Organic Chemistry (8th Edition)
Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 19.2, Problem 4P

(a)

Interpretation Introduction

Interpretation: The structure of the compound 3-quinuclidinone is to be represented.

Concept Introduction:

The structural representation of the compound shows the arrangement of the atoms in the two-dimensional plane. It gives the graphical representation of the molecular structure.

(b)

Interpretation Introduction

Interpretation: The approximate pKa value of conjugate acid of 3-quinuclidinone has to be given.

Concept Introduction:

An acid dissociation constant is the measure of the strength of an acid in the solution. The logarithmic function of dissociation constant is given as pKa.

(c)

Interpretation Introduction

Interpretation: The compound that has lower value of pKa from the conjugate acid of 3-bromoquinuclidine and the conjugate acid of 3-chloroquinuclidine should be given.

Concept Introduction:

An acid dissociation constant is the measure of the strength of an acid in the solution. The logarithmic function of dissociation constant is pKa.

Electronegativity is the property by provide the tendency of an atom to attract the shared pair of electrons towards itself. The element that has high electronegativity will attract electrons more tightly.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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Organic Chemistry (8th Edition)

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