 - Prob. 19PPCh. 2 - Practice Problem 2.20
Write bond-line formulas for...Ch. 2 - Practice Problem 2.21
Write bond-line formulas for...Ch. 2 - Practice Problem 2.22
Write bond-line formulas for...Ch. 2 - Prob. 23PPCh. 2 - Practice Problem 2.24 Write another resonance...Ch. 2 - Prob. 25PPCh. 2 - Practice Problem 2.26
Which compound would you...Ch. 2 - Practice Problem 2.27 Arrange the following...Ch. 2 - Prob. 28PPCh. 2 - Prob. 29PCh. 2 - Identify all of the functional groups in each of...Ch. 2 - 2.31 There are four alkyl bromides with the...Ch. 2 - Prob. 32PCh. 2 - Classify the following alcohols as primary,...Ch. 2 - 2.34 Classify the following amines as primary,...Ch. 2 - Prob. 35PCh. 2 - Identify all of the functional groups in Crixivan,...Ch. 2 - 2.37 Identify all of the functional groups in...Ch. 2 - 2.38 (a) Indicate the hydrophobic and hydrophilic...Ch. 2 - Hydrogen fluoride has a dipole moment of 1.83 D;...Ch. 2 - 2.40 Why does one expect the cis isomer of an...Ch. 2 - Prob. 41PCh. 2 - Prob. 42PCh. 2 - Prob. 43PCh. 2 - 2.44 Consider each of the following molecules in...Ch. 2 - True or false: For a molecule to be polar, the...Ch. 2 - 2.46 Which compound in each of the following...Ch. 2 - Prob. 47PCh. 2 - The IR spectrum of propanoic acid (Fig. 2.16)...Ch. 2 - Prob. 49PCh. 2 - Write structural formulas for four compounds with...Ch. 2 - There are four amides with the formula C3H7NO. (a)...Ch. 2 - Prob. 52PCh. 2 - Prob. 53PCh. 2 - Prob. 54PCh. 2 - Prob. 55PCh. 2 - 2.56 Compound C is asymmetric, has molecular...Ch. 2 - 2.57 Examine the diagram showing an -helical...Ch. 2 - Prob. 1LGPCh. 2 - Prob. 2LGPCh. 2 - Prob. 3LGPCh. 2 - Consider the molecular formula C4H8O2. Predict...Ch. 2 - Consider the molecular formula C4H8O2. If any of...Ch. 2 - Prob. 6LGPCh. 2 - Consider the molecular formula.
7. Pick five...Ch. 2 - Prob. 8LGP
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- For the following, you must draw an appropriate structure that has the chemical formula C5H,NO with the indicated functional group(s) and/or property. In each case, identify any other functional groups in the molecule you draw, that were not indicated in the question. You may use condensed dash or bond-line structure to draw your molecules. a) An aldehyde b) A cyclic ether c) An acyclic amide that cannot form hydrogen bonds with itselfarrow_forward(A) A researcher analyzed an unknown solid, extracted from the bark of spruce trees, to determine its percentage composition. An 11.32 mg sample was burned in a combustion apparatus. The carbon dioxide (24.87 mg) and water (5.82 mg) were collected and weighed. From the results of this analysis, Determine: (1) both empirical and molecular formulas if molar mass is 420 g/mol. (ii) How many aromatic rings can this compound contain? (iii)Give the possible chemical name and structure of this compound and hence reasons for your selection.arrow_forward3. Circle the polar functional group in the following and identify them. (a) Br-CH2-CHz-COOH (b) CH3-CH2-CH2-NH- CH2-SHarrow_forward
- Draw one possible structure for each of the following compounds based on the descriptions below. (i) A compound with molecular formula C6H11NO that includes alkene, secondary amine, and primary alcohol functional groups. (ii) A compound with molecular formula C6H9NO that has an amide functional group and does not have an alkene group.arrow_forward2.24 The general molecular formula for alkanes is C„H2n+2. What is the general molecular formula for: (a) Cycloalkanes (b) Alkenes (c) Alkynes (d) Cyclic hydrocarbons that contain one double bondarrow_forwardb) Suggest a chemical test to differentiate between cyclopentanol and 1-methylcyclopentanol. Write all the observations and equations involved.arrow_forward
- Draw structures that t each description and name the functional group in each molecule: (a) two constitutional isomers with molecular formula C5H10O that contain different functional groups; (b) two constitutional isomers with molecular formula C6H10O that contain the same functional group.arrow_forwardGive the molecular, structural and displayed formulae of the following molecules: (a) 2,2-dimethylpropane (b) 3-bromo-2, 4, 4-trimethyloctanearrow_forward. (a) Write the molecular formula of acetylsalicylic acid (see Fig. 7.34a).(b) An aspirin tablet contains 325 mg acetylsalicylic acid. Calculate the number of moles of that compound in the tablet.arrow_forward
- Identify which of the following statement(s) is/are true. (a) A functional group is a group of atoms in an organic molecule that undergoes a predictable set of chemical reactions. (b) The functional group of an alcohol, an aldehyde, and a ketone have in common the fact that each contains a single oxygen atom. (c) A primary alcohol has one -OH group, a secondary alcohol has two -OH groups, and a tertiary alcohol has three -OH groups. (d) There are two alcohols with the molecular formula C3H8O. (e) There are three amines with the molecular formula C3H9N.arrow_forward(b) Draw the structural formula for each of the following compounds. Lukiskan formula struktur bagi setiap sebatian berikut. (i) 3-fluoro-2,4,4-trimethylpent-2-ene (ii) ethyl butanoate (ii) 2,4-dichloro-3-methylpentanoic acidarrow_forwardPentane and pentene. (a) Are isomers because they have the same molecular formula. (b) Are isomers because they have the same number of carbon atoms. (c) Are not isomers because they have different molecular formulas (d) Are not isomers because they have different namesarrow_forward
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Chapter 4 Alkanes and Cycloalkanes Lesson 2; Author: Linda Hanson;https://www.youtube.com/watch?v=AL_CM_Btef4;License: Standard YouTube License, CC-BY
Chapter 4 Alkanes and Cycloalkanes Lesson 1; Author: Linda Hanson;https://www.youtube.com/watch?v=PPIa6EHJMJw;License: Standard Youtube License